In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts
Advanced Materials, EarlyView.An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea +9 more
wiley +1 more source
Electronic and Steric Effects in Regioselective Tritiation of Anilides.
, 1992 Kunio Oohashi, Masato UDO
openalex +2 more sources
Arm‐Length‐Controlled CsPbBr3 Nanocrystals for Tunable Optical and Assembly Behavior
Advanced Materials, EarlyView.In this work, the synthesis parameters that dictate the formation of armed CsPbBr3 nanocrystals are described, and routes enabling precise control over arm length are proposed. Direct links between morphology and optoelectronic behavior are established.
Irina Skvortsova +13 more
wiley +1 more source
Steric effects in the thermal C2-C6 diradical cyclization of enyne-allenes
ARKIVOC, 2006 Michael Schmittel +5 more
doaj +1 more source
Unlocking regioselectivity: steric effects and conformational constraints of Lewis bases in alkyllithium-initiated butadiene polymerization. [PDF]
Chem SciTang J +5 more
europepmc +1 more source
Particle Transport in Confinement: Nonlinearity, Compressibility, and Steric Effects
, 2020 Soichiro Tottori
openalex +1 more source
Advanced Materials, EarlyView.Structural water is harnessed as an active co‐monomer to drive supramolecular polymerization in bulk water. Zinc(II) Salphen complexes confine water molecules to form hollow, metal–organic nanofibers that assemble into adaptive hydrogels with thermoresponsive mechanics and selective chiral recognition.
Merlin R. Stühler +10 more
wiley +1 more source
Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes. [PDF]
Chemistry, 2019 Lenczyk C +8 more
europepmc +1 more source
Positively Charged Polymer‐Brush MOFs for Large‐Area, Pressure‐Resistant Gas Separation Membranes
Advanced Materials, EarlyView.A universal POPA strategy enables positively charged polymer‐brush MOFs with self‐adaptive interfacial interlocking to resist aggregation under fast processing. This design ensures seamless dispersion within large‐area selective layers, achieving 1 m‐wide roll‐to‐roll fabrication of pressure‐resistant MMCMs with tunable CO2 separation performance ...
Yi Yang +11 more
wiley +1 more source