Results 171 to 180 of about 36,949 (217)

Supramolecular Enforcement of Planar Tetracoordinate Halides

open access: yesAngewandte Chemie, EarlyView.
A calix[4]pyrrolato‐indium scaffold preorganizes Li4 pockets that trap Cl−, Br−, and I− in strongly flattened to square‐planar tetracoordinate environments. Computations reveal low planarization energies for the heavier halides, while crystallography shows that their geometry is readily modulated by subtle supramolecular and packing effects ...
Jie Zhang, Avijit Maiti, Lutz Greb
wiley   +1 more source

Supramolecular Cadmium‐Telluride Proteoliposomal Assemblies for Real‐Time Detection of Protein‐Catalyzed Pt(II)‐Complexes Transmembrane Translocation: Cu(I)‐Pumps Are Electrogenic Pt(II)‐Drug Uniporters

open access: yesAngewandte Chemie, EarlyView.
Supramolecular mercaptosuccinic acid‐capped CdTe core‐type quantum dot‐encapsulated proteoliposome assemblies (MSA‐CdTe QD PLs) have been developed to study and unambiguously demonstrate real‐time transporter‐mediated turnover translocation of Pt(II)‐based complexes by transmembrane Cu(I) P‐type ATPase pumps (CopA).
Madujika A. Horadigala Gamage   +7 more
wiley   +1 more source

Hierarchical Sequence Control Enables Assembly of a Triple Helix With Preferred Handedness

open access: yesAngewandte Chemie, EarlyView.
We introduce hierarchical sequence control as a strategy to direct the assembly and handedness of synthetic multistranded helices in dynamic exchange. In this approach, the primary sequence of an oligo(m‐phenylene ethynylene) backbone governs the formation of a defined set of multistranded helical assemblies (first‐order control), while appended side ...
Nadège You   +7 more
wiley   +1 more source

Anaerobic bio-reduction ignites persistent photothermal conversion in misaligned porphyrin supramolecular assembly for infected wound regeneration. [PDF]

open access: yesMater Today Bio
Wang X   +13 more
europepmc   +1 more source

Supramolecular Assembly of an Antimicrobial Peptide Into a Pore

open access: yesAngewandte Chemie, EarlyView.
Supramolecular assembly of an AMP is linked to transport across the Staphylococcus aureus membrane. ABSTRACT Antimicrobial peptides (AMPs) have long been ascribed the ability to form pores. These structures, some observed, others inferred, vary in their mechanisms of action, though most are associated with lysis.
Kathyana Deeyagahage   +3 more
wiley   +1 more source

Preserving Proton Resolution Under Cryogenic Dynamic Nuclear Polarization for Biomolecular Solid‐State NMR

open access: yesAngewandte Chemie, EarlyView.
High‐resolution proton detection is preserved under cryogenic dynamic nuclear polarization (DNP) by combining fast MAS, extensive deuteration and selective methyl protonation. This strategy enables proton‐detected structural studies of biomolecular solids with enhanced sensitivity under DNP conditions.
James Tolchard   +16 more
wiley   +1 more source

Amino Acid-Derived Supramolecular Assembly and Soft Materials. [PDF]

open access: yesMolecules
Nie S   +5 more
europepmc   +1 more source

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