Results 81 to 90 of about 2,030 (237)

One‐Shot Pd(II)‐Catalyzed Multiple C–H Activation Enables Modular Construction of Fluorenylidene Oxindole‐Based Multi(Polycyclic) Aromatic Enes

open access: yesChemistry – A European Journal, EarlyView.
A one‐shot Pd(II)‐catalyzed C─H activation strategy enables the rapid conversion of simple linear propiolamides into structurally diverse mono‐, di‐, and tri‐olefin‐bridged MPAEs. This cascade process orchestrates up to six sequential C–H activations in a single operation, providing streamlined access to highly conjugated architectures.
Haiyu Wang   +4 more
wiley   +1 more source

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

open access: yesChemistry – A European Journal, EarlyView.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

Sustainable Hydrogen Production by Glycerol and Monosaccharides Catalytic Acceptorless Dehydrogenation (AD) in Homogeneous Phase

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
wiley   +1 more source

o‐Carborane‐based multi‐resonance thermally activated delayed fluorescence emitter exhibits highly efficient and multifunctional electroluminescence

open access: yesFlexMat, EarlyView.
By strategically incorporating boron/nitrogen multi‐resonance (B/N‐MR) core into the o‐carborane unit, perfect exciton utilization can be achieved as well as exhibiting stimuli‐responsive properties. The resulting DBN‐oCb‐based organic light‐emitting diode (OLED) demonstrated an impressive external quantum efficiency of 22.3%, the highest reported for ...
Jiasen Zhang   +8 more
wiley   +1 more source

Combining the Underwater Vision Profiler 6 with sediment traps to measure in situ velocity of marine particles

open access: yesLimnology and Oceanography: Methods, EarlyView.
Abstract Particles sinking from the surface to the deep ocean play a key role in the biological carbon pump, whose efficiency depends partly on sinking velocities. Over the last decade, in situ imaging has enabled critical advances in our understanding of particle dynamics in the ocean.
Manon Laget   +5 more
wiley   +1 more source

Uncertainty assessment for a novel optically shallow water radiometric acquisition platform

open access: yesLimnology and Oceanography: Methods, EarlyView.
Abstract We present a novel motorized platform, a custom‐built jet‐ski designed for acoustic and radiometric measurements in optically shallow coastal waters. This platform integrates in‐water radiometers with single‐beam and multi‐beam acoustic sensors, along with a suite of active and passive instruments (conductivity‐temperature‐depth, fluorescence,
Raphaël Mabit   +2 more
wiley   +1 more source

Proteomic Profiling of Myofiber Repair Annexins and Their Role in Duchenne Muscular Dystrophy

open access: yesPROTEOMICS, EarlyView.
ABSTRACT Myofiber regeneration and membrane repair play crucial roles in maintaining the continuous physiological functioning of the neuromuscular system. A swift and efficient repair mechanism enables the rapid restoration of sarcolemmal integrity following cellular impairment in damaged skeletal muscles.
Paul Dowling   +6 more
wiley   +1 more source

Sliding Mode Control in Aerospace Applications: A Survey

open access: yesInternational Journal of Robust and Nonlinear Control, EarlyView.
ABSTRACT Sliding mode control (SMC) enjoys robustness to matched and unmatched (in the case of minimum phase input‐output dynamics) bounded perturbations, and finite time convergence. Second‐order and higher‐order sliding mode control systems (2‐SMC/HOSMC) retain all the advantages of sliding mode control, but in addition can be applied to systems of ...
Yuri Shtessel, Christopher Edwards
wiley   +1 more source

The Evolution of Autonomous Systems for Planetary Cave Exploration: A Review

open access: yesJournal of Field Robotics, EarlyView.
ABSTRACT The exploration of Subsurface Access Points (SAPs), such as lava tubes on the Moon and Mars, has gained significant interest due to their potential as stable environments shielded from surface radiation and temperature extremes. These sites are considered high‐value targets for detecting water and signs of ancient life, and assessing their ...
Sarah Swinton   +4 more
wiley   +1 more source

From Flybys to Sample Return: A Review of Space Probes and Robotic Sampling Technologies for Small Bodies

open access: yesJournal of Field Robotics, EarlyView.
ABSTRACT As a crucial puzzle piece of deep space exploration, exploring small bodies can provide significant scientific insights and valuable mineral resources. Unlike missions to the Moon and Mars, small‐body missions pose distinct technical challenges, including communication delays, weak gravity, and uncertain environments. This paper reviews a full
Xin Zhang   +3 more
wiley   +1 more source

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