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Biofilm behavior on sulfonated poly(ether-ether-ketone) (sPEEK)
Materials Science and Engineering: C, 2017Poly(ether-ether-ketone) (PEEK) has also shown to be very attractive for incorporating therapeutic compounds thanks to a sulfonation process which modifies the material structure resulting in a sulfonated-PEEK (sPEEK). Concerning biomedical applications, the objective of this work was to evaluate the influence of different sulfonation degree of sPEEK ...
Juan F D, Montero +7 more
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European Polymer Journal, 2006
Abstract Polymer blends of sulfonated poly(ether ether ketone) (SPEEK) and poly(ether sulfone) (PES) in N-methyl-2-pyrrolidinone (NMP) were prepared by solution casting. The investigation on water uptake, methanol uptake, permeability and proton conductivity has been conducted. The spin-lattice relaxation time in the rotating frame ( T 1 ρ
Han-Lang Wu +5 more
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Abstract Polymer blends of sulfonated poly(ether ether ketone) (SPEEK) and poly(ether sulfone) (PES) in N-methyl-2-pyrrolidinone (NMP) were prepared by solution casting. The investigation on water uptake, methanol uptake, permeability and proton conductivity has been conducted. The spin-lattice relaxation time in the rotating frame ( T 1 ρ
Han-Lang Wu +5 more
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Synthesis and characterization of poly(ether sulfone) and poly(ether sulfone ketone) copolymers
Journal of Applied Polymer Science, 1999Poly(ether sulfone) and poly(ether sulfone ketone) copolymers (I-V) were synthesized by the nucleophilic substitution reaction of 4,4'-dihydroxy diphenyl sulfone (DHDPS, A) with various mole proportions 4,4'-difluoro benzophenone (DFBP, B) and 4,4'-difluoro diphenyl sulfone (DFDPS, C) using sulfolane as solvent in the presence of anhydrous K 2 CO 3 ...
V. Lakshmana Rao +3 more
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Compatibility in immiscible poly(ether ether ketone)/poly(ether sulfone) blends
Journal of Applied Polymer Science, 1995AbstractBoth as‐molded and annealed poly(ether ether ketone) (PEEK)/poly(ether sulfone) (PES) blends have been prepared by direct injection molding. The system has been found to be immiscible at all compositions; however, as a result mainly of the produced morphology, it surprisingly maintains to a very great extent the excellent mechanical performance
A. Arzak, J. I. Eguiazábal, J. Nazábal
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High Performance Polymers, 2013
The monomer containing sulfone and imide linkages, namely bis[4-( p-phenoxybenzoyl)-1,2-benzenedioyl]- N, N, N′, N′-4,4′-diaminodiphenyl sulfone (BPBDADPS), was prepared by the Friedel–Crafts reaction of bis(4-chloroformyl-1,2-benzenedioyl)- N, N, N′, N′-4,4′-diaminodiphenyl sulfone with diphenyl ether.
Minghong Zhou +3 more
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The monomer containing sulfone and imide linkages, namely bis[4-( p-phenoxybenzoyl)-1,2-benzenedioyl]- N, N, N′, N′-4,4′-diaminodiphenyl sulfone (BPBDADPS), was prepared by the Friedel–Crafts reaction of bis(4-chloroformyl-1,2-benzenedioyl)- N, N, N′, N′-4,4′-diaminodiphenyl sulfone with diphenyl ether.
Minghong Zhou +3 more
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Synthesis and properties of poly(ether ether ketone)-poly(ether sulfone) block copolymers
Polymer, 1994Two series of block copolymers composed of poly(ether ether ketone) (PEEK) and poly(ether sulfone) (PES) components were prepared from the corresponding oligomers via a nucleophilic aromatic substitution reaction. In the first series of block copolymers, the Mn of the PEEK segment was fixed at 10 000, while the Mns of the PES segments ranged from 250 ...
Junkui Cao +4 more
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Polymers for Advanced Technologies, 2011
AbstractA new monomer, 4,4′‐bis(4‐phenoxybenzoyl)diphenyl(BPOBDP), was synthesized via a two‐step synthetic procedure. A series of novel poly(ether sulfone ether ketone ketone)/poly(ether ketone diphenyl ketone ether ketone ketone) copolymers were prepared by electrophilic Friedel–Crafts solution copolycondensation of isophthaloyl chloride (IPC) with a
Mingzhong Cai +4 more
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AbstractA new monomer, 4,4′‐bis(4‐phenoxybenzoyl)diphenyl(BPOBDP), was synthesized via a two‐step synthetic procedure. A series of novel poly(ether sulfone ether ketone ketone)/poly(ether ketone diphenyl ketone ether ketone ketone) copolymers were prepared by electrophilic Friedel–Crafts solution copolycondensation of isophthaloyl chloride (IPC) with a
Mingzhong Cai +4 more
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Crystallization behaviour of poly(ether ether ketone)/poly(ether sulfone) block copolymer
Polymer, 1996The crystallization and melting behaviours of a multiblock copolymer comprising poly(ether ether ketone) (PEEK) and poly(ether sulfone) (PES) blocks whose number average molecular weights were 10 000 and 2900, respectively, were studied. The effect of thermal history on crystallization was investigated by wide-angle X-ray diffraction measurement.
Junkui Cao +5 more
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Chinese Journal of Chemical Engineering, 2009
Abstract A sulfonated poly(ether ether ketone) (SPEEK) membrane with fairly high degree of sulfonation (DS) swells excessively and even dissolves at high temperature. To solve these problems, sulfonated phenolphthalein poly(ether sulfone) (SPES-C, DS53.7%) is blended with the SPEEK matrix (DS55.1%, 61.7%) to prepare SPEEK/SPES-C blend membrane.
Qijun GAO +4 more
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Abstract A sulfonated poly(ether ether ketone) (SPEEK) membrane with fairly high degree of sulfonation (DS) swells excessively and even dissolves at high temperature. To solve these problems, sulfonated phenolphthalein poly(ether sulfone) (SPES-C, DS53.7%) is blended with the SPEEK matrix (DS55.1%, 61.7%) to prepare SPEEK/SPES-C blend membrane.
Qijun GAO +4 more
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Development of Sulfonated Poly(ether-ether ketone)s for PEMFC and DMFC
2008During the last two decades, extensive efforts have been made to develop alternative hydrocarbon-based polymer electrolyte membranes to overcome the drawbacks of the current widely used perfluorosulfonic acid Nafion. This chapter presents an overview of the synthesis, chemical properties, and polymer electrolyte fuel cell applications of new proton ...
Kim, Dae Sik, Guiver, Michael
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