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Bioinorganic Site‐Specific Conjugation of Multi‐Arm Linkers to Create Pharmaceuticals With Targeting and Effector Functions

Journal of the Chinese Chemical Society, EarlyView.
This Account showcases a modular, multi‐arm linker platform that decouples payload loading from antibody conjugation. By leveraging a computationally designed ACPGHA zinc‐binding motif, we demonstrate the construction of homogeneous antibody‐drug conjugates and theranostic antibody‐radionuclide conjugates with high payload loading. The multi‐arm linker
Cédric Grauffel, Tse Wen Chang, Carmay Lim +2 more
wiley +1 more source

Optimising Sulphur Fertilisation in Ryegrass–White Clover Swards Reduces Leached Nitrate Nitrogen Losses, While Increasing Plant Yield and Nitrogen Off‐Take

Journal of Plant Nutrition and Soil Science, EarlyView.
The inclusion of sulphur at two inorganic nitrogen rates (0 and 150 kg N ha−1) improves plant productivity in a ryegrass–white clover sward and reduces nitrate‐N loss to groundwater in a free‐draining sandy loam soil. ABSTRACT Background Reducing nitrogen (N) losses to water, lessening reliance on inorganic fertiliser and maintaining agricultural ...
Donal Kinsella, Imelda A. Casey, Patrick J. Forrestal +2 more
wiley +1 more source

Sedimentary Mercury Enrichments as a Tracer of Large Igneous Province Volcanism

Geophysical Monograph Series, Page 247-262., 2021

Exploring the links between Large Igneous Provinces and dramatic environmental impact

An emerging consensus suggests that Large Igneous Provinces (LIPs) and Silicic LIPs (SLIPs) are a significant driver of dramatic global environmental and biological changes, including mass extinctions.
Lawrence M. E. Percival +3 more
wiley

+1 more source

Insect communities of late Pleistocene steppe–tundra and Holocene boreal forest ecosystems in central Yukon Territory, Canada

Journal of Quaternary Science, EarlyView.
ABSTRACT Subfossil insect communities from the Quartz Creek site provide a detailed record of both Late Pleistocene steppe–tundra and Holocene boreal forest ecosystems in central Yukon Territory, Canada. Fifteen Pleistocene assemblages (marine isotope stages [MIS] 4 to 2) are dominated by steppe–tundra and dry‐tundra taxa, particularly the weevils ...
Scott L. Cocker +4 more
wiley +1 more source

Qualitative Analysis of Biogas by Raman Spectroscopy: Effect of Pressure on Major Components

Journal of Raman Spectroscopy, EarlyView.
Raman spectra of major and selected minor biogas components were studied under pressures up to 100 bar. Pressure‐induced shifts and band broadening were quantified for methane, carbon dioxide, and nitrogen, while Raman spectra of ammonia and hydrogen sulfide are presented in the context of biogas quality monitoring.
Dominik Tománek, Matouš Kuneš, Tomáš Hlinčík +2 more
wiley +1 more source

Chemical Kinetics of 2‐, 4‐, and 2,4‐Seleno‐Uracils at Low Temperatures: Tautomerizations and Rotamerizations on Inert Matrices

International Journal of Chemical Kinetics, EarlyView.
ABSTRACT In the interstellar medium, chemical reactions proceed under conditions vastly different to those on Earth; these include extremely low temperatures and densities and take place in the gas phase and on water–ice grains. Understanding the energetics and more importantly the kinetics of such reactions is of relevance to the consequences on how ...
Judith Wurmel, John M. Simmie
wiley +1 more source

Size Matters: Barrier Heights and Widths in the Kinetics Of Tautomerisation and Rotamerisation of Thiotropolone and Its Five‐ and Three‐Membered Cyclic Analogues

International Journal of Chemical Kinetics, EarlyView.
ABSTRACT Recent experiments by Nunes et al. have demonstrated that unprecedented control of chemical reactions is possible by narrowband infrared vibrational photo‐excitation at low temperatures in inert matrices. The generated higher energy level conformers may then undergo rotamerisation and tautomerisation reactions which provide extremely useful ...
Judith Wurmel, John M. Simmie
wiley +1 more source

Cis–Trans Rotational Isomerism of Formic Acid, Sulfur, and Selenium Analogues and Their Dimers: Chemical Kinetics Under Interstellar Conditions

International Journal of Chemical Kinetics, EarlyView.
ABSTRACT We present chemical kinetic rate constants for the cis to trans isomerisation or rotamerization of monomeric seleno‐, thio‐, and formic acids and that of three of their dimeric species, based on variational transition state theory and multidimensional tunneling calculations in the gas‐phase, from 10 K to 300 K. These provide, firstly, reliable
Judith Wurmel, John M. Simmie
wiley +1 more source

Effects of preservatives and poisons on the elemental and isotopic composition of freshwater particulate organic matter

Limnology and Oceanography: Methods, EarlyView.
Abstract Sediment traps, often used in tandem with preservatives or poisons, are widely used for the collection of particulate organic matter (POM), providing insight into the source to sink mechanisms that shape major biogeochemical cycles and sedimentary carbon sequestration.
Diana Velazquez, Nathan D. Sheldon, Jenan J. Kharbush +2 more
wiley +1 more source

Chemical Ionization Mass Spectrometry: Fundamental Principles, Diverse Applications, and the Latest Technological Frontiers

Mass Spectrometry Reviews, EarlyView.
ABSTRACT The review examines the evolution of chemical ionization mass spectrometry (CI‐MS), a technique developed in 1966 by Field and Munson. CI is a soft‐ionization method that produces more intense molecular ions with less fragmentation than electron ionization (EI).
Malvika Dutt +4 more
wiley +1 more source

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