Results 31 to 40 of about 4,875 (234)

[(Z)-N-(3-Fluorophenyl)-O-methylthiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure, Hirshfeld surface analysis and computational study

Acta Crystallographica Section E: Crystallographic Communications, 2020
The title phosphanegold(I) thiolate, C26H22AuFNOPS or [Au(C8H7FNOS)(C18H15P)], has the AuI centre coordinated by phosphane-P [2.2494 (8) Å] and thiolate-S [2.3007 (8) Å] atoms to define a close to linear geometry [P—Au—S = 176.10 (3)°].
Chien Ing Yeo, Sang Loon Tan, Huey Chong Kwong, Edward R. T. Tiekink   +3 more
doaj   +1 more source

A non-solvated form of [(Z)-O-methyl-N-(2-methylphenyl)thiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure and Hirshfeld surface analysis

Acta Crystallographica Section E: Crystallographic Communications, 2016
The title compound, [Au(C9H10NOS)(C18H15P)], features a near linear P—Au—S arrangement defined by phosphane P and thiolate S atoms with the minor distortion from the ideal [P—Au—S is 177.61 (2)°] being traced in part to the close intramolecular approach ...
Chien Ing Yeo, Sang Loon Tan, Edward R. T. Tiekink   +2 more
doaj   +1 more source

Thiocarbamate

Zeitschrift für Naturforschung B, 1955
Rhodanide und konz. Schwefelsäure reagieren unter Bildung von Estern miteinander, deren Hydrolyse zu Monothiocarbamidsäure-S-R-estern (Thiocarbamaten) führt.
R. Riemschneider, O. Lorenz
openaire   +1 more source

Crystal structure of the (E)-O-methyl-N-phenyl-thiocarbamate – 4,4′-bipyridine (1/1), C18H17N3OS [PDF]

, 2018
C18H17N3OS, monoclinic, C2/c (no. 15), a=13.4754(3) Å, b=13.8997(3) Å, c=18.0300(4) Å, β=107.202(3)°, V =3226.03(13) Å3, Z =8, Rgt(F)=0.0341, wRref(F2)=0.0878, T =100(2 ...
Tiekink, Edward R. T. *, Yeo, Chien Ing *   +1 more
core   +1 more source

Unprecedented spin localisation in a metal-metal bonded dirhenium complex [PDF]

, 2015
he molecular and electronic structure of edge-sharing bioctahedral [N(n-Bu)4]3[Re2(mnt)5] is reported here. Despite the short intermetal bond length of 2.6654(2) Å with computed bond order of 1.2, the unpaired electron is localised by the asymmetric ...
Donahue, James, Mague, Joel T., Sproules, Stephen, Yan, Yong   +3 more
core   +1 more source

Biological Evaluation and Docking Studies of New Carbamate, Thiocarbamate, and Hydrazide Analogues of Acyl Homoserine Lactones as Vibrio fischeri-Quorum Sensing Modulators

Biomolecules, 2020
A series of carbamate, thiocarbamate, and hydrazide analogues of acylhomoserine lactones (AHLs) were synthesized and their ability to modulate Vibrio fischeri-quorum sensing was evaluated.
Qiang Zhang, Yves Queneau, Laurent Soulère   +2 more
doaj   +1 more source

A monoclinic polymorph of [(Z)-N-(3-chlorophenyl)-O-methylthiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure and Hirshfeld surface analysis

Acta Crystallographica Section E: Crystallographic Communications, 2016
The title compound, [Au(C8H7ClNOS)(C18H15P)], is a monoclinic (P21/n, Z′ = 1; form β) polymorph of the previously reported triclinic form (P-1, Z′ = 1; form α) [Tadbuppa & Tiekink (2010). Acta Cryst. E66, m664].
Chien Ing Yeo, Sang Loon Tan, Edward R. T. Tiekink   +2 more
doaj   +1 more source

Synthesis and pre-clinical evaluation of a [18F] fluoromethyl-tanaproget derivative for imaging of progesterone receptor expression [PDF]

, 2016
The estrogen receptor (ER) and progesterone receptor (PR) are over-expressed in ∼50% of breast cancer lesions, and used as biomarkers to stratify patients for endocrine therapy. Currently, immunohistochemical (IHC) assessment of these lesions from a core-
Aboagye, EO, Allott, L, Carroll, L, Kealey, S, Merchant, S, Miller, PW, Smith, G, Tittrea, V, Witney, TH   +8 more
core   +1 more source

Crystal structure of 4-{[(cyanoimino)(methylsulfanyl)methyl]amino}-1,5-dimethyl-2-phenyl-2,3-dihydro-1H-pyrazol-3-one

Acta Crystallographica Section E: Crystallographic Communications, 2015
In the title compound, C14H15N5OS, the tautomer present in the solid state is that in which the immediately exocyclic N atom bears the H atom. The central five-membered ring is almost planar (r.m.s.
Galal H. Elgemeie, Mamdouh Abouzeid, Peter G. Jones   +2 more
doaj   +1 more source

Characterization of the nucleophilic reactivities of thiocarboxylate, dithiocarbonate and dithiocarbamate anions [PDF]

, 2011
The kinetics of the reactions of thiocarboxylate and thiocarbonate anions with benzhydrylium ions have been determined in acetonitrile solution using laser-flash photolytic techniques.
Duan, Xin-Hua, Maji, Biplab, Mayr, Herbert   +2 more
core   +1 more source