Light and Dark Cycles Control the Structural Evolution of Photoresponsive Supramolecular Systems
Here, we report a photoswitchable synthetic peptide that, under light energy cycles, exhibits supramolecular polymorphism coupled to darkness‐driven structural self‐selection. We demonstrate that light sustains a transient assembled state in the form of helical nanoribbons, hindering the system from undergoing a transition to the disassembled state ...
Alejandro Méndez‐Ardoy +6 more
wiley +1 more source
Electrochemically Triggered Supramolecular Polymerization Under Kinetic Control
Chemical and electrochemical stimuli enable controlled supramolecular polymerization of perylene diimide–histidine (PDI–His). Redox processes mediate the transformation of kinetically trapped aggregates into thermodynamically stable nanofibers, thereby supporting seeded growth. This approach provides a strategy for regulating self‐assembly pathways and
Eun Gyu Lee +6 more
wiley +2 more sources
Preparation of a Supramolecular Assembly of Vitamin D in a β-Cyclodextrin Shell with Silver Nanoparticles. [PDF]
Bakirova RY +10 more
europepmc +1 more source
Interaction Hierarchy and Polymorphic Structure–Property Dynamics in Luminescent Molecular Crystals
Competing homotypic and heterotypic intermolecular interactions give rise to polymorphic structure–property dynamics in luminescent molecular crystals. Thermal and mechanical stimuli induce distinct phase‐transition pathways accompanied by pronounced photoluminescence changes.
Mahiro Nakabayashi, Shotaro Hayashi
wiley +2 more sources
Discharge and electron correlation of radical molecules in a supramolecular assembly on superconducting Pb(111). [PDF]
Drechsel C +9 more
europepmc +1 more source
Re‐envisioning the Ligandable Proteome: Reactive Metallo‐Scaffolds (r‐mS) combine non‐covalent protein engagement by a metallo‐scaffold with covalent cysteine capture through a tethered chloroacetamide warhead. Chemoproteomic profiling reveals unique enzyme engagement including ligases, kinases and methyltransferases, highlighting opportunities for ...
Jessica E. Waters +15 more
wiley +2 more sources
Molecular-Scale Tuning of Low-Molecular-Weight Gelators Controls Supramolecular Assembly and Directs Human Mesenchymal Stem Cell Growth. [PDF]
Tangsombun C +5 more
europepmc +1 more source
Supramolecular assembly of hypervalent iodine macrocycles and alkali metals. [PDF]
Pandey K +6 more
europepmc +1 more source
Induction and Stabilization of Peptide Alpha‐Helices on Silica Nanoparticles
Covalent docking turns silica nanoparticles (SNPs) into α‐helix‐stabilizing surfaces. Dynamic imine formation allows peptides with lysine residues aligned on one helical face to adapt to the surface before reduction locks the structure in place, while preserving the opposite face for functional recognition.
Fidel Lozano‐Elena +3 more
wiley +2 more sources
Supramolecular Assembly of Dendrobium officinale Polysaccharides-Hyaluronic Acid and Its Moisturizing Properties. [PDF]
Ren H, Di T, Meng H, Zha P.
europepmc +1 more source

