Engineering Rapid Payload Release Rate in 1,6‐Elimination Processes of Self‐Immolative Linkers
The payload release rate of self‐immolative linkers was greatly improved through stabilization of an intermediate carbocation, thereby achieving an up to 10 000‐fold improvement in rate constant. Furthermore, lipophilicity was identified as another factor that affects the release rate. This new strategy is applicable to different payloads and different
Albert Marten Schulte +4 more
wiley +1 more source
New Fluorescent Probes, Their Spectroscopic Properties, and an Iterative Analysis of Their Complexation with Cyclodextrins. [PDF]
Topa-Skwarczyńska M +5 more
europepmc +1 more source
Substituent Effects of Arylazo Groups on Dissociation Constant
Yoji HASHIDA +3 more
openaire +2 more sources
Continuous-flow photogeneration of nitrosobenzaldehydes enables indazolone formation. [PDF]
Leclercq N +3 more
europepmc +1 more source
Redox‐Modulated σ‐Bond Reactivity in a Radical‐Anion Dimer
A radialene‐based radical anion σ‐dimer comprising an elongated C‐C bond exhibits orthogonal stimuli responsiveness. Homolytic cleavage of the dimer to the radical state is triggered by mechanical strain and high temperature. Dimer scission is also achieved via oxidation, resulting in formation of neutral radialenes.
Sushil Ranjan Bhatta +8 more
wiley +1 more source
Synthesis and Comparative Investigation of <i>Ortho</i>-, <i>Meta</i>-, and <i>Para</i>-Carboxyphenylmaleimide-Styrene Copolymers. [PDF]
Guliyeva S +6 more
europepmc +1 more source
Low-Temperature Retro Diels-Alder Reactions of Tetramethoxyanthracenes and Tetracyanoethylene. [PDF]
Wolfarth SA +6 more
europepmc +1 more source
Negative cooperativity in the formation of two H-bonds with an oxygen H-bond acceptor. [PDF]
Misuraca MC, Hunter CA.
europepmc +1 more source
A Graph-Based Machine Learning Framework to Assign Empirical Interaction Parameters for Novel Molecules. [PDF]
Fu Y, Stroet M, O'Mara ML.
europepmc +1 more source
Linking Enol-Keto Tautomerization Ratios in β‑Diketones to Their Physical Properties Using Computational Quantum Chemistry. [PDF]
Gabriel J +4 more
europepmc +1 more source

