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Various aspects of supramolecular polymer were discussed. The hydrogen bonding enforced by liquid crystallinity and phase separation in the supramolecuar polymers were examined. The supramolecular polymers, based on discotic molecules, such as tryphenylenes, pthalocyanines and porphyrins were also elaborated.
L. Brunsveld +3 more
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Summary: The precise sequence control of polymer chain is an important research topic of polymer chemistry. Although some methods such as iterative synthesis and supramolecular polymerization have been developed to fabricate sequence-controllable polymer,
Hui Li +9 more
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In the past few decades, supramolecular polymers have emerged as novel materials with a wide variety of different functions. In this essay we reflect on the history of supramolecular polymers, their function in various applications and the challenges to be met in the near future.
Greef, de, T.F.A., Meijer, E.W.
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Low-temperature supramolecular adhesives based on hyperbranched polyester
Adhesives have been widely applied in various fields. However, most industrial adhesives contain organic solvents, which are toxic and difficult to clean after use.
Yiting Jing +4 more
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Functional Supramolecular Polymers [PDF]
Supramolecular Polymers Explained While polymers are constructed from chemically bonded units, supramolecular polymers arise through reversible linkages, such as hydrogen bonding and electrostatic interactions. Recent advances in the field of supramolecular polymer science have moved from a fundamental understanding of assembly ...
T. Aida, E. W. Meijer, S. I. Stupp
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Chiral supramolecular polymers
Within the field of supramolecular polymers, chiral supramolecular polymers are an excellent benchmark to generate helical structures that can clarify the origin of homochirality in Nature or to find out new exciting functionalities of organic materials.
Fátima García +2 more
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Developing eco-friendly chiral organocatalysts with the combined advantages of homogeneous catalysis and heterogeneous processes is greatly desired. In this work, a family of amphiphilic one-handed helical polyisocyanides bearing phosphine pendants is ...
Lei Xu +6 more
doaj +1 more source
Thermo‐responsive topological metamorphosis in covalent‐and‐supramolecular polymer architectures
Topological metamorphosis represents a powerful approach to modulate the properties of polymers. However, it still remains a major challenge to achieve the tunability of bulk mechanical properties via topological transformation in supramolecular polymer ...
Yongming Wang +7 more
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Self-healing metallo-supramolecular hydrogel based on specific Ni2+ coordination interactions of poly(ethylene glycol) with bistriazole pyridine ligands in the main chain [PDF]
In this study, a supramolecular hydrogel formed by incorporating the 2,6-bis(1,2,3-triazol-4-yl)-pyridine (btp) ligand in the backbone of a polymer prepared by copper(I)-catalyzed alkyne-azide cycloaddition (CuAAC) "click" polyaddition reaction of 2,6 ...
Hoogenboom, Richard +2 more
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Threading Through Macrocycles Enhances the Performance of Carbon Nanotubes as Polymer Fillers [PDF]
In this work we study the reinforcement of polymers by mechanically interlocked derivatives of single-walled carbon nanotubes (SWNTs). We compare the mechanical properties of fibers made of polymers and of composites with pristine single-walled carbon ...
Bernal, M. Mar +8 more
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