Results 91 to 100 of about 7,353 (249)

Durable Fuel Cell Cathode Enabled by Pt Embedded Nanoscale Carbon Network via a Scalable Process

Carbon Energy, EarlyView.
Platinum nanoparticles embedded nanoscale carbon network (Pt‐e‐Cn) are developed via a scalable flame spray pyrolysis process. Proton exchange membrane fuel cells (PEMFC) employing mesoporous Pt‐e‐Cn cathode electrocatalysts exhibit exceptional durability without compromising performance.
Suriya Venkatesan, Jens Mitzel, Tobias Morawietz, Emmanuelle Boehm‐Courjault, Deven P. Estes, Laure Guétaz, Indro Biswas, Jan Van Herle, Karsten Wegner, Pawel Gazdzicki, Kaspar Andreas Friedrich   +10 more
wiley   +1 more source

Constraining the atmospheric OCS budget from sulfur isotopes. [PDF]

Proc Natl Acad Sci U S A, 2020
Hattori S, Kamezaki K, Yoshida N.
europepmc   +1 more source

Rationales for the Choice of Metals for Super‐Reduced Biological Metal Centers: Cobalt in Cobalamin Versus Nickel in F430

Chemistry – A European Journal, EarlyView.
DFT calculations on porphyrin, corrin, and corphin complexes of cobalt, rhodium, iron, manganese, or nickel, and QM/MM calculations on enzyme models, explore the factors controlling the availably of super‐reduced metal(I) states. True metal(I) states are seen in corrin only for cobalt, in corphin only for nickel, and not at all in porphyrin.
Radu‐Ioan Onija, Sergiu‐Raul Cosma, Adrian M. V. Brânzanic, Radu Silaghi‐Dumitrescu   +3 more
wiley   +1 more source

One‐Shot Pd(II)‐Catalyzed Multiple C–H Activation Enables Modular Construction of Fluorenylidene Oxindole‐Based Multi(Polycyclic) Aromatic Enes

Chemistry – A European Journal, EarlyView.
A one‐shot Pd(II)‐catalyzed C─H activation strategy enables the rapid conversion of simple linear propiolamides into structurally diverse mono‐, di‐, and tri‐olefin‐bridged MPAEs. This cascade process orchestrates up to six sequential C–H activations in a single operation, providing streamlined access to highly conjugated architectures.
Haiyu Wang, Kouki Sakata, Takuma Sato, Masahiro Terada, Tienan Jin   +4 more
wiley   +1 more source

Geochemical transformations of sulfur and their role in the formation of different types and subtypes of saline lakes in Southeastern Transbaikalia

Applied Water Science
This study focused on the chemistry and isotopes of sulfur in lakes. The bottom sediments and water columns of lakes were found to contain reduced forms of sulfur, including hydrogen sulfide ions, elemental sulfur, and thiosulfate ions, along with ...
S. V. Borzenko, I. A. Fedorov
doaj   +1 more source

An Estimate of Sulfur Isotope Fractionation Due to SO₂ Self-Shielding in the Upper Atmosphere of Venus

Atmosphere
Sulfur dioxide is a trace constituent of the upper atmosphere of Venus but plays a dominant role in the photochemistry above the cloud tops. Because SO2 undergoes indirect dissociation to a relatively long-lived excited state, it has a line-type ...
James R. Lyons
doaj   +1 more source

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

Chemistry – A European Journal, EarlyView.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

Syntheses and Properties of Pentafluoroethylplumbanes in the Oxidation States +II, +III, and +IV

Chemistry – A European Journal, EarlyView.
Syntheses of pentafluoroethyl substituted plumbanes in the formal oxidation states +II, +III, and +IV are reported. The compounds were characterized by multinuclear NMR spectroscopy, including 207Pb NMR spectroscopy, mass spectrometry and single‐crystal x‐ray diffraction experiments. ABSTRACT Mono‐, bis‐, and tris(pentafluoroethyl)plumbanes of the type
Michael Grasse, Lukas Hartmann, Beate Neumann, Hans‐Georg Stammler, Berthold Hoge   +4 more
wiley   +1 more source

Guidelines for Sample Preparation and Stable Isotope Analysis of Food for Traceability Studies

Food Safety and Health
Stable isotope analysis is a powerful and increasingly applied tool for food traceability, enabling high‐confidence determination of origin, production practices, and authenticity. This guideline provides practical recommendations for the preparation and
Bayan Nuralykyzy, Syed Abdul Wadood, Jing Nie, Hanyi Mei, Shengzhi Shao, Yongzhi Zhang, Chunlin Li, Yuwei Yuan, Karyne M. Rogers   +8 more
doaj   +1 more source

Silica‐Supported Mononuclear Methyl‐Platinum Complexes Stabilized by Trimethylphosphine—Synthesis, Structure, and Reactions Under Reducing Conditions

Chemistry – A European Journal, EarlyView.
The article describes the synthesis and molecular transformations of a silica‐supported bis(phosphine)methylplatinum(II) complex under reactive (H2, CO) and inert gas atmospheres. The focus lies on the stabilizing effect of the sterically non‐demanding trimethylphosphine ligand, which alters the reactivity of the surface sites, compared to other ...
Lea S. Kopietz, Sven Schaefer, Oksana Storcheva, Gabriele Raudaschl‐Sieber, Johannes Bitzer, Wolfgang Kleist, Klaus Köhler   +6 more
wiley   +1 more source