Results 51 to 60 of about 1,283 (179)
Synthetic Strategies for Activity‐Based Probes to Decode Ubiquitin‐Like Modifiers
ABSTRACT Ubiquitin‐like proteins (Ubls) such as SUMO, NEDD8, ISG15, URM1, UFM1, FAT10, ATG8/ATG12, and FUBI are essential regulators of cellular homeostasis, controlling processes from protein stability and trafficking to immune signaling and autophagy.
Saibal Chanda +5 more
wiley +1 more source
(E)-O-Isopropyl N-(4-nitrophenyl)thiocarbamate
The configuration of the thione–aryl C—N single bond in the title molecule, C10H12N2O3S, is E. Centrosymmetrically related molecules are connected into a dimer via an eight-membered thioamide {...H—N—C=S}2 synthon and molecules ...
Carol A. Ellis +2 more
doaj +1 more source
The Therapeutic Potential of H2S‐Releasing Platforms in Cardiovascular Applications
The Therapeutic Potential of H2S‐Releasing Platforms. ABSTRACT Once known as a toxic gas, hydrogen sulfide (H2S) is now making its way into many therapeutic applications. Similar to its other fellow endogenous gasotransmitters, nitric oxide and carbon monoxide, H2S is a small gas with a short half‐life, making it extremely capable of penetrating ...
Tia N. Shorter, Elizabeth J. Brisbois
wiley +1 more source
Synthesis of Some Phenolic and Amino derivatives of Cinchoninic Acid [PDF]
Treatment of cinchoninic acids (1a,b) with allyl bromide afforded compounds (2a,b), and the hydrolysis of (2a) gave the 2-(4`-allyloxyphenyl) cinchoninic acid (4) .
M. A. Al-Iraqi, K Al-Naimi, A Al- Sabawi
doaj +1 more source
On Oxalyl Halide Isothiocyanates Part II: Decarbonylation and Reactivity Studies
Thermal decarbonylation of oxalyl halide isothiocyanates affords the respective carbonyl halide isothiocyanates as liquids. Crystals grown from melt allowed the elucidation of their crystal structures. Spectroscopic signatures (IR, Raman, NMR) are presented alongside reactivity studies. The reaction of oxalyl halide isothiocyanate, X(CO)2NCS (X = Cl (1)
Sven Ringelband, Frank Tambornino
wiley +1 more source
Toward Sustainable Carbonylation Reactions Enabled by CO Surrogates in Green Solvents
Carbonylation reactions offer a sustainable route to valuable carbonyl compounds. This review highlights methodologies that exploit carbonylative coupling to drastically enhance process sustainability, avoiding the direct use of CO through CO surrogates and promoting syntheses in green solvents potentially derived from renewable and sustainable sources.
Francesco Messa +2 more
wiley +1 more source
A new series of structurally rich polyaromatic isonitriles is presented as photoredox catalysts. Their photophysical properties are investigated by UV–Vis absorption and fluorescence measurements, combined with experimental and theoretical studies to evaluate both ground‐ and excited‐state redox properties.
Cristina Martini +9 more
wiley +1 more source
Echoing the recent celebration of the fortieth anniversary of the Barton-McCombie reaction, this review aims to explore another facet of radical processes for deoxygenation of alcohols by considering SET (single electron transfer) reduction of ...
Ludwig Chenneberg, Cyril Ollivier
doaj +1 more source
Designed Lewis Acid–Base Passivation for High Performance Perovskite Solar Cells
ABSTRACT Silicon's high cost and long energy payback time remain major barriers to the global expansion of solar power. In contrast, metal–halide perovskites offer abundant, solution‐processable absorbers, and have achieved efficiencies of 25%–30%, positioning them as strong competitors to silicon.
Afna Manaf +4 more
wiley +1 more source
An efficient, scalable, and versatile base‐triggered synthesis of sulfur‐substituted imides with the utility of alkyl isothiouronium salts and masked carboxylic acids under mild reaction conditions. Imides have a vast presence in pharmaceuticals and natural products, and their synthesis generally relies on the utility of the disagreeable strong ...
Malibongwe P. Shandu +4 more
wiley +1 more source

