One‐Pot Synthesis of Thiocarbamates [PDF]
AbstractAn efficient isocyanide‐based synthesis of S‐thiocarbamates was discovered and thoroughly investigated. The new reaction protocol is a one‐pot procedure and allows the direct conversion of N‐formamides into thiocarbamates by initial dehydration with p‐toluene sulfonyl chloride to the respective isocyanide and subsequent addition of a sulfoxide ...
Waibel, Kevin A. +4 more
openaire +3 more sources
Quantum Interference Effect in Saturated Systems: Effect of Anchoring Group Position on Conductance of Bipiperidines and their in-situ Derived Dithiocarbamates. [PDF]
This study illustrates distinct quantum interference effect in saturated systems as compared to their unsaturated counterparts and the origin of multiple conductance features observed in single molecule conductance experiments of different isomers of bipiperdine and their in‐situ generated dithiocarbamates.
Rashid U +5 more
europepmc +3 more sources
In order to investigate the coordination chemistry of O-alkyl N-aryl thiocarbamate ligands toward coinage metals, CuBr was reacted with one equivalent of MeOC(=S)N(H)Ph L in MeCN solution to afford the 1D-polymeric title compound [{Cu(μ2-Br)2Cu}{μ2-MeOC(=
Wafa Arar +6 more
doaj +1 more source
Enantioselective Desymmetrization by Chiral Bifunctional H-Bonding Organocatalysts. [PDF]
Enantioselective desymmetrization has emerged as a highly efficient and conceptually elegant strategy for the construction of chiral molecules from readily available prochiral substrates. This review focuses on recent developments in organocatalytic desymmetrization reactions, with particular emphasis on approaches involving bifunctional activation ...
Urban M, Veselý J.
europepmc +2 more sources
Crystal structure of ο-methyl N-(o-tolyl)thiocarbamate, SC(OCH3)NH(C6H4CH3)
Kuan F. S. +2 more
doaj +2 more sources
Bis(μ-iodo)-tetrakis(O-methyl N-phenylthiocarbamate)-tetraiodo-dibismuth
In order to investigate the coordination chemistry of O-alkyl N-aryl thiocarbamate ligands, BiI3 was reacted with two equivalents of MeOC(=S)N(H)Ph in MeCN solution to afford the dinuclear title compound complexes [{I2Bi(μ2-I)2BiI2}{κ1-MeOC(=S)N(H)Ph}4 ...
Wafa Arar +4 more
doaj +1 more source
Cytotoxic Thiocarbamate Derivatives of Boldine [PDF]
Two new boldine derivatives: the 3-thiocarbamateboldine (3) and the 2,9 -O,O-diacetyl-3-thiocarbamateboldine (4) have been synthesized and their cytotoxicity evaluated.
Franz A, Thomet +4 more
openaire +2 more sources
Recent advances in stereoselective bromofunctionalization of alkenes using N-bromoamide reagents [PDF]
10.1039/C3CC43950JChemical Communications49737985 ...
Tan, Chong Kiat, Yeung, Ying-Yeung
core +1 more source
2-Oxo-2-(2-oxo-2H-chromen-3-yl)ethyl diethyldithiocarbamate
In the title compound, C16H17NO3S2, the dihedral angles between the O/C/C/S group and the 2H-chromene ring system and the thiocarbamate group are 14.46 (9) and 83.30 (9)°, respectively.
T. G. Meenakshi +4 more
doaj +1 more source
Click grafting of seaweed polysaccharides onto PVC surfaces using an ionic liquid as solvent and catalyst [PDF]
International audienceSeaweed antibacterial polysaccharides were grafted onto poly(vinylchloride) (PVC) surfaces using an original click chemistry pathway.
Bigot, Sandra, +3 more
core +4 more sources

