Results 101 to 110 of about 2,550,084 (285)

Synthesis and characterization of polymer networks obtained by conventional radical and RAFT copolymerization processes in supercritical carbon dioxide

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Conventional and RAFT dispersion copolymerizations of HEMA and EGDMA in supercritical CO2 are compared in terms of swelling index (crosslink density), morphology, particle size distribution, and modular differential scanning calorimetry. Abstract The syntheses of net‐poly((2‐hydroxyethylene methacrylate)‐co‐(ethylene glycol dimethacrylate ...
Patricia Pérez‐Salinas   +6 more
wiley   +1 more source

Sustainable Hydrogen Production by Glycerol and Monosaccharides Catalytic Acceptorless Dehydrogenation (AD) in Homogeneous Phase

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
wiley   +1 more source

Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo   +4 more
wiley   +1 more source

Redox Biocatalysis in Lidocaine‐Based Hydrophobic Deep Eutectic Solvents: Non‐Conventional Media Outperform Aqueous Conditions

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
Two hydrophobic DESs, lidocaine/oleic acid and lidocaine/decanoic acid, were utilized as reaction media that were enzyme‐compatible and highly substrate‐solubilizer for carbonyl reduction catalyzed by horse liver alcohol dehydrogenase, focusing on the effect of water contents and on maximizing substrate loadings, which showcases for the first time the ...
Ningning Zhang   +6 more
wiley   +1 more source

Modeling and monitoring injectivity evolution during cold CO2 injection with field evidence from aquistore carbon capture and storage operations

open access: yesDeep Underground Science and Engineering, EarlyView.
This work integrates 5 years of field data from the Aquistore CCS project with a non‐isothermal THM modeling framework to explain how cold CO2 injection alters injectivity over time. The study shows that sustained cooling near the wellbore reduces effective stresses, promotes tensile micro‑cracking, and leads to semi‑reversible permeability enhancement
Alireza Rangriz Shokri   +3 more
wiley   +1 more source

EFFECT OF SOLVENT FLOW RATE ON THE SUPERCRITICAL CARBON DIOXIDE EXTRACTION OF ANDROGRAPHOLIDE FROM ANDROGRAPHIS PANICULATA [PDF]

open access: yes, 2006
Malaysia is one of the major medicinal plants (Andrographis paniculata) producers in the world. Extraction of bioactive component (andrographolide) from ground dried leaves of this plant using supercritical carbon dioxide has been studied.
Kumoro, A.C., Hasan, M.
core   +1 more source

Determination of Pure Neutron Radiolysis Yields for use in Chemical Modeling of Supercritical Water [PDF]

open access: yes, 2007
This work has determined pure neutron radical yields at elevated temperature and pressure up to supercritical conditions using a reactor core radiation.
Edwards, Eric
core  

Circular and Bio‐Sourced Polymers for Energy Applications: Natural Feedstocks, Recycling, and Upcycling Routes

open access: yesEcoEnergy, EarlyView.
This review provides a critical comparative analysis of circular and bio‐sourced polymers for energy storage, systematically evaluating natural feedstocks alongside recycling and upcycling strategies for battery components. Key structure–property–performance relationships and inherent trade‐offs between sustainability metrics and electrochemical ...
Priyank Sinha   +3 more
wiley   +1 more source

Latitudinal effect on the structure of snake–prey interaction networks is mediated by snake species richness

open access: yesEcography, EarlyView.
Despite the growing number of studies on trophic networks in recent decades, there are still important gaps in our understanding of how these networks are structured across broad environmental gradients. These gaps are even greater in some groups of terrestrial vertebrates, such as snakes, requiring a cohesive synthesis of their broader trophic ...
Daniela Pinto‐Coelho   +4 more
wiley   +1 more source

Supercritical Fluids: An Innovative Strategy for Drug Development

open access: yesBioengineering
Nanotechnology plays a pivotal role in the biomedical field, especially in the synthesis and regulation of drug particle size. Reducing drug particles to the micron or nanometer scale can enhance bioavailability.
Hui Liu   +4 more
doaj   +1 more source

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