Results 131 to 140 of about 153,377 (362)

Dynamic transition in supercritical iron [PDF]

open access: yesarXiv, 2014
Recent advance in understanding the supercritical state posits the existence of a new line above the critical point separating two physically distinct states of matter: rigid liquid and non-rigid gas-like fluid. The location of this line, the Frenkel line, remains unknown for important real systems. Here, we map the Frenkel line on the phase diagram of
arxiv  

Hydrogen Storage and Release via Carbon Dioxide Hydrogenation to Formate Salts under High‐Pressure Conditions with Ir Complex and Subsequent Formic Acid Dehydrogenation

open access: yesChemistryOpen, EarlyView.
We demonstrated the potential of formic acid for efficient hydrogen storage and regeneration through CO₂ reduction followed by dehydrogenation. Using Cp*Ir catalysts with an amino‐substituted bipyridine ligand, we achieved a 96 % yield of formic acid with a formate concentration of 0.81 mol/L under supercritical conditions, followed by dehydrogenation ...
Seo Ono, Ryoichi Kanega, Hajime Kawanami
wiley   +1 more source

Thermodynamic Aspects of Supercritical Fluids Processing: Applications of Polymers and Wastes Treatment Aspects thermodynamiques des procédés mettant en oeuvre des fluides supercritiques : applications aux traitements des polymères et des déchets

open access: yesOil & Gas Science and Technology, 2006
Supercritical fluid processes are of increasing interest for many fields : in supercritical fluid separation (petroleum-chemistry separation and purification, food industry) and supercritical fluid chromatography (analytical and preparative separation ...
Beslin P., Cansell F., Rey S.
doaj   +1 more source

Analysis of Enantiomers in Products of Food Interest

open access: yesMolecules, 2019
The separation of enantiomers has been started in the past and continues to be a topic of great interest in various fields of research, mainly because these compounds could be involved in biological processes such as, for example, those related to human ...
Chiara Fanali   +3 more
doaj   +1 more source

Ab initio intermolecular interactions mediate thermochemically real-fluid effects that affect system reactivity [PDF]

open access: yesarXiv
The properties of supercritical fluids are dictated by intermolecular interactions that involve two or more molecules. Such intermolecular interactions were described via intermolecular potentials in historical supercritical combustion modeling studies, but have been treated empirically and with no consideration of radical interactions or multi-body ...
arxiv  

Local structure of supercritical matter [PDF]

open access: yesarXiv, 2014
The supercritical state is currently viewed as uniform on the pressure-temperature phase diagram. Supercritical fluids have the dynamic motions of a gas but are able to dissolve materials like a liquid. They have started to be deployed in many important industrial applications stimulating fundamental theoretical work and development of experimental ...
arxiv  

A Validated GC‐MS Method for Major Terpenes Quantification in Hydrodistilled Cannabis sativa Essential oil

open access: yesPhytochemical Analysis, EarlyView.
ABSTRACT Introduction Terpenes, which are found in high concentrations in the essential oil fraction of the Cannabis sativa flower, have demonstrated potential in many therapeutic and industrial applications. Objectives This work reports on a method developed for quantifying 18 terpenes in C. sativa essential oil obtained through hydrodistillation. The
Noelle Joy   +2 more
wiley   +1 more source

Superheated liquids for the extraction of solid residues from winemaking processes [PDF]

open access: yes, 2003
Solid residues from winemaking process have been subjected to extraction with superheated water-ethanol mixtures. Identification and characterisation of the extracted compounds have been made by spectrophotometry, gas chromatography with either flame ...
Gonzalez-Rodriguez, Jose   +2 more
core   +1 more source

Ultra-high-performance supercritical fluid chromatography with quadrupole-time-of-flight mass spectrometry (UHPSFC/QTOF-MS) for analysis of lignin-derived monomeric compounds in processed lignin samples

open access: yesAnalytical and Bioanalytical Chemistry, 2017
The conversion of lignin to potentially high-value low molecular weight compounds often results in complex mixtures of monomeric and oligomeric compounds.
Jens Prothmann   +4 more
semanticscholar   +1 more source

The enantioselective potential of amylose tris(3‑chloro-5-methylphenyl carbamate)-based chiral stationary phase in sub/supercritical fluid and normal phase liquid chromatography

open access: yesJournal of Chromatography Open
The enantioselective potential of amylose tris (3‑chloro-5-methylphenylcarbamate) based chiral stationary phase in sub/supercritical fluid chromatography and normal phase liquid chromatography was evaluated.
Denisa Folprechtová   +2 more
doaj  

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