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Various aspects of supramolecular polymer were discussed. The hydrogen bonding enforced by liquid crystallinity and phase separation in the supramolecuar polymers were examined. The supramolecular polymers, based on discotic molecules, such as tryphenylenes, pthalocyanines and porphyrins were also elaborated.
L. Brunsveld +3 more
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Functional Supramolecular Polymers [PDF]
Supramolecular Polymers Explained While polymers are constructed from chemically bonded units, supramolecular polymers arise through reversible linkages, such as hydrogen bonding and electrostatic interactions. Recent advances in the field of supramolecular polymer science have moved from a fundamental understanding of assembly ...
T. Aida, E. W. Meijer, S. I. Stupp
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In the past few decades, supramolecular polymers have emerged as novel materials with a wide variety of different functions. In this essay we reflect on the history of supramolecular polymers, their function in various applications and the challenges to be met in the near future.
Greef, de, T.F.A., Meijer, E.W.
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Supramolecular Polymer Brushes
Polymer brushes are thin polymer films that consist of densely grafted, chain-end tethered polymers. These thin polymer films can be produced either by anchoring presynthesized chain-end functional polymers to the surface of interest ("grafting to"), or by using appropriately modified surfaces to facilitate growth of polymer chains from the substrate ("
Friederike K. Metze, Harm-Anton Klok
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Chiral supramolecular polymers
Within the field of supramolecular polymers, chiral supramolecular polymers are an excellent benchmark to generate helical structures that can clarify the origin of homochirality in Nature or to find out new exciting functionalities of organic materials.
Fátima García +2 more
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CPL-active supramolecular polymers. [PDF]
Supramolecular polymers constitute a highly dynamic and rapidly evolving research field, characterized by the continuous development of systems with increasing structural and functional complexity.
Atienza C, García F, Sánchez L.
europepmc +2 more sources
Metallo-Supramolecular Cyclic Polymers
Cyclic brush polymers represent an exciting new macromolecular topology. For the first time, this new topology has been combined with metallo-supramolecular interactions to construct novel cyclic brush polymers. Here, ring-expansion metathesis polymerization was used to synthesize a universal cyclic template with a polynorbornene backbone, which was ...
Ke, Zhang +4 more
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Sumanene-Stacked Supramolecular Polymers. Dynamic, Solvation-Directed Control [PDF]
Supramolecular polymer chemistry has recently garnered considerable attention in multidisciplinary science, however, the mutual choice of supramolecular hosts and monomer units has yet to be demonstrated on a trial-and-error basis.
Makoto, Harada +5 more
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Electron spin polarization in supramolecular polymers with complex pathways [PDF]
Mastering the manipulation of the electron spin plays a crucial role in comprehending the behavior of organic materials in various practical applications, such as asymmetric catalysis, chiroptical switches, and electronic devices.
Abhinandan, Kumar +4 more
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Controlling Exchange Pathways in Dynamic Supramolecular Polymers by Controlling Defects [PDF]
Supramolecular fibers composed of monomers that self-assemble directionally via noncovalent interactions are ubiquitous in nature, and of great interest in chemistry.
De Marco A. L. +14 more
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