Chiral sulfoxide-olefin ligands: tunable stereoselectivity in Rh-catalyzed asymmetric 1,4-additions
, 2012 A class of chiral sulfoxide-olefins were designed and synthesized through concise routes. Their applications as ligands in Hayashi-Miyaura reaction were studied, which found that vinyl substituents of the ligands vary in stereocontrolling ability ...
Liao, J (reprint author), Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China. +4 more
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Onium ions. 18. Static protonated and exchanging diprotonated ambivalent heteroorganic systems. hydroxylamines, acetone oxime, and dimethyl sulfoxide [PDF]
, 1978 Mayr, Herbert +5 more
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The Structural Basis of the Activity Cliff in Modafinil-Based Dopamine Transporter Inhibitors
BiomoleculesModafinil analogs with either a sulfoxide or sulfide moiety have improved binding affinities at the human dopamine transporter (hDAT) compared to modafinil, with lead sulfoxide-substituted analogs showing characteristics of atypical inhibition (e.g ...
Kuo-Hao Lee +3 more
doaj +1 more source
Methionine Sulfoxide Reduction in Mammals: Characterization of Methionine-\u3ci\u3eR\u3c/i\u3e-Sulfoxide Reductases [PDF]
, 2004 Methionine residues in proteins are susceptible to oxidation by reactive oxygen species, but can be repaired via reduction of the resulting methionine sulfoxides by methionine-S-sulfoxide reductase (MsrA) and methionine-R-sulfoxide reductase (MsrB ...
Gladyshev, Vadim, Kim, Hwa-Young
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Redox Biochemistry and ChemistryProteins are highly abundant and readily oxidized targets of reactive species formed in biological systems, with these often accounting for greater than 50 % of the dry mass of biological samples.
Michael J. Davies
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Selenium and methionine sulfoxide reduction [PDF]
, 2006 Methionine residues in proteins can be readily oxidized to a diastereomeric mixture of methionine sulfoxides by reactive oxygen species. In most organisms, methionine sulfoxides are reversibly and stereospecifically reduced back to methionine by two ...
Gladyshev, Vadim N., Kim, Hwa-Young
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Theoretical Studies of the Sulfenate−Sulfoxide Rearrangement
, 2016 Theoretical Studies of the Sulfenate−Sulfoxide ...
Daniel J. Pasto (3035751) +2 more
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Post-thaw dimethyl sulfoxide reduction in autologous peripheral blood progenitor cell suspensions
Hematology, Transfusion and Cell TherapyBackground and objectives: Dimethyl sulfoxide has become the most common cryoprotectant used for cryopreservation of hematopoietic progenitor cells because of its efficiency, regardless of its potentially toxic side effects. Its application is considered
Miroslava Jandová +6 more
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Chiral Sulfoxide Ligands in Catalytic Asymmetric Cyanohydrin Synthesis.
, 2003 A novel chiral sulfoxide-containing ligand for the catalytic addition of trimethylsilylcyanide to aldehydes is reported.
Gareth Rowlands (16063778) +1 more
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Effects of Octyl Phenyl Sulfoxide on the Hydration of Cement
, 2018 Controlling the hydration rate of cement can influence the properties of cement hydrates. Many commercial cement retarders are mainly adopted for slowing down the rate of cement hydration.
Maw Tien Lee +2 more
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