Results 91 to 100 of about 2,030 (237)

Outer‐Sphere Tuning of Synthetic Iron–Sulfur Clusters Within Nanoscale Cage Frameworks

Small, EarlyView.
Noncovalent encapsulation of a synthetic iron–sulfur cluster within hydrophobic, naphthalenediimide (NDI)‐paneled cages is shown to lead to dramatic changes in the electronic structure and covalency of the Fe─S core. ABSTRACT As atomic‐scale archetypes for multi‐electron transfer, iron–sulfur clusters are compelling candidates for the design of redox ...
Rupal Baliyan, Shelby T. Davis, Jan‐Niklas Boyn, Gwendolyn A. Bailey   +3 more
wiley   +1 more source

Easily Accessible and Up‐Scalable Aliphatic Bis‐Formamides with Afterglow Luminescence: Photoluminescence Properties and Applications

Small, EarlyView.
A bis formamide molecule was found to feature afterglow properties, in both crystalline powder state and in polyvinyl alcohol films. This was attributed to the intermolecular packing that allows H‐trapped emitting state and/or clustering‐triggered emission, which was intensified upon insertion of tetramethylbenzidine as a doping agent.
Chengyi Zhu, Sara Ferrara, Anna Zieleniewska, Daniel Van Opdenbosch, Rubén D. Costa, Youssef Atoini, Jean‐Marie Lehn   +6 more
wiley   +1 more source

Polysulfide Immobilization and Sulfur Conversion Kinetics Promotion via a Tetrathiafulvalene–Crown Ether COF@Graphene Layer for High‐Rate Lithium–Sulfur Batteries

Small, EarlyView.
A polysulfide‐regulating covalent organic framework (TUS‐44) integrating tetrathiafulvalene and crown‐ether linkers forms an electron‐delocalized, ion‐coordinative network that synergistically mediates Li–S redox chemistry. When interfaced with graphene, the TUS‐44@G layer functions as a catalytic and chemisorptive interface, enabling efficient ...
Kai Sun, Tsukasa Irie, Samim Reza, Kohki Sasaki, Mika Nozaki, Tokuhisa Kawawaki, Yujun Fu, Dequan Liu, Ranjit Thapa, Saikat Das, Deyan He, Yuichi Negishi   +11 more
wiley   +1 more source

Model‐Based Systems Engineering in Space Applications: A Comprehensive Literature Review

Systems Engineering, EarlyView.
ABSTRACT The growing complexity of space engineering is driving the demand to embrace the adoption of Model‐Based Systems Engineering (MBSE). Although the MBSE is well‐practiced in the space industry, the level of effort and need required to obtain the benefits of MBSE vastly differ across enterprises; this disparity presents a significant challenge to
Rehobot Bekele Buruso, Sara Himmiche, Taiwo Tejumola, Yeshirun Alemayehu, Bertrand Rose   +4 more
wiley   +1 more source

RNA targeting and cleavage by the type III-Dv CRISPR effector complex

Nature Communications
CRISPR-Cas are adaptive immune systems in bacteria and archaea that utilize CRISPR RNA-guided surveillance complexes to target complementary RNA or DNA for destruction1–5.
Evan A. Schwartz, Jack P. K. Bravo, Mohd Ahsan, Luis A. Macias, Caitlyn L. McCafferty, Tyler L. Dangerfield, Jada N. Walker, Jennifer S. Brodbelt, Giulia Palermo, Peter C. Fineran, Robert D. Fagerlund, David W. Taylor   +11 more
doaj   +1 more source

Nickel Foam Electrodes—A Versatile, Powerful, and Readily Available Tool in Electro‐Organic Synthesis

The Chemical Record, EarlyView.
Nickel foam—one material, two faces, and several versatile roles depending on electrolytic conditions. For more than 50 years, nickel foam electrodes have served in electrosynthesis as powerful and readily available electrode materials. Due to their inexpensive nature and easy handling, they have been widely employed.
Rok Narobe, Johannes Schneider, Siegfried R. Waldvogel   +2 more
wiley   +1 more source

Long-Duration Inspection of GNSS-Denied Environments with a Tethered UAV-UGV Marsupial System

Drones
Unmanned Aerial Vehicles (UAVs) have become essential tools in inspection and emergency response operations due to their high maneuverability and ability to access hard-to-reach areas. However, their limited battery life significantly restricts their use
Simón Martínez-Rozas, David Alejo, José Javier Carpio, Fernando Caballero, Luis Merino   +4 more
doaj   +1 more source

Recent Advances in Photocatalyst‐Driven Protein Labeling and Proximity Mapping

The Chemical Record, EarlyView.
Photocatalyst‐driven protein labeling and proximity mapping have rapidly advanced as powerful strategies for spatiotemporal control in complex biological environments. This review integrates recent developments across single‐electron transfer and energy transfer‐based mechanisms and highlights how catalyst design, reactive intermediates, and diffusion ...
Shinichi Sato, Kazuki Miura, Juki Nakao, Hiroyuki Nakamura   +3 more
wiley   +1 more source

Percutaneous Aponeurotomy and Lipofilling in Complex Periorbital Scar Revision

World Journal of Otorhinolaryngology - Head and Neck Surgery, EarlyView.
ABSTRACT Periorbital scars and deformities pose a significant challenge due to the region's delicate anatomy and esthetic importance. This case series explores the application of percutaneous aponeurotomy and lipofilling (PALF) in three patients with complex periorbital scarring resulting from surgical, traumatic, and pathological causes.
Daniel Karasik, Alexandra F. Welschmeyer, Eve Tranchito, Humzah Quereshy, Saikrishna Gourishetti, Cyrus C. Rabbani   +5 more
wiley   +1 more source

GOVERNING THE CLOUD: Infrastructural Statecraft and the Political Ecology of Digital Expansion in Oregon

International Journal of Urban and Regional Research, EarlyView.
Abstract Oregon's wave of data center and semiconductor projects shows how cloud capitalism reorganizes resource systems and territorial governance. Examining Amazon, Google, and Intel, the article traces how fiscal incentives, utility programs, and land‐use instruments are recalibrated to secure hyperscale loads.
Justin Kollar
wiley   +1 more source