Results 151 to 160 of about 892,606 (318)

Spectroscopic Insights Into the Role of the Coverage of *CO and *H on Bifurcation of Ethylene and Ethanol Pathways in Carbon Dioxide Electroreduction

open access: yesCarbon Energy, EarlyView.
Zhao et al. control the coverage of *CO or *H intermediates by introducing foreign metal into Cu nanoparticles. The increased *CO coverage on Ag‐doped and Zn‐doped Cu promotes the generation of multi‐carbon products while the increased *H coverage of Co‐doped and Pd‐doped Cu enhances the selectivity of oxygenates. ABSTRACT As key reaction intermediates
Zi‐Hao Zhao   +3 more
wiley   +1 more source

Geochemical transformations of sulfur and their role in the formation of different types and subtypes of saline lakes in Southeastern Transbaikalia

open access: yesApplied Water Science
This study focused on the chemistry and isotopes of sulfur in lakes. The bottom sediments and water columns of lakes were found to contain reduced forms of sulfur, including hydrogen sulfide ions, elemental sulfur, and thiosulfate ions, along with ...
S. V. Borzenko, I. A. Fedorov
doaj   +1 more source

(NH4)2[Tc2O2(S2O7)4]: An Unexpected Technetium(V)‐Sulfate From the Reaction of (NH4)(TcO4) With SO3

open access: yesChemistry – A European Journal, EarlyView.
The reaction of the radioactive pertechnetate (99TcO4)− with the oxidizer SO3 leads to blue crystals of (NH4)2[Tc2O2(S2O7)4]. The complex dimeric [Tc2O2(S2O7)4]2− anion exhibits the technetium in the oxidation state V, showing that reduction occurs during the reaction.
Stefan Sutorius   +5 more
wiley   +1 more source

Ion–Molecule Reaction Products as Probes and Precursors for Preparative Mass Spectrometry

open access: yesChemistry – A European Journal, EarlyView.
Ion–molecule reactions in the gas phase of mass spectrometers are important for preparative mass spectrometry because they (1) provide knowledge about the intrinsic reactivity of ions, helping to predict and control their reactivity at interfaces, and (2) generate new complex ions that can be mass selected and deposited on surfaces.
Markus Rohdenburg   +4 more
wiley   +1 more source

On the Vapor Pressures, Phase Transitions, and Solid‐State Fluorescence of 2‐(2‐Hydroxyphenyl)benzoxazole and 2‐(2‐Hydroxyphenyl)benzothiazole

open access: yesChemPhysChem, EarlyView.
Benzazoles 2‐(2‐hydroxyphenyl)benzothiazole and 2‐(2‐hydroxyphenyl)benzoxazole exhibit tunable optoelectronic properties via excited‐state intramolecular proton transfer. Combining thermogravimetry (TG‐DSC), vapor pressure measurements, and fluorescence spectroscopy, how sulfur (S) versus oxygen (O) substitution dictates their stability, sublimation ...
José M. Silva Ferraz   +6 more
wiley   +1 more source

Why aquatic scientists should use sulfur stable isotope ratios (ẟ34S) more often.

open access: yesChemosphere
Over the last few decades, measurements of light stable isotope ratios have been increasingly used to answer questions across physiology, biology, ecology, and archaeology.
Vincent Raoult   +10 more
semanticscholar   +1 more source

Mononuclear Molybdenum and Tungsten Phosphine Complexes for Catalytic Ammonia Synthesis: Development of the pentaPod Concept

open access: yesChemPhysChem, EarlyView.
The pentaPod (P5) concept unites tridentate and tripodal fragments to form molybdenum and tungsten catalytic Chatt‐type complexes for N2‐to‐NH3 reduction. Two pentaPod ligands, P5Me and P5Pln, are available with either two dimethylphosphine or phospholano (Pln) groups. The complexes enable the investigation of reactivity differences in N2 reduction and,
Anna‐Marlene Vogt   +3 more
wiley   +1 more source

Reconstructing Redox Landscape With Coupled Nitrogen‐Sulfur Isotopes: A Case Study From Middle‐Late Triassic Chang 7 Member of the Yanchang Formation in the Ordos Basin (North China)

open access: yesGeochemistry, Geophysics, Geosystems
Euxinia, a crucial geological condition, usually signifies more severe extinction events attributed to deoxygenation in Earth's history. Despite extensive exploration of various proxies in paleoredox studies, most are primarily utilized to reconstruct ...
Xubin Wang   +8 more
doaj   +1 more source

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