Results 101 to 110 of about 7,353 (249)

Reconstructing Redox Landscape With Coupled Nitrogen‐Sulfur Isotopes: A Case Study From Middle‐Late Triassic Chang 7 Member of the Yanchang Formation in the Ordos Basin (North China)

Geochemistry, Geophysics, Geosystems
Euxinia, a crucial geological condition, usually signifies more severe extinction events attributed to deoxygenation in Earth's history. Despite extensive exploration of various proxies in paleoredox studies, most are primarily utilized to reconstruct ...
Xubin Wang, Lin Dong, Tong Li, Kun Ling, Changhu Zhang, Yijie Bin, Ziyi Wang, Zhijun Jin, Jinhua Fu   +8 more
doaj   +1 more source

Bismuth Chalcogenide‐Based Photocatalysts for Nitrogen Reduction: Recent Progress and Prospects

Chemistry – A European Journal, EarlyView.
Bismuth chalcogenides emerge as promising visible‐light photocatalysts for sustainable ammonia synthesis, driven by tunable electronic structures and strong N2 activation. Recent advances reveal how defects, doping and heterojunction design synergistically enhance charge separation and reactivity. Key challenges and future directions highlight pathways
Mukesh K. Verma, Muhammad D. Bala, Phindile B. Khoza, Tshephiso R. Papo, Mzamo L. Shozi   +4 more
wiley   +1 more source

On Metal Carbonyl Compounds in Catalytic Methanol Synthesis: Detection, Consequences, and Removal

Chemie Ingenieur Technik, EarlyView.
Deactivation of Cu/ZnO/Al2O3 catalysts by metal carbonyl compounds in the feed gas is a critical problem in catalytic methanol synthesis. We utilize PTR–MS to identify potential chemical sources, detect contamination in an in‐house CO gas line, and validate filter methods for removing these catalyst poisons before synthesis.
Florian Stappert, Daniel Laudenschleger, Tim Herrendorf, Julia Menten, Holger Ruland   +4 more
wiley   +1 more source

Experimental methods in chemical engineering: Temperature‐programmed oxidation—TPO

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract Temperature‐programmed oxidation (TPO) probes the oxidative capacity and redox properties of solid materials—catalysts, metal oxides, perovskites, and carbonaceous deposits. It identifies coke type, distribution, and reactivity. TPO instruments pass an oxidizing gas (diluted O2$$ {\mathrm{O}}_2 $$, air, or less commonly N2O$$ {\mathrm{N}}_2 ...
Gholamreza Roohollahi, Jildimara de Jesus Santana, Alexander R. P. Harrison, Sara Andreoli, Ewa Marek, Stuart Scott, Mohammad Latifi, Gregory S. Patience   +7 more
wiley   +1 more source

Snapshots of Coastal Ecology Using Multiproxy Analysis Reveals Insights Into the Preservation of Swamp and Marsh Environments Since the Late Pleistocene

Geochemistry, Geophysics, Geosystems
The southeastern United States Coastal Plain ecosystem contains baldcypress (Taxodium distichum) swamps and grass‐dominated marshes. These ecosystems also occurred on the exposed continental shelf during lower sea levels but are rarely preserved due to ...
Kendall Fontenot, Kristine L. DeLong, Brian A. Schubert, Sophie Warny, Davin J. Wallace, Carrie M. Miller, Erin Culver‐Miller, Michael J. Polito, Carl A. Reese, Kathryn Garretson, Kehui Xu, Grant L. Harley, Jeffrey Obelcz, Kelli L. Moran, Julian Traphagan, Douglas Jones, Alicia Caporaso   +16 more
doaj   +1 more source

Polyoxometalates in Photocatalytic CO2 Reduction: Multielectron Redox Regulation Across Molecular and Hybrid Architectures

EcoEnergy, EarlyView.
This review focuses on multielectron redox regulation across molecular and hybrid architectures for photocatalytic CO2 reduction, covering intrinsic POM photocatalysts, photosensitizer‐assisted assemblies, POM–metal–organic complexes, and POM‐integrated semiconductors and MOF/COF heterostructures to link structural motifs with charge transport, product
Bonan Li, Xiaowen Ruan, Sai Kishore Ravi
wiley   +1 more source

Locking Fe Single Atoms Into the Lattices of Mesoporous TiO2 Promotes Nitrogen Reduction

EcoEnergy, EarlyView.
S‐coordinated Fe single‐atom catalysts on mesoporous TiO2 have been constructed by a universal lattice‐confined strategy. This catalyst shows a unique nanoconfinement effect for mass transfer and maximizes the active sites to mimic nitrogenase for ambient electrocatalytic N2 reduction reaction.
Danli Liang, Ruicong Wang, Yujuan Zhao, Zaiwang Zhao   +3 more
wiley   +1 more source

Advances in Design Strategy and Mechanism Insights for Alkaline Hydrogen Evolution Reaction: Multilevel Site Engineering and Structure–Activity Relationship

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This review is about material design based on engineering multilevel sites from theoretical calculation and synthetic routes to mechanism, structure–activity relationship, challenges and perspectives for boosting hydrogen production in alkaline electrolyte. Electrolytic water splitting is a clean, carbon‐free method for producing green hydrogen and has
Ke Zhang, Hongying Luo, Yudong Du, Kehao Yu, Huayu Wu, Shimin Chai, Yanyan Liu, Yongfeng Wang, Jianchun Jiang, Baojun Li   +9 more
wiley   +1 more source

Sulfur Isotope Effects. IV. Sulfur Isotope Effects in Anion Exchange Systems. [PDF]

Acta Chemica Scandinavica, 1972
Trygve E. Eriksen, Per-Gunnar Jönsson, Rune Liminga, Karin Nilsson, Wolfgang Nimmich   +4 more
openaire   +1 more source

1,2‐Dihydroxyanthraquinone, 6,7‐Dihydroxyisobenzofuranone and 7,8‐Dihydroxyquinolinone Derivatives as Ligands for the Self‐Assembly of Hierarchically Formed Lithium‐Bridged Titanium(IV) Helicates

European Journal of Organic Chemistry, EarlyView.
Catechol‐based annulated aromatics with carbonyl units are ideal ligands for the formation of titanium(IV) containing lithium‐bridged hierarchical helicates. They allow for the first time the use of amide units to obtain the dimeric helicate‐type complexes.
Steffen Schauerte, Frauke S. Adamsky, Christian Cremer, Niklas Polter, Markus Albrecht   +4 more
wiley   +1 more source