Results 181 to 190 of about 56,095 (275)

Mechanistic elucidation of HFIP‐enabled C–Cl bond activation in the synthesis of tetrahydroquinoline derivatives

Bulletin of the Korean Chemical Society, EarlyView.
Mechanistic studies reveal that hexafluoroisopropanol (HFIP) enables C–Cl activation of propargylic halides by stabilizing ion pairs and enhancing effective Brønsted acidity. This cooperative solvent effect allows access to cationic intermediates and promotes cascade formation of tetrahydroquinolines through cyclization and disproportionation ...
Seung Hoon Lee, Hyung Min Chi
wiley   +1 more source

Copper(II) Complexes with 4-Substituted 2,6-Bis(thiazol-2-yl)pyridines-An Overview of Structural-Optical Relationships. [PDF]

Int J Mol Sci
Maroń AM, Świtlicka A, Szłapa-Kula A, Choroba K, Erfurt K, Siwy M, Machura B.   +6 more
europepmc   +1 more source

Genetic code expansion for chemosensing and chemical actuation of biological functions

Bulletin of the Korean Chemical Society, EarlyView.
Genetic code expansion (GCE) broadens the chemical repertoire for precise control of protein function in biological systems. This review highlights GCE‐based sensing and actuating systems that operate through selective interactions between noncanonical amino acids and chemical triggers.
Jieun Bae, Dong‐Hyun Kim, Minseob Koh
wiley   +1 more source

Thermodynamics of Protonation and Prototropic Equilibria in Simple <i>para</i>- and Di-<i>meta</i>-Substituted Phenols. [PDF]

ACS Omega
Kováčová A, Michalík M, Hartmann H, Lukeš V.   +3 more
europepmc   +1 more source

Multifunctional Design of Solid Polymer Electrolytes: Paving the Way for High‐Performance All‐Solid‐State Batteries

Carbon Energy, EarlyView.
This review provides a comprehensive and systematic overview of the multifunctional design strategies for solid polymer electrolytes (SPEs), a pivotal component for enabling high‐performance all‐solid‐state batteries (ASSBs). It begins with a detailed classification of SPE systems and elaborates on their respective molecular design principles. The work
Bin Man, Yuzhen Zhao, Bo Fu, Yulong Zeng, Yinwen Chen, Qingrui Liu, Wenjing Luo, Xin Li, Xuewei Li, Zikang Zhang, Yun Zheng, Sijie Liu   +11 more
wiley   +1 more source

Aromaticity switching by quantum tunnelling. [PDF]

Chem Sci
Rodríguez-Sotelo SJ, Santoyo-Flores JJ, Młodzikowska-Pieńko K, Poranne RG, Kozuch S.   +4 more
europepmc   +1 more source

Design of a Fluorescent Boronic Acid‐Functionalized Pyranoflavylium Receptor to Host and Release Diol‐Rich Bioactive Analytes in a pH‐Dependent Manner

ChemFoodChem, EarlyView.
This work presents a pH‐responsive ON–OFF fluorescent system based on a novel pyranoflavylium dye functionalized with a boronic acid receptor. The receptor exhibits a markedly higher affinity for the catechol‐containing polyphenol (+)‐catechin than for conventional diol‐rich molecules such as glucose and lactic acid.
Beatriz Senra, Mariana Cunha, Ana Sofia Pires, Ricardo Dias, Victor de Freitas, Luís Cruz   +5 more
wiley   +1 more source

Synthesis, Properties and Application of Novel 2-Substituted Benzothiazole-Based Oxime Esters. [PDF]

Materials (Basel)
Dzwonkowska-Zarzycka M, Balcerak-Woźniak A, Kabatc-Borcz J.   +2 more
europepmc   +1 more source

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

Chemistry – A European Journal, EarlyView.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve, Mariana Gomes Manso, Tibo Van Eeckhoorn, Mark E. Light, Bruno Linclau   +4 more
wiley   +1 more source

A Rational Framework to Estimate the Chiroptical Activity of [6]Helicene Derivatives. [PDF]

J Phys Chem A
Vanzan M, Bertuletti S, Becatti G, Bazan B, Rispens MT, Wan SIC, Leeman M, Noorduin WL, Baletto F.   +8 more
europepmc   +1 more source