Results 191 to 200 of about 363,660 (280)

Engineering Rapid Payload Release Rate in 1,6‐Elimination Processes of Self‐Immolative Linkers

open access: yesAngewandte Chemie, EarlyView.
The payload release rate of self‐immolative linkers was greatly improved through stabilization of an intermediate carbocation, thereby achieving an up to 10 000‐fold improvement in rate constant. Furthermore, lipophilicity was identified as another factor that affects the release rate. This new strategy is applicable to different payloads and different
Albert Marten Schulte   +4 more
wiley   +1 more source

New Fluorescent Probes, Their Spectroscopic Properties, and an Iterative Analysis of Their Complexation with Cyclodextrins. [PDF]

open access: yesJ Phys Chem B
Topa-Skwarczyńska M   +5 more
europepmc   +1 more source

Substituent Effects of Arylazo Groups on Dissociation Constant

open access: yesThe Journal of the Society of Chemical Industry, Japan, 1970
Yoji HASHIDA   +3 more
openaire   +2 more sources

Redox‐Modulated σ‐Bond Reactivity in a Radical‐Anion Dimer

open access: yesAngewandte Chemie International Edition, Volume 65, Issue 44, 26 October 2026.
A radialene‐based radical anion σ‐dimer comprising an elongated C‐C bond exhibits orthogonal stimuli responsiveness. Homolytic cleavage of the dimer to the radical state is triggered by mechanical strain and high temperature. Dimer scission is also achieved via oxidation, resulting in formation of neutral radialenes.
Sushil Ranjan Bhatta   +8 more
wiley   +1 more source

Low-Temperature Retro Diels-Alder Reactions of Tetramethoxyanthracenes and Tetracyanoethylene. [PDF]

open access: yesJ Org Chem
Wolfarth SA   +6 more
europepmc   +1 more source

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