Light and Dark Cycles Control the Structural Evolution of Photoresponsive Supramolecular Systems
Here, we report a photoswitchable synthetic peptide that, under light energy cycles, exhibits supramolecular polymorphism coupled to darkness‐driven structural self‐selection. We demonstrate that light sustains a transient assembled state in the form of helical nanoribbons, hindering the system from undergoing a transition to the disassembled state ...
Alejandro Méndez‐Ardoy +6 more
wiley +1 more source
Controlled reductive unfolding of BSA-α under pH stimuli and its supramolecular assembly with aminated gum acacia nanocarriers for targeted gemcitabine delivery in lung cancer therapy. [PDF]
Li Y, Zhang P, Ma Y, Jia C.
europepmc +1 more source
Here we demonstrate that weak HB CH donor cyanostilbenes promote water/ion transport through their ability to form less‐ordered transient water channels within the lipid bilayer with increased water permeability and NO3−/ Cl− selectivity. ABSTRACT Transmembrane water transport strongly depends on how dynamic, translocating water clusters are stabilized
Ioan Stroia +6 more
wiley +1 more source
Vortex-Flow-Directed Chiral Macroscopic Ordering of Platelet Nanostructures Formed via the Supramolecular Assembly of Platinum Complexes with Bis(phenylisoxazolyl)benzene. [PDF]
Yoshida M +10 more
europepmc +1 more source
Porous Organic Cages for CO2 Capture and Confined Reduction
Porous organic cages (POCs) enable the coupling of CO2 capture and conversion through the interplay of molecular structure and solid‐state organization. Beyond intrinsic cavities, packing‐dependent pore accessibility and mass transport govern local CO2 concentration and catalytic performance, linking adsorption to reactivity in integrated capture ...
Valeria Amendola, Sonia La Cognata
wiley +1 more source
Amino Acid-Derived Supramolecular Assembly and Soft Materials. [PDF]
Nie S +5 more
europepmc +1 more source
Redirecting Excited‐State Proton Transfer Through Supramolecular Polymerization in Nanoconfinement
Supramolecular confinement redirects the excited‐state proton transfer pathway of an amphoteric emitter. In water, the molecule undergoes ESPD, whereas co‐assembly with γ‐cyclodextrin forms nanotubes that template slip‐stacked emitter pairs and enable ESIMPT. Structural and photophysical characterization of the assemblies shows that the preorganization
Luis C. Pantaleone +8 more
wiley +1 more source
Supramolecular assembly of novel achatin structurally similar peptide as potential G protein-coupled receptors anticancer ligands: focus on its pseudo-macrocycle nature. [PDF]
Bojarska J +7 more
europepmc +1 more source
Reduced Symmetry Metal–Organic Cage‐to‐Framework Materials
A series of Ag(I) MOFs was synthesised from organic cages of varying structure and symmetry as linkers. Minor variations in the cage linkers were shown to significantly influence the structures of the resulting MOFs. This work represents the first incorporation of reduced symmetry (including chiral), intrinsically porous building blocks into MOFs, and ...
Cameron J. T. Cox +5 more
wiley +1 more source
Modulating the Interactions of Peptide-Polyphenol for Supramolecular Assembly Coatings with Controllable Kinetics and Multifunctionalities. [PDF]
Huo K +8 more
europepmc +1 more source

