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Molecular Thioamide ↔ Iminothiolate Switches for Sulfur Mustards
Inorganic Chemistry, 2011SNS platinum(II) pincer complexes reversibly bind and release the surrogate half sulfur mustard, 2-chloroethyl ethyl sulfide (CEES). The switch-like behavior of the pincers is attributed to a reversible transformation between the thioamide and iminothiolate forms of the pincer skeleton under slightly acidic and basic conditions, respectively.
Qi-Qiang, Wang +3 more
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Detection of sulfur mustard-induced DNA modifications
Chemico-Biological Interactions, 1994Sulfur mustard is acutely toxic to the skin, eyes, and respiratory tract, and is considered carcinogenic to humans by the IARC. Since all of these toxicities are thought to be initiated by DNA alkylation, the level of DNA damage should serve as a biomarker for exposure.
D B, Ludlum +4 more
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Toxicokinetics of sulfur mustard
2016In this chapter an overview is presented on the state of knowledge concerning the toxicokinetics of sulfur mustard. The procedures to analyze intact sulfur mustard in the blood and tissues of laboratory animals at toxicologically relevant levels are discussed.
Langenberg, J.P. +2 more
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