Results 51 to 60 of about 108,781 (359)

Selective Adsorption of a Supramolecular Structure on Flat and Stepped Gold Surfaces

open access: yes, 2017
Halogenated aromatic molecules assemble on surfaces forming both hydrogen and halogen bonds. Even though these systems have been intensively studied on flat metal surfaces, high-index vicinal surfaces remain challenging, as they may induce complex ...
Donadio, Davide, Peköz, Rengin
core   +1 more source

Immune signalling by supramolecular assemblies [PDF]

open access: yesImmunology, 2018
SummaryFormation of supramolecular assemblies appears to be a general mechanism in immune signalling pathways. These supramolecular assemblies appear to form through a nucleated polymerization mechanism. This review examines selected immune signalling pathways that involve supramolecular assemblies, describes the concepts of protein polymerization, and
Santosh Kumar, Shweta Jain
openaire   +2 more sources

Removing Homocoupling Defects in Alkoxy/Alkyl‐PBTTT Enhances Polymer:Fullerene Co‐Crystal Formation and Stability

open access: yesAdvanced Functional Materials, EarlyView.
PBTTT‐OR‐R, a C14‐alkoxy/alkyl‐PBTTT polymer derivative, is of substantial interest for optoelectronics due to its specific fullerene intercalation behavior and enhanced charge‐transfer absorption. Comparing this polymer with (S) and without (O) homocoupling defects reveals that PBTTT‐OR‐R(O) forms stable co‐crystals with PC61BM, while PBTTT‐OR‐R(S ...
Zhen Liu   +14 more
wiley   +1 more source

Fine‐Tuning Supramolecular Assemblies by Controlling Micellar Aggregates

open access: yesMacromolecular Materials and Engineering, 2023
Supramolecular assembly can be used to fabricate complex functional materials by organizing simple building blocks. However, it is difficult to control the hierarchical assembly across multiple length scales.
Dipankar Ghosh   +7 more
doaj   +1 more source

Does Supramolecular Gelation Require an External Trigger?

open access: yesGels, 2022
The supramolecular gelation of small molecules is typically preceded by an external stimulus to trigger the self-assembly. The need for this trigger stems from the metastable nature of most supramolecular gels and can limit their applicability.
Ruben Van Lommel   +9 more
doaj   +1 more source

Supramolecular electrode assemblies for bioelectrochemistry

open access: yesChemical Communications, 2017
Supramolecular approaches in bioelectrochemistry have boosted enzyme loading on electrodes and shaped biocompatible environments for enzymes.
Theodoros Laftsoglou, Lars J. C. Jeuken
openaire   +3 more sources

Supramolecular Assemblies for Electronic Materials

open access: yesChemistry – A European Journal, 2020
AbstractThis work presents a synergy between organic electronics and supramolecular chemistry, in which a host–guest complex is designed to function as an efficacious electronic material. Specifically, the noncovalent recognition of a fullerene, phenyl‐C61‐butyric acid methyl ester (PC61BM), by an alternating perylene diimide (P)‐bithiophene (B ...
Timothy A. Barendt   +8 more
openaire   +3 more sources

Intermolecular Interactions as Driving Force of Increasing Multiphoton Absorption in a Perylene Diimide‐Based Coordination Polymer

open access: yesAdvanced Functional Materials, EarlyView.
This study uncovers the unexplored role of intermolecular interactions in multiphoton absorption in coordination polymers. By analyzing [Zn2tpda(DMA)2(DMF)0.3], it shows how the electronic coupling of the chromophores and confinement in the MOF enhance two‐and three‐photon absorption.
Simon Nicolas Deger   +11 more
wiley   +1 more source

Constructing Supramolecular Frameworks Based Imidazolate-Edge-Bridged Metallacalix[3]arenes via Hierarchical Self-Assemblies

open access: yesCrystals, 2022
Hierarchical self-assembly of novel supramolecular structures has obtained increasing attention. Herein we design and synthesize the palladium(II)-based molecular basket-like structures, as structural analog of metallacalix[3]arene [M3L3]3+ (M = (dmbpy ...
Bo Cui   +4 more
doaj   +1 more source

Potential Driven Non-Reactive Phase Transitions of Ordered Porphyrin Molecules on Iodine-Modified Au(100): An Electrochemical Scanning Tunneling Microscopy (EC-STM) Study [PDF]

open access: yes, 2018
The modelling of long-range ordered nanostructures is still a major issue for the scientific community. In this work, the self-assembly of redox-active tetra(N-methyl-4-pyridyl)-porphyrin cations (H2TMPyP) on an iodine-modified Au(100) electrode surface ...
Blanco, Mat\uedas   +3 more
core   +1 more source

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