Results 151 to 160 of about 20,671 (253)

3D‐Printed Crosslinked Nanocellulose‐MXene Hydrogels and Aerogels with High Strength and Conductivity

open access: yesSmall, EarlyView.
This study presents a robust strategy for 3D printing conductive, mechanically resilient MXene–CNF composite structures using a single‐step freeze‐induced crosslinking method. The printed architectures remain stable in both wet and dry states, exhibit high electrical conductivity and mechanical strength, and demonstrate practical application in fully ...
Nuzhet Inci Kilic   +5 more
wiley   +1 more source

Mild-Temperature Supercritical Water Confined in Hydrophobic Metal-Organic Frameworks. [PDF]

open access: yesJ Am Chem Soc
Merchiori S   +15 more
europepmc   +1 more source

Navigating Classical and Nonclassical Realms of Nucleation and Crystallization

open access: yesSmall, EarlyView.
Classical nucleation and growth theories have long been foundational, yet recent nonclassical concepts have challenged and refined our understanding of solid‐state genesis. This paradigm shift introduced new, often ambiguous vocabulary. Here, we clarify key concepts, correct common misconceptions, and provide a terminological field guide across systems,
Stephan E. Wolf, Peter G. Vekilov
wiley   +1 more source

A Versatile Heterometallic Microporous MOF for Photocatalytic Hydrogen Generation

open access: yesSmall, EarlyView.
This work describes a green and scalable approach to robust and flexible heterometallic MOFs, MIP‐215's, with tunable photoactivity for efficient, noble‐metal‐free solar hydrogen production. ABSTRACT Photocatalytic particulate systems offer a cost‐effective solar hydrogen production but are generally limited by narrow visiblelight absorption and poor ...
Xingze Wang   +10 more
wiley   +1 more source

Characterization of the Pore Environments in Covalent Organic Frameworks by Dynamic Spin Probe Exchange

open access: yesSmall, EarlyView.
Covalent organic frameworks (COFs) with alkyl or triethylene glycol pore linings are probed with water‐dissolved nitroxide radicals using CW EPR spectroscopy. Adsorption affinity, local polarity, and radical concentration inside the pores are quantified, revealing hydrogen bonding, dipolar, and π‐π interactions that govern guest binding, which ...
Sebastian Michler   +5 more
wiley   +1 more source

Downsize Effect on Photocatalytic Syngas Production of a 2D Metal Organic Framework—Tuning the Selectivity From HER to CO2RR via Dimensional Modulation and Mechanical Exfoliation of 2D Metal‐Organic Layers

open access: yesSmall Methods, EarlyView.
A cobalt(II) 2D MOF (2D) has been downsized by covalent bond breaking to form a 1D MOF (1D) and by sonication, to form a 2D exfoliated MOF (2D‐ex). Photocatalytic CO2 reduction shows that 2D and 1D lead to H2‐enriched syngas, whereas 2D‐ex leads to CO‐enriched syngas.
Rajat Saha   +10 more
wiley   +1 more source

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