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Enantioselective Desymmetrization by Chiral Bifunctional H-Bonding Organocatalysts. [PDF]

open access: yesChemistry
Enantioselective desymmetrization has emerged as a highly efficient and conceptually elegant strategy for the construction of chiral molecules from readily available prochiral substrates. This review focuses on recent developments in organocatalytic desymmetrization reactions, with particular emphasis on approaches involving bifunctional activation ...
Urban M, Veselý J.
europepmc   +2 more sources

Recent advances in stereoselective bromofunctionalization of alkenes using N-bromoamide reagents [PDF]

open access: yes, 2013
10.1039/C3CC43950JChemical Communications49737985 ...
Tan, Chong Kiat, Yeung, Ying-Yeung
core   +1 more source

Thiocarbamates as plant growth regulators [PDF]

open access: yesPlant Physiology, 1961
The findings of van der Kerk and his coworkers (10) that carboxymethyl (limietlhyldithiocarbamate (1) caused epinastic curvature ancl leaf deformations as well as some elongation of Avena coleoptile tissue related its action as a growth regulator to that of indole-3-acetic acid and other aromatic structures.
R M, Muir, C, Hansch, J, Gally
openaire   +2 more sources

Novel Cholinesterase Inhibitors Based on O-Aromatic N,N-Disubstituted Carbamates and Thiocarbamates

open access: yesMolecules, 2016
Based on the presence of carbamoyl moiety, twenty salicylanilide N,N-disubstituted (thio)carbamates were investigated using Ellman’s method for their ability to inhibit acetylcholinesterase (AChE) and butyrylcholinesterase (BChE).
Martin Krátký   +4 more
doaj   +1 more source

Structure-guided engineering of molinate hydrolase for the degradation of thiocarbamate pesticides.

open access: yesPLoS ONE, 2015
Molinate is a recalcitrant thiocarbamate used to control grass weeds in rice fields. The recently described molinate hydrolase, from Gulosibacter molinativorax ON4T, plays a key role in the only known molinate degradation pathway ending in the formation ...
José P Leite   +6 more
doaj   +1 more source

A non-solvated form of [(Z)-O-methyl-N-(2-methylphenyl)thiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure and Hirshfeld surface analysis

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2016
The title compound, [Au(C9H10NOS)(C18H15P)], features a near linear P—Au—S arrangement defined by phosphane P and thiolate S atoms with the minor distortion from the ideal [P—Au—S is 177.61 (2)°] being traced in part to the close intramolecular approach ...
Chien Ing Yeo   +2 more
doaj   +1 more source

A novel three-component reaction between isocyanides, alcohols or thiols and elemental sulfur: a mild, catalyst-free approach towards O-thiocarbamates and dithiocarbamates

open access: yesBeilstein Journal of Organic Chemistry, 2019
A new multicomponent reaction has been developed between isocyanides, sulfur and alcohols or thiols under mild reaction conditions to afford O-thiocarbamates and dithiocarbamates in moderate to good yields.
András György Németh   +2 more
doaj   +1 more source

2-Oxo-2-(2-oxo-2H-chromen-3-yl)ethyl diethyldithiocarbamate

open access: yesActa Crystallographica Section E, 2013
In the title compound, C16H17NO3S2, the dihedral angles between the O/C/C/S group and the 2H-chromene ring system and the thiocarbamate group are 14.46 (9) and 83.30 (9)°, respectively.
T. G. Meenakshi   +4 more
doaj   +1 more source

[(Z)-N-(3-Fluorophenyl)-O-methylthiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure, Hirshfeld surface analysis and computational study

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2020
The title phosphanegold(I) thiolate, C26H22AuFNOPS or [Au(C8H7FNOS)(C18H15P)], has the AuI centre coordinated by phosphane-P [2.2494 (8) Å] and thiolate-S [2.3007 (8) Å] atoms to define a close to linear geometry [P—Au—S = 176.10 (3)°].
Chien Ing Yeo   +3 more
doaj   +1 more source

Thiocarbamate

open access: yesZeitschrift für Naturforschung B, 1955
Rhodanide und konz. Schwefelsäure reagieren unter Bildung von Estern miteinander, deren Hydrolyse zu Monothiocarbamidsäure-S-R-estern (Thiocarbamaten) führt.
R. Riemschneider, O. Lorenz
openaire   +1 more source

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