Results 111 to 120 of about 15,552 (245)

1,2‐Dihydroxyanthraquinone, 6,7‐Dihydroxyisobenzofuranone and 7,8‐Dihydroxyquinolinone Derivatives as Ligands for the Self‐Assembly of Hierarchically Formed Lithium‐Bridged Titanium(IV) Helicates

European Journal of Organic Chemistry, EarlyView.
Catechol‐based annulated aromatics with carbonyl units are ideal ligands for the formation of titanium(IV) containing lithium‐bridged hierarchical helicates. They allow for the first time the use of amide units to obtain the dimeric helicate‐type complexes.
Steffen Schauerte, Frauke S. Adamsky, Christian Cremer, Niklas Polter, Markus Albrecht   +4 more
wiley   +1 more source

Mechanistic Dichotomy in Enantioselective Pd‐Catalyzed Alkylation of Pyrroles With Diazoesters

European Journal of Organic Chemistry, EarlyView.
Ligand‐controlled mechanistic divergence controls the Pd‐catalyzed asymmetric alkylation of pyrroles with diazoesters. While bipyridine ligands promote a conventional metal‐carbene pathway, bipyridine‐N,N′‐dioxide ligands redirect catalysis through electrophilic CH metalation before carbene transfer.
Vladimir Yu. Vaganov, Yasuaki Fukazawa, Svyatoslav M. Pechenkin, Vladimir S. Hein, Aleksandr E. Rubtsov, Andrei V. Malkov   +5 more
wiley   +1 more source

Stage‐Dependent Metabolic Reprogramming Drives a Self‐Organizing Microbial Network During Shanxi Aged Vinegar

Food Bioengineering, EarlyView.
Metabolic shifts from growth to stress adaptation in Shanxi aged vinegar fermentation link flavor maturation and microbial cooperation, and Lactobacillus and Acetobacter form a self‐organizing metabolic network through division of labor. ABSTRACT Acetic acid fermentation (AAF) is a vital stage in the production of Shanxi aged vinegar (SAV), during ...
Yanfang Wu, Jing Liu, Dantong Liu, Menglei Xia, Jia Song, Yu Zheng, Min Wang   +6 more
wiley   +1 more source

Strategies for Identification and Mitigation of Sanguinarine in Mustard Oil Adulterated by Argemone—A Comprehensive Review

Food Chemistry International, EarlyView.
Sanguinarine, a toxic alkaloid present in argemone, can lead to epidemic dropsy or chronic diseases through DNA intercalation and immune system suppression. Regulatory efforts face challenges due to economic motivations for adulteration as well as technical, social, and infrastructure barriers.
Gururaj Pejavara Narayana, Subhangi Panigrahi, Suresh Kumar Kalakandan, Hema Vincent, Ashish Rawson   +4 more
wiley   +1 more source

Monitoring and Mitigation Strategies for Hazardous Compounds in Chinese Rice Wine (Huangjiu): A Comprehensive Review

Food Safety and Health, EarlyView.
This review elucidates the formation pathways and detection technologies for ethyl carbamate, biogenic amines, and higher alcohols in Huangjiu. It concludes that integrated control frameworks are essential to decouple safety risks from the metabolic processes responsible for flavor development.
Lulu Liu, Zhiqiang Kong, Lin Li, Yifan Zhang, Bei Fan, Minmin Li   +5 more
wiley   +1 more source

An enormous sulfur isotope excursion indicates marine anoxia during the end-Triassic mass extinction. [PDF]

Sci Adv, 2020
He T, Dal Corso J, Newton RJ, Wignall PB, Mills BJW, Todaro S, Di Stefano P, Turner EC, Jamieson RA, Randazzo V, Rigo M, Jones RE, Dunhill AM.   +12 more
europepmc   +1 more source

Sulfur Isotope Effects. IV. Sulfur Isotope Effects in Anion Exchange Systems. [PDF]

Acta Chemica Scandinavica, 1972
Trygve E. Eriksen, Per-Gunnar Jönsson, Rune Liminga, Karin Nilsson, Wolfgang Nimmich   +4 more
openaire   +1 more source

Replacement of Ores Recorded by Textures and Chemical Compositions of Sphalerite: An Example From the Furutobe Kuroko Deposit, Akita, Japan

Geological Journal, EarlyView.
Coupled dissolution‐reprecipitation of early formed Cd‐, Fe‐, Ag‐ and Sb‐poor sphalerite through interaction with high‐temperature and high‐sulphur fugacity Cu‐rich fluids, responsible for the formation of the yellow ores, resulted in the formation of Cd‐, Fe‐, Ag‐ and Sb‐rich, heavily chalcopyrite‐diseased sphalerite and enrichment of critical metals ...
Manuel Nopeia, Ryohei Takahashi, Andrea Agangi, Pearlyn Manalo, Hinako Sato   +4 more
wiley   +1 more source

Geochemical and Geological Investigation of Skarn‐Type Pb–Zn Mineralization in Hastanetepe (Balya‐Balıkesir, Türkiye): An Approach Based on Fluid Inclusions, Sulphur Isotopes and Geochemical Data

Geological Journal, EarlyView.
Integrated petrographic, mineralogical and geochemical data from the Hastanetepe Pb–Zn deposit (Balya, Türkiye) reveal multi‐stage hydrothermal alteration and a magmatic sulphur source. Fluid inclusion and sulphur isotope results indicate a complex fluid evolution responsible for skarn‐type Pb–Zn mineralization along limestone–dacite contacts ...
Esra Ünal‐Çakır
wiley   +1 more source

Blood Biomarkers of Helicobacter pylori‐Infected Chronic Gastritis in Active Versus Stable Phases: A Clinical Indicator Analysis Combined With Proteomic and Metabolomic Investigations

iMetaMed, EarlyView.
Combining clinical data with serum proteomics and metabolomics, the HGB–CAPZB–acetic acid model was developed as a potential diagnostic index to distinguish the active and stable stages of Helicobacter pylori‐infected chronic gastritis, and the related mechanism was explored through multi‐omics.
Tiantong Jiang, Zhen Ma, Yang Li, Shaoli Wang, Yanjiao Zhang, Lei Song, Xianyu Li, Zhen Liu   +7 more
wiley   +1 more source