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Smart materials based on thermoresponsive polymers

, 2014
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Thermoresponsive Coiled-Coil Peptide–Polymer Grafts

Bioconjugate Chemistry, 2023
Alkyl halide side groups are selectively incorporated into monodispersed, computationally designed coiled-coil-forming peptide nanoparticles. Poly[2-(dimethylamino)ethyl methacrylate] (PDMAEMA) is polymerized from the coiled-coil periphery using photoinitiated atom transfer radical polymerization (photoATRP) to synthesize well-defined, thermoresponsive
Nicole I. Halaszynski, Jeffery G. Saven, Darrin J. Pochan, Christopher J. Kloxin   +3 more
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Thermoresponsive Supramolecular Dendronized Polymers

Chemistry – An Asian Journal, 2011
AbstractCombining the concepts of supramolecular polymers and dendronized polymers provides the opportunity to create bulky polymers with easy structural modification and tunable properties. In the present work, a novel class of side‐chain supramolecular dendronized polymethacrylates is prepared through the host–guest interaction.
Jiatao, Yan, Wen, Li, Kun, Liu, Dalin, Wu, Feng, Chen, Peiyi, Wu, Afang, Zhang   +6 more
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Thermoresponsive Dendronized Polymers

Macromolecules, 2008
The efficient synthesis of high molar mass, first- (G1) and second-generation (G2) dendronized polymethacrylate derivatives PG1 and PG2, respectively, and their thermoresponsive properties in aqueous solution are described. All dendrons are branched 3-fold and were synthesized on the multigram scale using gallic acid as branching point and tri(ethylene
Wen Li, Afang Zhang, Kirill Feldman, Peter Walde, A. Dieter Schlüter   +4 more
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New directions in thermoresponsive polymers

Chemical Society Reviews, 2013
Interest in thermoresponsive polymers has steadily grown over many decades, and a great deal of work has been dedicated to developing temperature sensitive macromolecules that can be crafted into new smart materials. However, the overwhelming majority of previously reported temperature-responsive polymers are based on poly(N-isopropylacrylamide ...
Debashish, Roy, William L A, Brooks, Brent S, Sumerlin   +2 more
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Confined Microenvironments from Thermoresponsive Dendronized Polymers

Macromolecular Rapid Communications, 2020
AbstractConfined microenvironments in biomacromolecules arising from molecular crowding account for their well‐defined biofunctions and bioactivities. To mimick this, synthetic polymers to form confined structures or microenvironments are of key scientific value, which have received significant attention recently.
Gang Xu, Kun Liu, Biyi Xu, Yi Yao, Wen Li, Jiatao Yan, Afang Zhang   +6 more
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Thermoresponsive polymer-stabilized silver nanoparticles

Journal of Colloid and Interface Science, 2008
Silver nanoparticles (Ag NPs) stabilized by a thermoresponsive polymer, poly(N-isopropylacrylamide) (PNIPAM), have been synthesized by the reduction of silver ions with NaBH(4) in aqueous solutions. The obtained Ag NPs are very stable at room temperature due to the extended coil conformation of the PNIPAM chain at temperatures below its volume phase ...
Guo, L., Nie, J., Du, B., Peng, Z., Tesche, B., Kleinermanns, K.   +5 more
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Thermoresponsive Synthetic Polymer–Microtubule Hybrids

Langmuir, 2013
Thermoresponsive hybrids consisting of synthetic polymers and microtubules (MTs), i.e., assemblies of tubulins, were prepared by bonding MTs covalently to a few reactive units in a macromolecular strand. The hybrids exhibited the gel/sol transition because of the "assembling of tubulins to MTs/disintegrating of MTs to tubulins" by the temperature ...
Kiyotaka, Shigehara, Hiroki, Kudoh, Takamasa, Sakai, Yoshihito, Osada, Yoshihiko, Murakami, Kazuhiro, Shikinaka   +5 more
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