Results 201 to 210 of about 52,059 (299)

Light and Dark Cycles Control the Structural Evolution of Photoresponsive Supramolecular Systems

open access: yesAngewandte Chemie, EarlyView.
Here, we report a photoswitchable synthetic peptide that, under light energy cycles, exhibits supramolecular polymorphism coupled to darkness‐driven structural self‐selection. We demonstrate that light sustains a transient assembled state in the form of helical nanoribbons, hindering the system from undergoing a transition to the disassembled state ...
Alejandro Méndez‐Ardoy   +6 more
wiley   +1 more source

Electrochemically Triggered Supramolecular Polymerization Under Kinetic Control

open access: yesAngewandte Chemie, EarlyView.
Chemical and electrochemical stimuli enable controlled supramolecular polymerization of perylene diimide–histidine (PDI–His). Redox processes mediate the transformation of kinetically trapped aggregates into thermodynamically stable nanofibers, thereby supporting seeded growth. This approach provides a strategy for regulating self‐assembly pathways and
Eun Gyu Lee   +6 more
wiley   +2 more sources

Preparation of a Supramolecular Assembly of Vitamin D in a β-Cyclodextrin Shell with Silver Nanoparticles. [PDF]

open access: yesMolecules
Bakirova RY   +10 more
europepmc   +1 more source

Interaction Hierarchy and Polymorphic Structure–Property Dynamics in Luminescent Molecular Crystals

open access: yesAngewandte Chemie, EarlyView.
Competing homotypic and heterotypic intermolecular interactions give rise to polymorphic structure–property dynamics in luminescent molecular crystals. Thermal and mechanical stimuli induce distinct phase‐transition pathways accompanied by pronounced photoluminescence changes.
Mahiro Nakabayashi, Shotaro Hayashi
wiley   +2 more sources

Discharge and electron correlation of radical molecules in a supramolecular assembly on superconducting Pb(111). [PDF]

open access: yesNanoscale Horiz
Drechsel C   +9 more
europepmc   +1 more source

Proteome‐Wide Target Identification Using Reactive Metallo‐Scaffolds (r‐mS): A Platform for Metallodrug Discovery

open access: yesAngewandte Chemie, EarlyView.
Re‐envisioning the Ligandable Proteome: Reactive Metallo‐Scaffolds (r‐mS) combine non‐covalent protein engagement by a metallo‐scaffold with covalent cysteine capture through a tethered chloroacetamide warhead. Chemoproteomic profiling reveals unique enzyme engagement including ligases, kinases and methyltransferases, highlighting opportunities for ...
Jessica E. Waters   +15 more
wiley   +2 more sources

Supramolecular assembly of hypervalent iodine macrocycles and alkali metals. [PDF]

open access: yesBeilstein J Org Chem
Pandey K   +6 more
europepmc   +1 more source

Induction and Stabilization of Peptide Alpha‐Helices on Silica Nanoparticles

open access: yesAngewandte Chemie, EarlyView.
Covalent docking turns silica nanoparticles (SNPs) into α‐helix‐stabilizing surfaces. Dynamic imine formation allows peptides with lysine residues aligned on one helical face to adapt to the surface before reduction locks the structure in place, while preserving the opposite face for functional recognition.
Fidel Lozano‐Elena   +3 more
wiley   +2 more sources

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