Results 11 to 20 of about 34,840 (283)
Thermo‐responsive topological metamorphosis in covalent‐and‐supramolecular polymer architectures
Aggregate, 2022 Topological metamorphosis represents a powerful approach to modulate the properties of polymers. However, it still remains a major challenge to achieve the tunability of bulk mechanical properties via topological transformation in supramolecular polymer ...
Yongming Wang +7 more
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How to Determine the Role of an Additive on the Length of Supramolecular Polymers?
Organic Materials, 2020 In polymer chemistry, modulation of sequence and control over chain length are routinely applied to alter and fine-tune the properties of covalent (co)polymers.
Elisabeth Weyandt +5 more
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Molecules, 2018 In this work we prepared poly(styrene–b–vinylphenol) (PS-b-PVPh) by sequential anionic living polymerization and poly(ethylene oxide-b-4-vinylpyridine) (PEO-b-P4VP) by reversible addition fragmentation chain transfer polymerization (RAFT) by ...
Tzu-Chun Tseng, Shiao-Wei Kuo
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Second-virial theory for shape-persistent living polymers templated by discs [PDF]
Phys. Rev. E 104, 054505 (2021), 2021 Living polymers composed of non-covalently bonded building blocks with weak backbone flexibility may self-assemble into thermoresponsive lyotropic liquid crystals. We demonstrate that the reversible polymer assembly and phase behavior can be controlled by the addition of (non-adsorbing) rigid colloidal discs which act as an entropic reorienting ...
arxiv +1 more source
Aggregation‐induced emission polymer systems with circularly polarized luminescence
Aggregate, 2023 Functional materials with circularly polarized luminescence (CPL) have attracted tremendous attention due to their promising applications in three‐dimensional displays, chiral recognition and catalysis, photoelectronic devices, contrast imaging ...
Hewei Yan +4 more
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Organic Materials, 2021 The introduction of a chemical additive to supramolecular polymers holds high potential in the development of new structures and functions. In this regard, various donor- and acceptor-based molecules have been applied in the design of these noncovalent ...
P. Chidchob +8 more
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Micromachines, 2022 In this study, we have used the one-pot polycondensation method to prepare novel 2D conjugated microporous polymers (Th-F-CMP) containing thiophene (Th) and fluorene (Fl) moieties through the Suzuki cross-coupling reaction. The thermogravimetric analysis
Mohamed Gamal Mohamed +9 more
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Phase stability of a reversible supramolecular polymer solution mixed with nanospheres [PDF]
J. Phys.: Condens. Matter 23 (2011) 194113, 2011 Theory is presented for the phase stability of mixtures containing nanospheres and non-adsorbing reversible supramolecular polymers. This was made possible by incorporating the depletion thickness and osmotic pressure of reversible supramolecular polymer chains into generalized free-volume theory, recently developed for investigating the phase ...
arxiv +1 more source
Crystals, 2018 A poly(styrene-b-vinylbenzyl triazolylmethyl methyladenine) (PS-b-PVBA) diblock copolymer and a poly(vinylbenzyl triazolylmethyl methylthymine) (PVBT) homopolymer were prepared through a combination of nitroxide-mediated radical polymerizations and click
Wei-Chen Su +3 more
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Ring-o-rings: a new category of supramolecular structures with topologically tunable properties [PDF]
, 2021 Macrochains of topologically interlocked rings with unique physical properties have recently gained considerable interest in supramolecular chemistry, biology, and soft matter. Most of the work has been, so far, focused on linear chains and on their variety of conformational properties compared to standard polymers.
arxiv +1 more source