Results 171 to 180 of about 44,938 (289)

Cationic Sulfonium‐Based Tripodal Ligand and Its Rh(I) Complexes

open access: yesChemistry – A European Journal, Volume 32, Issue 30, 13 August 2026.
We report a cationic EP3‐type tripodal ligand based on an aromatic sulfonium cation (E = S+) along with a series of its Rh(I) complexes. Structural, spectroscopic, electrochemical, and computational analyses of these complexes compared to isostructural analogs (E = Si− or P) reveal pronounced electron density depletion at Rh in the sulfonium congener ...
Nitsan Barel   +5 more
wiley   +1 more source

(NH4)2[Tc2O2(S2O7)4]: An Unexpected Technetium(V)‐Sulfate From the Reaction of (NH4)(TcO4) With SO3

open access: yesChemistry – A European Journal, Volume 32, Issue 29, 7 August 2026.
The reaction of the radioactive pertechnetate (99TcO4)− with the oxidizer SO3 leads to blue crystals of (NH4)2[Tc2O2(S2O7)4]. The complex dimeric [Tc2O2(S2O7)4]2− anion exhibits the technetium in the oxidation state V, showing that reduction occurs during the reaction.
Stefan Sutorius   +5 more
wiley   +1 more source

Heterozygous loss‐of‐function alleles associate the conserved 3′‐5′ exoribonuclease EXOSC10 with hypersensitivity to the anticancer drug 5‐fluorouracil

open access: yesMolecular Oncology, Volume 20, Issue 8, Page 1913-1932, August 2026.
EXOSC10, an essential nuclear RNA exosome‐associated 3′‐5′ exoribonuclease, is inhibited by the anticancer drug 5‐fluorouracil (5‐FU), and EXOSC10 depletion increases 5‐FU sensitivity. The colon‐cancer variant EXOSC10S402T, located in a proteolysis motif, is stable and nuclear but nonfunctional in vivo.
Radhika Sain   +10 more
wiley   +1 more source

Band Alignment and Composition of the Buried TiO2/GaInP Interface

open access: yesAdvanced Materials Interfaces, Volume 13, Issue 16, 18 August 2026.
Buried TiO2$\text{TiO}_2$/GaInP interfaces formed by mild plasma‐enhanced ALD are shown to be largely insensitive to the initial GaInP surface condition. Angle‐dependent photoelectron spectroscopy reveals similar interfacial chemistry and band alignment for phosphorus‐rich and naturally oxidized surfaces, demonstrating a robust pathway for reproducible
David Ostheimer   +11 more
wiley   +1 more source

Bandgap‐Engineered PtxTey:Ag2Te Composite Quantum Dots Enable Programmable NIR‐II Imaging and Photothermal‐Immune Synergistic Therapy

open access: yesAdvanced Science, Volume 13, Issue 46, 17 August 2026.
A bandgap‐engineered PtxTey:Ag2Te quantum dot platform enables tunable NIR‐IIb emission for deep‐tissue imaging and mild photothermal therapy. Conjugation with αPD‐L1 confers dual tumor targeting and real‐time monitoring of PD‐L1 dynamics. Mild photothermal modulation induces immune reprogramming, enhancing checkpoint blockade efficacy and achieving ...
Jing Liu   +9 more
wiley   +1 more source

Advances in Ceria‐Based Fuel Electrodes for Solid Oxide Cells: Reaction Mechanisms, Performance, Stability, and Future Directions With Focus on Nickel–Gadolinium‐Doped Ceria

open access: yesAdvanced Energy and Sustainability Research, Volume 7, Issue 8, August 2026.
This review focuses on Ni–GDC cermet and ceria‐based fuel electrodes for solid oxide cell applications. It highlights the advantages of mixed‐conducting ceria, defect chemistry, expanded electrochemically active reaction zones, and enhanced carbon tolerance.
Ifeanyichukwu D. Unachukwu   +4 more
wiley   +1 more source

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