In this work we prepared poly(styrene–b–vinylphenol) (PS-b-PVPh) by sequential anionic living polymerization and poly(ethylene oxide-b-4-vinylpyridine) (PEO-b-P4VP) by reversible addition fragmentation chain transfer polymerization (RAFT) by ...
Tzu-Chun Tseng, Shiao-Wei Kuo
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Supramolecular polymer hydrogels induced by host-guest interactions with di-[cyclobis(paraquat-p-phenylene)] cross-linkers: from molecular complexation to viscoelastic properties [PDF]
Supramolecular polymer networks have been designed on the basis of a -electron donor/acceptor complex: naphthalene (N)/cyclobis(paraquat-p-phenylene) (CBPQT4+=B). For this purpose, a copolymer of N,N-dimethylacrylamide P(DMA-N1), lightly decorated with 1
Belal, Khaled +7 more
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How to Determine the Role of an Additive on the Length of Supramolecular Polymers?
In polymer chemistry, modulation of sequence and control over chain length are routinely applied to alter and fine-tune the properties of covalent (co)polymers.
Elisabeth Weyandt +5 more
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Supramolecular control over self-assembly and double thermoresponsive behavior of an amphiphilic block copolymer [PDF]
A poly(ethylene glycol)-b-poly[N, N-dimethylacrylamide-ran-2-acrylamidoethyl nonanoate] (PEG-b-P(DMA-AAEN)) block copolymer has been demonstrated to show double thermoresponsive behavior in aqueous solution in the presence of hydroxypropylated ...
Hoogenboom, Richard +5 more
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Mechanochemistry in Polymers with Supramolecular Mechanophores [PDF]
Mechanochemistry is a burgeoning field of materials science. Inspired by nature, many scientists have looked at different ways to introduce weak bonds into polymeric materials to impart them with function and in particular mechano-responsiveness. In the following sections, the incorporation of some of the weakest bonds, i.e.
Haehnel, Alexander P. +3 more
openaire +4 more sources
Hydrogen bonded supramolecular elastomers : correlating hydrogen bonding strength with morphology and rheology [PDF]
A series of six low molecular weight elastomers with hydrogen bonding end-groups have been designed, synthesised and studied. The poly(urethane) based elastomers all contained essentially the same hard block content (ca.
Greenland, Barnaby William +6 more
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Electroactive peptide-based supramolecular polymers
The electroactivity as a supramolecular feature of intelligently designed self-assembled systems stimulates a wide interest in development of new stimuli-responsive biomaterials.
Ruslan Garifullin, Mustafa O. Guler
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Functional supramolecular tetrathiafulvalene-based films with mixed valences states [PDF]
Tetrathiafulvalene molecules substituted with a carboxylic acid group (TTFCOOH) were bound as redox-active moieties into a poly(4-vinyl pyridine) (P4VP) skeleton through non-covalent interactions (hydrogen bonds). The aspect of the resulting P4VP-TTFCOOH
Amabilino, David B. +4 more
core +2 more sources
A 3D printed drug delivery implant formed from a dynamic supramolecular polyurethane formulation [PDF]
Using a novel molecular design approach, we have prepared a thermo-responsive supramolecular polyurethane as a matrix material for use in drug eluting implants.
Clark, E. A. +10 more
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A poly(styrene-b-vinylbenzyl triazolylmethyl methyladenine) (PS-b-PVBA) diblock copolymer and a poly(vinylbenzyl triazolylmethyl methylthymine) (PVBT) homopolymer were prepared through a combination of nitroxide-mediated radical polymerizations and click
Wei-Chen Su +3 more
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