Tuning the rate of covalent network formation in hybrid double network hydrogels regulates whether supramolecular filaments retain their low‐nm structures or depletion‐induced supramolecular assembly takes place forming bundles. This kinetic handle programs the mesoscale architecture and toughness of the hydrogels, establishing a link between ...
Mertcan Özel +7 more
wiley +2 more sources
Mechanically Activated Luminescence in Polyurethanes Incorporating Calixarene Mechanophores
The conformational flexibility of a calix[4]arene is exploited to obtain a reversible mechanoluminophore featuring a pyrene excimer couple at the upper rim. Stretching a linear polyurethane incorporating such mechanophore results in luminescence color change from yellow–green to blue, consistent with a force‐induced conformational motion of the ...
Lucia Visieri +3 more
wiley +2 more sources
Structure-Activity Relationships for 1,3-Dipolar Cycloaddition Reactions of Criegee Intermediates with Carbonyls. [PDF]
Cornwell ZA +4 more
europepmc +1 more source
Reactive MD Screening of Antioxidants for Substituent-Dependent Phenoxyl Radical Stability. [PDF]
Ahmed S +4 more
europepmc +1 more source
Steroid absorption - use of the substituent constant π'
M E, Pickup, A H, Beckett
openaire +2 more sources
The Nonadiabatic Nature of the Substituent Effects in Azobenzene. [PDF]
van der Wal JJ +4 more
europepmc +1 more source
Methyl-substituted allyl cations. A comparison of experimental stability, rotational barrier, and solvolysis data with ab initio calculations [PDF]
Foerner, Wolfgang +2 more
core +1 more source
Negative cooperativity in the formation of two H-bonds with an oxygen H-bond acceptor. [PDF]
Misuraca MC, Hunter CA.
europepmc +1 more source
6,6'-Biazulenic core as a platform for unlocking Hammett constants <i>via</i> electrochemical free-energy relationships. [PDF]
Mandigo JA +10 more
europepmc +1 more source

