Results 51 to 60 of about 210,733 (130)

A near-infrared fluorescent probe for sensitive detection and imaging of sulfane sulfur in living cells and &ITin vivo&IT

open access: yes, 2018
Sulfane sulfur refers to ionized sulfur that is reversibly attached to other sulfur atoms in the form of 6-valence electrons (S-0). Sulfane sulfur possesses stronger nucleophilicity and reducibility than hydrogen sulfide in a series of physiological ...
Han, Xiaoyue   +9 more
core   +1 more source

Molecular and energetic basis of histidine switch dynamics in respiratory complex I

open access: yesProtein Science, Volume 35, Issue 8, August 2026.
Abstract The respiratory complex I in mitochondria and bacteria drives the two‐electron reduction of quinone to pump protons across the membrane. The molecular basis of this catalytic reaction remains enigmatic despite significant progress in structural characterization of the complex.
Erik Endres   +7 more
wiley   +1 more source

Endogenous Sulfane Sulfur Mediates the Oxidative Stress Response Process in Pseudomonas aeruginosa

open access: yesAntioxidants
Sulfane sulfur species are increasingly recognized as integral cellular components involved in signaling pathways and cytoprotection against oxidative stress in mammals.
Weining Sun   +3 more
doaj   +1 more source

Advancing the Resolution of the Sulfur Compound Disproportionation Puzzle in Dissulfuribacter Thermophilus S69ᵀ Through Quantitative Label‐Free Comparative Proteomics

open access: yesEnvironmental Microbiology Reports, Volume 18, Issue 4, August 2026.
To date, only three microorganisms have been functionally characterised for sulfur disproportionation. Our work identifies a fourth example and provides novel proteomic insights into its underlying pathways. These findings advance our understanding of microbial sulfur catabolism and highlight the ecological role of D.
Marilina Fernandez   +8 more
wiley   +1 more source

Cars2‐Mediated Cysteine Catabolism Drives Brown Fat Development and Thermogenesis Through Persulfidating EBF2

open access: yesAdvanced Science, Volume 13, Issue 31, 4 June 2026.
We demonstrate that Cars2, a cysteine catabolic enzyme in mouse iBAT, is critical for cold tolerance and brown adipocyte differentiation. Through its CPERS activity, Cars2 produces CysSSH/H2S to induce EBF2 persulfidation, promoting its interaction with PPARγ and BRG1 to enhance thermogenic gene expression.
Xin Peng   +8 more
wiley   +1 more source

Thiosulfonate‐Derived BODIPY “Stick and Glue” Strategy for Fluorescent Thiol Labeling

open access: yesAngewandte Chemie, Volume 138, Issue 6, 2 February 2026.
We present a powerful photochemical strategy for converting disulfide bonds into stable thioether linkages via a [1,2]‐sigmatropic rearrangement. By integrating this reaction into traditional methanethiosulfonate‐based thiol labeling, we enable light‐triggered stabilization of peptide and protein conjugates with enhanced robustness and versatility ...
Lucie Šálková   +4 more
wiley   +2 more sources

Sulfane Decreases the Nucleophilic Reactivity of Zinc Thiolates: Implications for Biological Reactive Sulfur Species

open access: yes, 2022
A zinc dithiolate complex supported by a [N3S2] ligand was studied as a model for zinc-mediated thiolate-disulfide exchange, enabling isolation of a zinc-bound mixed-disulfide intermediate.
Emily Y. Tsui (1540417)   +2 more
core   +1 more source

Synthesis of (E)‐β‐SF5‐Styrenes via a Heck Reaction of in situ Generated Vinylsulfur Pentafluoride†

open access: yesChinese Journal of Chemistry, Volume 44, Issue 11, Page 1823-1827, 1 June 2026.
A Heck cross‐coupling reaction between aryl(hetero)iodides and in situ generated vinylsulfur pentafluoride is reported. This reaction provides β‐SF5‐styrenes in one‐step as a single (E)‐stereoisomer and tolerates a broad range of functional groups. Comprehensive Summary The synthesis of (E)‐(1‐alken‐1‐yl)pentafluoro‐λ6‐sulfanes, a valuable class of ...
Nicolas DeGrâce   +1 more
wiley   +1 more source

Sulfur‐Rich Sustainable Copolymers for Enhancing Redox Kinetics and Alleviating Cathode Passivation in Lithium‐Sulfur Batteries

open access: yesExploration, Volume 6, Issue 3, June 2026.
A molecularly engineered, sustainable sulfur‐rich redox copolymer cathode delivers accelerated sulfur conversion and suppressed passivation, enabling high sulfur utilization and durable, high‐performance LiS batteries. ABSTRACT Lithium‐sulfur (Li‐S) batteries are promising candidates for advanced energy storage systems.
Sangeeta Sahu   +8 more
wiley   +1 more source

Sodium thiosulfate treatment rescues hyperglycaemia‐induced pronephros damage in zebrafish by upregulating nitric oxide signalling

open access: yesThe Journal of Physiology, Volume 604, Issue 11, Page 4247-4260, 1 June 2026.
Abstract figure legend Sodium thiosulfate (STS) rescues the pronephros phenotype of pdx1 morphants through compensatory upregulation of nitric oxide (NO) metabolism. Zebrafish larvae injected with a control morpholino show the typical pronephros structure at 48 h post‐fertilization (hpf) with and without STS treatment.
Hannes Ott   +6 more
wiley   +1 more source

Home - About - Disclaimer - Privacy