Results 21 to 30 of about 14,690 (264)

Local versus bulk circular dichroism enhancement by achiral all-dielectric nanoresonators

open access: yesNanophotonics, 2022
Large optical chirality in the vicinity of achiral high-index dielectric nanostructures has been recently demonstrated as useful means of enhancing molecular circular dichroism.
Czajkowski Krzysztof M.   +1 more
doaj   +1 more source

Metal–Organic Frameworks-Based Analytical Devices for Chiral Sensing and Separations: A Review (2012–2022)

open access: yesChemosensors, 2022
Metal–organic frameworks (MOFs), as high-surface-area materials, have shown promise in various areas of application, such as chiral sensing and separation, due to their flexibility in design and organized porous cages.
Soodabeh Hassanpour   +2 more
doaj   +1 more source

Amplification of Chirality at Solid Surfaces [PDF]

open access: yesOrigins of Life and Evolution of Biospheres, 2009
Symmetry-breaking phenomena in two-dimensional crystallization at surfaces are reviewed and the potential impact to chiral amplification in three-dimensional systems in connection with the origin of homochirality in the biomolecular world is discussed.
openaire   +3 more sources

Chiral and Gravitational Anomalies on Fermi Surfaces [PDF]

open access: yesPhysical Review Letters, 2013
5 pages, 1 ...
Basar, Gokce   +2 more
openaire   +3 more sources

Chirality control of a single carbene molecule by tip-induced van der Waals interactions

open access: yesNature Communications, 2023
Non-covalent interactions such as van der Waals interactions and hydrogen bonds are crucial for the chiral induction and control of molecules, but it remains difficult to study them at the single-molecule level.
Yunjun Cao   +5 more
doaj   +1 more source

Naturally Chiral Surfaces [PDF]

open access: yesTopics in Catalysis, 2003
Chiral surfaces are of growing importance as a result of their potential for use in enantioselective chemical processes. By far the most widely used and commonly studied chiral surfaces are those prepared by templating of achiral surface with chiral organic ligands.
Horvath, Joshua D, Gellman, Andrew J
openaire   +1 more source

Asymmetric transformation of achiral gold nanoclusters with negative nonlinear dependence between chiroptical activity and enantiomeric excess

open access: yesNature Communications, 2023
The investigation of chirality at the nanoscale is important to bridge the gap between molecular and macroscopic chirality. Atomically precise metal nanoclusters provide an ideal platform for this research, while their enantiopure preparation poses a ...
Chang Liu   +6 more
doaj   +1 more source

The interplay of configuration and conformation in helical perylenequinones: Insights from chirality induction in liquid crystals and calculations

open access: yesBeilstein Journal of Organic Chemistry, 2012
The chirality transfer in liquid crystals induced by two helical perylenequinones (namely, the natural compounds cercosporin and phleichrome) was investigated by integrating measurements of helical twisting power with a conformational analysis by DFT ...
Elisa Frezza   +4 more
doaj   +1 more source

Anomalous Chiral Fermi Surfaces

open access: yesPhysical Review Letters, 2012
4 pages; version to appear in ...
openaire   +4 more sources

Molecular chirality at surfaces [PDF]

open access: yesphysica status solidi (b), 2012
AbstractWith the adsorption of larger molecules being increasingly tackled by surface scientists, the aspect of chirality often plays a role. This paper gives a topical review of molecular chirality at surfaces and gives a phenomenological overview of different aspects of adsorption and self‐assembly of chiral and prochiral molecules and the principles
Ernst Karl Heinz, Ernst Karl Heinz
openaire   +1 more source

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