Results 121 to 130 of about 9,785 (280)

Rationales for the Choice of Metals for Super‐Reduced Biological Metal Centers: Cobalt in Cobalamin Versus Nickel in F430

Chemistry – A European Journal, EarlyView.
DFT calculations on porphyrin, corrin, and corphin complexes of cobalt, rhodium, iron, manganese, or nickel, and QM/MM calculations on enzyme models, explore the factors controlling the availably of super‐reduced metal(I) states. True metal(I) states are seen in corrin only for cobalt, in corphin only for nickel, and not at all in porphyrin.
Radu‐Ioan Onija, Sergiu‐Raul Cosma, Adrian M. V. Brânzanic, Radu Silaghi‐Dumitrescu   +3 more
wiley   +1 more source

One‐Shot Pd(II)‐Catalyzed Multiple C–H Activation Enables Modular Construction of Fluorenylidene Oxindole‐Based Multi(Polycyclic) Aromatic Enes

Chemistry – A European Journal, EarlyView.
A one‐shot Pd(II)‐catalyzed C─H activation strategy enables the rapid conversion of simple linear propiolamides into structurally diverse mono‐, di‐, and tri‐olefin‐bridged MPAEs. This cascade process orchestrates up to six sequential C–H activations in a single operation, providing streamlined access to highly conjugated architectures.
Haiyu Wang, Kouki Sakata, Takuma Sato, Masahiro Terada, Tienan Jin   +4 more
wiley   +1 more source

Stable sulfur isotopes identify habitat-specific foraging and mercury exposure in a highly mobile fish community

, 2017
Tracking the uptake and transfer of toxic chemicals, such as mercury (Hg), in aquatic systems is challenging when many top predators are highly mobile and may therefore be exposed to chemicals in areas other than their location of capture, confounding ...
Lindenschmidt, Karl-Erich, Tendler, Brett, Brett Tendler, Lorne E. Doig, Pete Cott, Carr, Meghan K, Karl-Erich Lindenschmidt, John Chételat, Bharadwaj, Lalita, Paul D. Jones, Jardine, Timothy D, Jones, Paul D, Doig, Lorne E, Lalita Bharadwaj, Chetelat, John, Cott, Pete, Meghan K. Carr, Timothy D. Jardine   +17 more
core   +1 more source

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

Chemistry – A European Journal, EarlyView.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

Methylmercury dietary pathways and bioaccumulation in Arctic benthic invertebrates of the Beaufort Sea

Arctic Science
This study investigated methylmercury (MeHg) concentrations in Arctic benthic invertebrates from two shelf sites in the Canadian Beaufort Sea. Carbon, nitrogen, and sulfur stable isotopes and fatty acids were measured to examine diet influences on MeHg ...
Christine McClelland, John Chételat, Kathleen Conlan, Alec Aitken, Mark R. Forbes, Andrew Majewski   +5 more
doaj   +1 more source

Polyoxometalates in Photocatalytic CO2 Reduction: Multielectron Redox Regulation Across Molecular and Hybrid Architectures

EcoEnergy, EarlyView.
This review focuses on multielectron redox regulation across molecular and hybrid architectures for photocatalytic CO2 reduction, covering intrinsic POM photocatalysts, photosensitizer‐assisted assemblies, POM–metal–organic complexes, and POM‐integrated semiconductors and MOF/COF heterostructures to link structural motifs with charge transport, product
Bonan Li, Xiaowen Ruan, Sai Kishore Ravi
wiley   +1 more source

Microbiological fractionation of stable sulfur isotopes: A review and critique

, 1979
Microbiological transformations of sulfur compounds discriminate to various degrees between the stable sulfur isotopes 32S and 34S. Comparatively little is known on isotopic effects associated with sulfur‐oxidizing organisms, and the interpretation of ...
Trudinger, P. A., Chambers, L. A.
core   +1 more source

Locking Fe Single Atoms Into the Lattices of Mesoporous TiO2 Promotes Nitrogen Reduction

EcoEnergy, EarlyView.
S‐coordinated Fe single‐atom catalysts on mesoporous TiO2 have been constructed by a universal lattice‐confined strategy. This catalyst shows a unique nanoconfinement effect for mass transfer and maximizes the active sites to mimic nitrogenase for ambient electrocatalytic N2 reduction reaction.
Danli Liang, Ruicong Wang, Yujuan Zhao, Zaiwang Zhao   +3 more
wiley   +1 more source

Advances in Design Strategy and Mechanism Insights for Alkaline Hydrogen Evolution Reaction: Multilevel Site Engineering and Structure–Activity Relationship

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This review is about material design based on engineering multilevel sites from theoretical calculation and synthetic routes to mechanism, structure–activity relationship, challenges and perspectives for boosting hydrogen production in alkaline electrolyte. Electrolytic water splitting is a clean, carbon‐free method for producing green hydrogen and has
Ke Zhang, Hongying Luo, Yudong Du, Kehao Yu, Huayu Wu, Shimin Chai, Yanyan Liu, Yongfeng Wang, Jianchun Jiang, Baojun Li   +9 more
wiley   +1 more source

Constraining the atmospheric OCS budget from sulfur isotopes. [PDF]

Proc Natl Acad Sci U S A, 2020
Hattori S, Kamezaki K, Yoshida N.
europepmc   +1 more source