Results 91 to 100 of about 9,711 (311)

Bacterial‐Electrochemical Platform Utilizing a MXene‐Peptide Hydrogel

open access: yesAdvanced Functional Materials, EarlyView.
A peptide‐based fibrillar hydrogel incorporating MXene facilitates efficient electron delivery to intracellular recombinant [FeFe]‐hydrogenase enzyme in E. coli, enabling sustained bioelectrochemical H2 production without engineered exoelectrogenicity pathways.
Oren Ben‐Zvi   +6 more
wiley   +1 more source

Oxidation of Sulfides to Sulfoxides by NaBrO3-NH4Cl in Aqueous Acetonitrile [PDF]

open access: yesIranian Journal of Chemistry & Chemical Engineering, 2000
NaBrO3 combined with NH4Cl is found to be an efficient reagent for the transformation of sulfides into sulfoxides in aqueous and under mild conditions.
Ahmad Shaabani   +2 more
doaj  

Coupling Anodic Activity and Stability at Ni‐Based Non‐Oxide Catalysts via Coordinating Alcohol Oxidation and Oxygen Evolution

open access: yesAdvanced Functional Materials, EarlyView.
A cooperative and competitive interrelationship between alcohol oxidation (AOR) and water oxidation (OER) was observed on a typical anode catalyst of Ni2P. In situ Raman spectroscopy and electrochemical analyses revealed a specific complementary mechanism between them, in which OER and AOR critically contribute to the activity and stability of anodic ...
Yong Yan   +10 more
wiley   +1 more source

Aryl Sulfoxides from Allyl Sulfoxides via [2,3]-Sigmatropic Rearrangement and Domino Pd-Catalyzed Generation/Arylation of Sulfenate Anions

open access: yes, 2016
Allylic sulfoxides, via [2,3]-sigmatropic rearrangement and oxidative addition of the resulting allylic sulfenate esters to Pd(0), are found to be excellent precursors of sulfenate anions.
Gaëtan Le Duc (1867183)   +5 more
core   +1 more source

Support‐Controlled Reaction Pathways via Dynamic Sulfur‐Mediated Interfaces for Selective Urea Electrolysis

open access: yesAdvanced Functional Materials, EarlyView.
Sulfur‐doped graphitized carbon nanofibers act as adaptive catalyst–support platforms, enabling dynamic sulfur‐mediated reconstruction and strong metal–support interactions. This unique behavior enhances catalyst stability and controls reaction pathways, achieving highly selective urea oxidation (∼92% N2) coupled with efficient hydrogen evolution ...
Melanie Guillén‐Soler   +4 more
wiley   +1 more source

Ring Contracting Sulfur Extrusion from Oxidized Phenothiazine Ring Systems

open access: yesMolecules, 2008
Lithium, used in conjunction with sodium metal, produces a high yield of carbazole when reacted with phenothiazine-5-oxide or phenothiazine-5,5-dioxide.
Seth H. Berg, Steven C. Farmer
doaj   +1 more source

Sustainable Electrochemical Synthesis of High‐Quality MXenes: Mechanistic Insights, Applications, Challenges, and Technological Prospects

open access: yesAdvanced Functional Materials, EarlyView.
Electrochemical etching provides an eco‐friendly alternative to hazardous HF methods for MXene production. This approach facilitates the selective isolation of the A‐layer from MAX phases with tunable surface terminations. Controlling voltage, electrolytes, temperature, and duration enables the optimal structural integrity. Nevertheless, existing scale
Jagdeep Singh   +4 more
wiley   +1 more source

A Solvent Free Route to the Synthesis of Diaryl Sulfoxides [PDF]

open access: yesIranian Journal of Chemistry & Chemical Engineering, 2005
The solvent free route for the synthesis of diaryl sulfoxides from arenes and thionyl chloride in the presence of Lewis acids such as aluminum chloride and ferric chloride on silica gel are described.
Abbas Shockravi,   +2 more
doaj  

Garlic γ-glutamyl transpeptidases that catalyze deglutamylation of biosynthetic intermediate of alliin

open access: yesFrontiers in Plant Science, 2015
S-Alk(en)yl-L-cysteine sulfoxides are pharmaceutically important secondary metabolites produced by plants that belong to the genus Allium. Biosynthesis of S-alk(en)yl-L-cysteine sulfoxides is initiated by S-alk(en)ylation of glutathione, which is ...
Naoko eYoshimoto   +8 more
doaj   +1 more source

Nucleophilic Epoxidation of α‘-Hydroxy Vinyl Sulfoxides

open access: yes, 2016
The nucleophilic epoxidation of a variety of α‘-(1-hydroxyalkyl) vinyl sulfones and sulfoxides has been studied. The sulfones give rise to anti oxiranes with modest (E) or excellent (Z) selectivities and in good yields.
Paloma Méndez (2650711)   +8 more
core   +1 more source

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