Results 31 to 40 of about 1,283 (179)

Crystal structure of 4-{[(cyanoimino)(methylsulfanyl)methyl]amino}-1,5-dimethyl-2-phenyl-2,3-dihydro-1H-pyrazol-3-one

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
In the title compound, C14H15N5OS, the tautomer present in the solid state is that in which the immediately exocyclic N atom bears the H atom. The central five-membered ring is almost planar (r.m.s.
Galal H. Elgemeie   +2 more
doaj   +1 more source

New method for synthesis of N-alkyl and N,N-dialkyl-O-ethyl and O-isopropylthiocarbamates by oxidation of ammonium salt of xhantogenic acid [PDF]

open access: yesHemijska Industrija, 2010
A synthesis of N-alkyl and N,N-dialkyl-O-ethyl and O-isopropyl thiocarbamates by oxidation of ammonium salt of ethyl and isopropylxanthogenic acid in a presence of sodium hypochlorite and hydrogen peroxide were performed.
Milisavljević Smiljka S.   +2 more
doaj   +1 more source

Crystal structure of O-ethyl N-(ethoxycarbonyl)thiocarbamate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
The title compound, C6H11NO3S, provides entries to novel carbamoyl disulfanes and related compounds of interest to our laboratory. The atoms of the central O(C=S)N(C=O)O fragment have an r.m.s.
Matthew J. Henley   +3 more
doaj   +1 more source

Carboxy Bodipy-Based Fast Trigger Fluorescent Probe for Imaging Endogenous Hypochlorous Acid

open access: yesChemosensors, 2022
Although hypochlorous acid (HClO/ClO−) is regarded as a harmful reactive oxygen species (ROS) in cells, it plays an essential role in many physiological and pathological processes, such as an innate immunity and metabolic balance.
Hao Zhang   +4 more
doaj   +1 more source

Study the Effect of UV-Light on the Degradation of Thiobencarb Technical [PDF]

open access: yesJournal of Plant Protection and Pathology, 2018
The photodegradation of thiobencarb technical by UVC ( λ=254) was studied to investigate the degradation of thiobencarb after exposure to UVC light for 144 hours, in addition to identification of some by-products by GC/MS.
I. Ismail
doaj   +1 more source

Durch anomere Amide ermöglichte divergente Synthese unsymmetrischer Harnstoffe, Carbamate, Thioester und Amide aus Aldehyden

open access: yesAngewandte Chemie, EarlyView.
Eine divergente Aldehyd‐Funktionalisierungssequenz, ermöglicht durch ein anomeres Amid, erlaubt den Ein‐Topf‐Zugang zu unsymmetrischen Harnstoffen, Carbamaten, Thiocarbamaten, Thioestern und Amiden. Entscheidend für diese Transformation ist die Bildung von N‐Boc‐Hydroxamat‐Intermediaten, die als Plattformen für eine orthogonale Aktivierung über Lossen ...
Jasper L. Tyler   +6 more
wiley   +1 more source

Photochemical Reaction Discovery Enabled by the Dynamic Speciation of Copper Complexes

open access: yesAngewandte Chemie International Edition, EarlyView.
A strategy for accelerated photochemical reaction discovery is reported that harnesses the dynamic speciation of copper complexes, driven by their labile metal–ligand bonds. This platform simplifies reaction screening by combining an earth‐abundant copper(II) salt with commercially available ligands, which reversibly generate multiple catalytic species
Alessio Regni   +6 more
wiley   +1 more source

Anomeric Amide Enabled Divergent Synthesis of Unsymmetrical Ureas, Carbamates, Thioesters, and Amides From Aldehydes

open access: yesAngewandte Chemie International Edition, EarlyView.
An anomeric amide‐enabled divergent aldehyde functionalization sequence provides one‐pot access to unsymmetrical ureas, carbamates, thiocarbamates, thioesters, and amides. Key to this transformation is the formation of N‐Boc‐hydroxamate intermediates, which serve as platforms for orthogonal activation via Lossen‐type rearrangements, single‐electron ...
Jasper L. Tyler   +6 more
wiley   +1 more source

2,3,4,6-Tetra-O-acetyl-1-[(dimethylcarbamothioyl)sulfanyl]-β-d-galactopyranose

open access: yesIUCrData
In the structure of the title compound, C17H25NO9S2, the bond lengths in the C—S—C moiety are almost equal at 1.7959 (8) and 1.7877 (9) Å, with a shorter formally double C—S bond of 1.6698 (9) Å at the other sulfur atom.
Reham A. Mohamed-Ezzat   +2 more
doaj   +1 more source

Fungal Antimicrobial Resistance: Mechanisms, Drivers, and Global Clinical Burden

open access: yesChemFoodChem, EarlyView.
ABSTRACT Fungal antimicrobial resistance (AMR) is a growing concern for world health caused by an increase in multidrug‐resistant infections, an increase in environmental reservoirs, and the ineffectiveness of current antifungal treatments. Fungal infections continue to be largely excluded from AMR initiatives while causing over 1.6 million deaths ...
Bikash Baral
wiley   +1 more source

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