Results 151 to 160 of about 56,095 (275)

Comparative Review of <i>O</i>,<i>O</i>'-, <i>N</i>,<i>O</i>-, and <i>N</i>,<i>N</i>'-Bidentate Ligands: Structural and Electronic Properties of β-Diketones, Enaminones, and β-Diketiminates. [PDF]

Molecules
Conradie J.
europepmc   +1 more source

Mapping the Reactivity of the C═C Bond of Cyclic Enol Ether Derivatives of Sugars: Nucleophilicity Parameters of Glycals

Angewandte Chemie International Edition, EarlyView.
Endo or Exo? The first quantitative kinetic mapping of the nucleophilic reactivity of endo‐ and exo‐glycal compounds highlighted that endo‐glycals are typically 102 times less reactive than their corresponding parent cyclic enol ethers while exo‐glycals are 103 more nucleophilic. This experimental and computational structure–reactivity study highlights
Sophie Rodrigues, Saloua Chelli, Jenny Ha, Lucie Pedussaut, Sami Lakhdar, Raphaël Robiette, Stéphane P. Vincent, Guillaume Berionni   +7 more
wiley   +1 more source

Substituent and Ring-Number Effects on the Kinetics of PAH + OH Reactions: A QSAR-DOE Approach with Tunneling Corrections. [PDF]

Molecules
Parzych C, Baradyn M, Ratkiewicz A.
europepmc   +1 more source

C-N Coupling of 3-Aminothiophene with Substituted Benzenediazonium Cations: Carbon Nucleophilicity, Hyper-Ortho Effects, and Predictive Modeling of Structural Analogs. [PDF]

Chemphyschem
El Abed R, Slama T, Mahdhaoui F, Boubaker T.   +3 more
europepmc   +1 more source

A Dithio Vinylthio C2 Synthon Enabling Crystalline and Luminescent Sulfur‐Decorated Polymers

Angewandte Chemie International Edition, EarlyView.
Transforming CaC2 into a modular C2 building block enables the synthesis of α,ω‐bis(vinylthio) monomer and its conversion into crystalline, sequence‐defined sulfur‐decorated polymers. Their dense thioether clustering induces nonconventional luminescence and provides structure–function control in a more‐sustainable polymer platform.
Bercis Pektas, Cuong M. Q. Le, Samar Hajjar‐Garreau, Simon Gree, Hatice Mutlu   +4 more
wiley   +1 more source

Fluorescence Properties and Mg²⁺ Selectivity of Aryl-Alkynyl Derivatives of the o-Aminophenoltriacetate (APTRA) Ligand. [PDF]

Chemistry
Duncan LL, Hogg C, Williams JAG.
europepmc   +1 more source

o‐Terphenyl‐Based Family of Conjugated Macrocycles: Selective Recognition of Phenylalanine in Water and Interaction With Insulin

Angewandte Chemie International Edition, EarlyView.
This study presents the synthesis and binding properties of a new family of o‐terphenyl‐based macrocycles, TP[n] (n = 2‐8). The trimer variant efficiently binds phenylalanine in water with a 10‐fold selectivity compared to other amino acids and aromatic neurotransmitters.
Swapnil Ghule, Sayan Sarkar, Maria Eugenia Pérez‐Ojeda Rodriguez, Mark Spector, Frank Hampel, Evgeny A. Kataev   +5 more
wiley   +1 more source

New Insights into Intersystem Crossing in Substituted Aromatics: Singlet-Triplet Conversion in Carbonyl-Substituted Anthracenes. [PDF]

J Phys Chem B
Guarin CA, Larios-Sandoval A, Avila-Serna M, Bravo-Romero M, Jara-Cortés J, Resendiz-Pérez A, Peon J.   +6 more
europepmc   +1 more source

Normalizing Covalent Potency for Electrophilicity with Ligand Reactivity Efficiency. [PDF]

J Med Chem
Horning BD, Kingston C, Simon GM, Patricelli MP, Weinstein DS, Cook BN.   +5 more
europepmc   +1 more source

Decoding the Benzaldehyde Pharmacophore: Structural Determinants for Enhancing Antibacterial Efficacy and Food Safety. [PDF]

Foods
Arunachalam K, Zhao J, Arumugam VR, Gu R, Shi C.   +4 more
europepmc   +1 more source