Results 31 to 40 of about 77,416 (292)
Nature Communications, 2023 Immobilizing organocatalysts onto helical polymers can facilitate catalyst recycling and boost enantioselectivity. Here, the authors prepare achiral organoiodine-functionalized single left- and right-handed helical polyisocyanides from the same monomers ...
Zong-Quan Wu +6 more
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Supramolecular control over self-assembly and double thermoresponsive behavior of an amphiphilic block copolymer [PDF]
, 2020 A poly(ethylene glycol)-b-poly[N, N-dimethylacrylamide-ran-2-acrylamidoethyl nonanoate] (PEG-b-P(DMA-AAEN)) block copolymer has been demonstrated to show double thermoresponsive behavior in aqueous solution in the presence of hydroxypropylated ...
Hoogenboom, Richard +5 more
core +1 more source
Mechanochemistry in Polymers with Supramolecular Mechanophores [PDF]
, 2015 Mechanochemistry is a burgeoning field of materials science. Inspired by nature, many scientists have looked at different ways to introduce weak bonds into polymeric materials to impart them with function and in particular mechano-responsiveness. In the following sections, the incorporation of some of the weakest bonds, i.e.
Haehnel, Alexander P. +3 more
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Heterogeneous Nucleation in Protein Crystallization
Biomimetics, 2023 Protein crystallization was first discovered in the nineteenth century and has been studied for nearly 200 years. Protein crystallization technology has recently been widely used in many fields, such as drug purification and protein structure analysis ...
Hao Liu, Yue Zhao, Jing Sun
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Supramolecular hierarchy among halogen and hydrogen bond donors in light-induced surface patterning [PDF]
, 2015 Halogen bonding, a noncovalent interaction possessing several unique features compared to the more familiar hydrogen bonding, is emerging as a powerful tool in functional materials design.
Barrett C. J. +10 more
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An unexpected N-dependence in the viscosity reduction in all-polymer nanocomposite
Nature Communications, 2019 Addition of small nanoparticles into polymer melt can lead to decrease in viscosity but the underlying mechanism for such viscosity reduction remains unclear.
Tao Chen +9 more
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Hydrogen bonded supramolecular elastomers : correlating hydrogen bonding strength with morphology and rheology [PDF]
, 2010 A series of six low molecular weight elastomers with hydrogen bonding end-groups have been designed, synthesised and studied. The poly(urethane) based elastomers all contained essentially the same hard block content (ca.
Greenland, Barnaby William +6 more
core +1 more source
Enhanced intermolecular forces in supramolecular polymer nanocomposites
eXPRESS Polymer Letters, 2017 Ureido-pyrimidone (Upy) can dimerize in a self-complementary array of quadruple hydrogen bonds. In this paper, supramolecular polymer composites were prepared by blending Upy functionalized nanosilica with Upy end-capped polycarbonatediol.
F. Lin +5 more
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Aggregate, 2022 Understanding the precise molecular arrangement of chiral supramolecular polymers is essential not only to comprehend complex superstructures like proteins and DNA but also for the development of next‐generation optoelectronic materials, including ...
Hye Jin Cho +9 more
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Aromatic Gain in a Supramolecular Polymer
Angewandte Chemie International Edition, 2015 AbstractThe synergy of aromatic gain and hydrogen bonding in a supramolecular polymer is explored. Partially aromatic bis(squaramide) bolaamphiphiles were designed to self‐assemble through a combination of hydrophobic, hydrogen‐bonding, and aromatic effects into stiff, high‐aspect‐ratio fibers.
Saez Talens, V. +5 more
openaire +4 more sources