Results 81 to 90 of about 2,101 (233)
The Mechanism of Visible‐Light Photochemical Rearrangements of Conjugated Amide Enolates
Chemistry – A European Journal, EarlyView.Visible light irradiation of extended enolates of N‐benzylamides leads to homolytic C─N Bond cleavage, generating a biradical. Computational and mechanistic studies suggest rapid radical recombination within a solvent cage to give either ring‐expanded or rearranged products. ABSTRACT Deprotonation of conjugated amides forms colored solutions of lithium
James Mortimer +3 more
wiley +1 more source
Multimodal Fluorescent MOF@BODIPY Platform: Bridging Sensing and Mechanistic Insight
Chemistry – A European Journal, EarlyView.ABSTRACT Hybrid metal–organic frameworks (MOFs) that integrate organic chromophores constitute powerful platforms for optical sensing by combining structural order with tunable photophysics. Incorporating photoresponsive chromophores into MOFs enables sensitive probing of guest–framework interactions through well‐defined luminescent signatures. Herein,
Alejandro Cortés‐Villena +8 more
wiley +1 more source
ChemSusChem, Volume 18, Issue 6, March 15, 2025.Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
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EcoEnergy, EarlyView.This review comprehensively outlines molecular modification strategies for steering CO2 electroreduction toward C2+ products, including the classification of diverse molecular structures, elucidation of their roles in microenvironment regulation, dissection of C–C coupling pathway engineering, and forward‐looking perspectives on machine learning and ...
Lingling Peng, Hanwen Liu, Tianyou Peng
wiley +1 more source
Hydride Materials for Advanced Electrochemical Energy Storage: Progress and Perspectives
EcoEnergy, EarlyView.Hydrides are emerging as functional materials for low‐carbon electrochemical energy storage. Complex hydrides provide polyanionic electrolyte frameworks for all‐solid‐state, Li–S, and multivalent batteries; hydride ion conductors enable H− transport for emerging hydride‐based cells; and metal hydrides offer established electrode chemistries for Ni–MH ...
Taehyun Kim +4 more
wiley +1 more source
FlexMat, EarlyView.By strategically incorporating boron/nitrogen multi‐resonance (B/N‐MR) core into the o‐carborane unit, perfect exciton utilization can be achieved as well as exhibiting stimuli‐responsive properties. The resulting DBN‐oCb‐based organic light‐emitting diode (OLED) demonstrated an impressive external quantum efficiency of 22.3%, the highest reported for ...
Jiasen Zhang +8 more
wiley +1 more source
Laser &Photonics Reviews, EarlyView.Micro‐transfer printing enables GaAs and InP gain materials to be integrated on a commercial silicon nitride photonic platform. The resulting chip supports O‐ and C‐band comb and single‐mode lasers, demonstrating a scalable route toward multi‐material, multi‐wavelength, and multifunctional integrated light sources.
Dongbo Wang +12 more
wiley +1 more source
Macromolecular Rapid Communications, EarlyView.TPET‐F2CN CMP exhibited higher CO2 uptake (2.88 mmol g−1 at 273 K) and superior Rhd B adsorption, with an equilibrium capacity of 98.12 mg g−1 and a maximum monolayer capacity of 155.6 mg g−1. ABSTRACT Herein, two conjugated microporous polymers (CMPs), TPET‐FO and TPET‐F2CN, are functionalized with carbonyl and nitrile groups.
Mohamed Gamal Mohamed +8 more
wiley +1 more source
Sliding Mode Control in Aerospace Applications: A Survey
International Journal of Robust and Nonlinear Control, EarlyView.ABSTRACT Sliding mode control (SMC) enjoys robustness to matched and unmatched (in the case of minimum phase input‐output dynamics) bounded perturbations, and finite time convergence. Second‐order and higher‐order sliding mode control systems (2‐SMC/HOSMC) retain all the advantages of sliding mode control, but in addition can be applied to systems of ...
Yuri Shtessel, Christopher Edwards
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Small, EarlyView.Horan et al. demonstrate that RGD peptide‐functionalized poly(ethylene glycol) brush films synthesized in polydimethylsiloxane microfluidic channels by surface‐initiated atom transfer radical polymerization enable label‐free separation of melanoma and ovarian cancer cells based on differential integrin expression.
Stephen Horan +6 more
wiley +1 more source