Results 61 to 70 of about 89,931 (179)

Evidence for structural crossover in the supercritical state

open access: yes, 2013
The state of matter above the critical point is terra incognita, and is loosely discussed as a physically homogeneous flowing state where no differences can be made between a liquid and a gas and where properties undergo no marked or distinct changes ...
Bolmatov, Dima   +4 more
core   +1 more source

Understanding the Role of Morphology in the Direct Synthesis of Diethyl Carbonate Over Ceria‐Based Catalysts: An In Situ Infrared and High‐Resolution TEM Study

open access: yesChemCatChem, EarlyView.
Pure and Zr‐doped ceria‐based catalysts with different morphologies were developed for the direct synthesis of diethyl carbonate from ethanol and CO2. Rod‐shaped pure CeO2 outperformed the other samples, thanks to abundant structural defects and high basicity.
Mara Arduino   +4 more
wiley   +1 more source

Analysis of triacylglycerol and phospholipid sn‐positional isomers by liquid chromatographic and mass spectrometric methodologies

open access: yesMass Spectrometry Reviews, EarlyView., 2023
Abstract Analysis of triacylglycerol (TG) and phospholipid sn‐positional isomers can be divided into two main categories: (a) direct separation by chromatography or other means such as ion mobility mass spectrometry and (b) quantification of regioisomer ratios by structurally informative fragment ions with mass spectrometric methods.
Mikael Fabritius, Baoru Yang
wiley   +1 more source

Linear instability of Poiseuille flows with highly non-ideal fluids

open access: yes, 2018
The objective of this work is to investigate linear modal and algebraic instability in Poiseuille flows with fluids close to their vapour-liquid critical point.
Fu, Song, Pecnik, Rene, Ren, Jie
core   +1 more source

Cannabigerol Extraction from a Cannabis Cultivar Using a Supercritical Carbon Dioxide Process

open access: yesChemical Engineering &Technology, EarlyView.
The aim of this work was to assess for the first time the supercritical fluid extraction (SFE) process feasibility to obtain a CBG‐rich extract from Cannabis. Extraction experiments highlighted that CBG can be properly extracted at 18 MPa and 40 °C and the extraction plant scheme affected CBG recovery and purity.
Lucia Baldino   +3 more
wiley   +1 more source

Electrodeposition of Thermoelectric Materials

open access: yesChemElectroChem, EarlyView.
Thermoelectric (TE) materials produce electrical energy when exposed to a thermal gradient. This review presents the opportunities of electrochemistry as a synthetic route for promising TE materials, highlighting the materials scopes and synthetic strategies toward high‐performing electrochemically synthesized TE materials.
Samuel C. Perry   +4 more
wiley   +1 more source

Chiral Cobaltabis(dicarbollide) Catalysts Prepared Using a Silica Helical Nanoplatform for the Enantioselective Photooxidation of Aromatic Secondary Alcohols

open access: yesChemistry – A European Journal, EarlyView.
Chiral COSAN Nanocatalysts: Enantiopure silica COSAN‐Hybrid nanohelices have been prepared by electrostatic co‐assembly of achiral COSAN anions and silica hybrid nanohelices. Their optical activity was confirmed by CD and ROA measurements. These COSAN‐Hybrids are efficient and recoverable catalysts in the photooxidative kinetic resolution of aromatic ...
Hao Wang   +8 more
wiley   +1 more source

Thermal analysis of turbulent flow of a supercritical fluid [PDF]

open access: yes
The influence of the large variation of thermodynamics and transport properties near the pseudocritical temperature on the heat transfer coefficient of supercritical fluid in turbulent flow was studied.
Yamane, E.
core   +1 more source

Development and Validation of a Laboratory‐Scale Methanol Synthesis Mini‐Plant and Digital Twin Simulation

open access: yesChemie Ingenieur Technik, EarlyView.
A methanol mini‐plant and its digital twin were developed to study flexible feedstocks, reactant recycling, and product condensation. Experimental results show good agreement with simulations, allowing systematic investigation of process parameters. Tests with biomass‐derived syngas demonstrated the feasibility of industrial COx sources.
Timothy A. Nowak   +5 more
wiley   +1 more source

Corn cob pyrolysis: A systematic literature review of methods and applications

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Mapping the research landscape of corn cob pyrolysis. Abstractas The agricultural sector is experiencing a surge in waste generation due to population growth, creating an urgent need to convert byproducts into value‐added products. Maize (Zea mays L.), a leading global crop, produces significant byproducts, such as corn cob, which are often undervalued.
Vilmar Steffen   +5 more
wiley   +1 more source

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