Results 131 to 140 of about 21,252 (299)

Zinc Promoted Cross‐Electrophile Sulfonylation to Access Alkyl–Alkyl Sulfones

open access: yesAdvanced Science
The transition metal‐catalyzed multi‐component cross‐electrophile sulfonylation, which incorporates SO2 as a linker within organic frameworks, has proven to be a powerful, efficient, and cost‐effective means of synthesizing challenging alkyl–alkyl ...
Zhuochen Wang   +6 more
doaj   +1 more source

Boron: A key element in radical reactions [PDF]

open access: yes, 2017
Boron derivatives are becoming key reagents in radical chemistry. Here, we describe reactions where an organoboron derivative is used as a radical initiator, a chain-transfer reagent, and a radical precursor.
Beauseigneur, Alice   +12 more
core  

Synthetic Strategies for Activity‐Based Probes to Decode Ubiquitin‐Like Modifiers

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT Ubiquitin‐like proteins (Ubls) such as SUMO, NEDD8, ISG15, URM1, UFM1, FAT10, ATG8/ATG12, and FUBI are essential regulators of cellular homeostasis, controlling processes from protein stability and trafficking to immune signaling and autophagy.
Saibal Chanda   +5 more
wiley   +1 more source

Metal Nanoparticles on Halloysite Applied in Stereoselective Hydrogenation of Tetrasubstituted Alkenes

open access: yesChemistry – A European Journal, EarlyView.
Composite materials based on metal nanoparticles supported on a naturally occurring nanotubular clay, halloysite (HAL), led to the diastereoselective hydrogenation of tetra‐substituted alkenes under relatively smooth conditions, mainly oxazolidinone‐based heterocycles.
Rosa Pich   +9 more
wiley   +1 more source

Synthesis and characteristics of polyarylene ether sulfones [PDF]

open access: yes
A method utilizing potassium carbonate/dimethyl acetamide, as base and solvent respectively, was used for the synthesis of several homopolymers and copolymers derived from various bisphenols.
Johnson, B. C.   +3 more
core   +1 more source

Iridium‐Catalyzed Linear‐Selective sp3 C−H Alkylation of N‐Methylamides Using Alkenes Enabled by Diphosphite Ligands

open access: yesChemistry – A European Journal, EarlyView.
An iridium‐catalyzed linear‐selective sp3 C─H alkylation of N‐methylamides with alkenes is described. This method tolerates various N‐methylacetamide derivatives and has a broad alkene scope. Mechanistic studies were also conducted. Internal alkenes can also be used through in situ consecutive alkene isomerization.
Haluhi Takahashi, Takanori Shibata
wiley   +1 more source

Monosubstituted N‐Arylhydroxylamine Chemistry: Integrating Contemporary Synthetic Approaches for the Efficient Construction of Diverse Heterocyclic Scaffolds

open access: yesChemistry – A European Journal, EarlyView.
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis   +2 more
wiley   +1 more source

Electrolyte Design Strategies for High‐Energy‐Density Li/Na/K‐Metal Batteries Toward Grid‐Scale Energy Storage: From Liquid to Solid

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This review summarizes key parameters including cathode loading and electrolyte consumption, clarifies the practical application scope of alkali metal batteries, and research progress on advanced electrolytes for grid‐scale energy storage systems. The growing demand for grid‐scale battery energy storage systems (BESSs) has prompted researchers to turn ...
Hui Shao, Zhiwei Ni, Jinkui Feng
wiley   +1 more source

Epimerization of chlorophyll derivatives [PDF]

open access: yes, 1992
Mazaki, Hitoshi   +4 more
core   +1 more source

Poly(aryl ethers) and related polysiloxane copolymer molecular coatings: Preparation and radiation degradation [PDF]

open access: yes
The radiation degradation of poly(arylene ether sulfones) and related materials is studied. These basic studies are important both as a means to developing stronger, more stable matrix resins for composite materials, as well as to improve the data base ...
Mcgrath, J. E.
core   +1 more source

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