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Supramolecular Autoregulation

Journal of the American Chemical Society, 2013
Enzyme activity in biological systems is often governed by control mechanisms in which the catalytic properties are made sensitive or insensitive to differences in enzyme or substrate concentration. Here, we report the first supramolecular system where the catalytic activity is made concentration independent through the use of newly designed inhibitor ...
Rodriguez Llansola, F., Meijer, E.W.
openaire   +3 more sources

Supramolecular photochirogenesis

Chem. Soc. Rev., 2014
Supramolecular photochirogenesis is a rapidly growing interdisciplinary area of science at the boundary of photochemistry, asymmetric synthesis and supramolecular chemistry. The major advantage of supramolecular photochirogenesis over the conventional molecular one is entropic in origin, being achieved by preorganizing substrate(s) in the ground state ...
Cheng, Yang, Yoshihisa, Inoue
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The Contributions of Supramolecular Kinetics to Dynamics of Supramolecular Polymers

ChemPlusChem, 2022
AbstractSupramolecular polymers exhibit well‐controlled dynamics with fascinating capacity for remodeling, self‐healing, and stimuli‐responsiveness. Supramolecular kinetics of non‐covalent bonds is a dominant control handle among the relevant factors to tailor dynamics of supramolecular polymers.
Hao Chen, Kun Tong
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Supramolecular Polymers

MRS Bulletin, 2000
What started as a scientific challenge roughly 10 years ago has become a technological reality today, as materials from supramolecular polymers and their many applications as smart materials have emerged. Synthetic polymeric materials are among the most important classes of new materials introduced in the 20th century.
Brunsveld, L.   +2 more
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Supramolecular ferroelectrics

Nature Chemistry, 2015
Supramolecular chemistry uses non-covalent interactions to coax molecules into forming ordered assemblies. The construction of ordered materials with these reversible bonds has led to dramatic innovations in organic electronics, polymer science and biomaterials.
Alok S, Tayi   +4 more
openaire   +2 more sources

Supramolecular cruciforms

Chemical Communications, 2006
By self-assembling fluorescent pyridyl cruciforms with bis-Pd-pincer complexes, supramolecular assemblies with attractive optical properties were synthesized; these assemblies show potential as electro-optical materials.
Warren W, Gerhardt   +5 more
openaire   +2 more sources

Supramolecular amphiphiles

Chem. Soc. Rev., 2011
Supramolecular amphiphiles (SA), also named superamphiphiles, refer to amphiphiles that are formed by non-covalent interactions. This tutorial review focuses on the molecular architectures of SAs, including diversified topologies such as single chain, double chain, bolaform, gemini and rotaxane types.
Xi, Zhang, Chao, Wang
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Supramolecular medicine

Chem. Soc. Rev., 2017
Guest editors Honggang Cui and Bing Xu introduce the supramolecular medicine issue of Chemical Society Reviews. In a broader context, Supramolecular Medicine can be defined as the supramolecular formulation of diagnostic and therapeutic agents for the diagnosis, treatment, and prevention of disease.
Honggang Cui, Bing Xu
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Supramolecular biomaterials

Nature Materials, 2015
Polymers, ceramics and metals have historically dominated the application of materials in medicine. Yet rationally designed materials that exploit specific, directional, tunable and reversible non-covalent interactions offer unprecedented advantages: they enable modular and generalizable platforms with tunable mechanical, chemical and biological ...
Webber, Matthew J.   +3 more
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Emergences of supramolecular chemistry: from supramolecular chemistry to supramolecular science

Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2011
We describe the field of supramolecular chemistry as a consequence of the progress of chemistry from its premises to recent achievements. Supramolecular chemistry has been claimed to be an emergent field of research taking its roots in chemistry. According to the definitions of emergences related to hierarchy or more recently to scope, supramolecular ...
Jacques Vicens, Quentin Vicens
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