S-2-(Adamant-1-yl)-4-methylphenyl N,N-dimethylthiocarbamate
The title compound, C20H27NOS, was obtained from the corresponding O-thiocarbamate. The structure features a C=O bond distance of 1.209 (2) Å and an sp3-hybridized S atom [C—S—C = 101.66 (1)°].
Raúl Huerta +2 more
doaj +1 more source
Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis [PDF]
The presence of both κ2-chelating and μ2,κ2-tridentate bridging dithiocarbamate ligands in centrosymmetric {Hg[S2CN(iPr)CH2CH2OH]2}2 (1) leads to globular aggregates that are linked into a three-dimensional architecture via hydroxyl-O–H···O(hydroxy ...
Jotani, Mukesh M. +2 more
core +1 more source
[(Z)-O-Ethyl-N-(p-tolyl)thiocarbamato-κS](triphenylphosphine)-κP]gold(I)
The title compound, [Au(C10H12NOS)(C18H15P)], features a linear S,P-donor set about the central Au atom. The thiocarbamate ligand is orientated to place the aryl ring in close proximity to Au [the closest Au...C distance is 3.238 (4) &
Edward R. T. Tiekink +1 more
doaj +1 more source
Distinct coordination geometries in bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2S,S′]diphenyltin(IV) and bis[N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2S,S′]diphenyltin(IV): crystal structures and Hirshfeld surface analysis [PDF]
The crystal and molecular structures of two diphenyltin bis(dithiocarbamate)s, [Sn(C6H5)2(C5H10NOS2)2], (I), and [Sn(C6H5)2(C7H14NO2S2)2], (II), are described.
Jotani, Mukesh M. +3 more
core +2 more sources
Self‐Immolative Systems in Diagnostic and Therapeutic Applications
Self‐Immolative Systems enable the precise, residue‐free release of active molecules, drugs, probes, or sensors, via cyclization or elimination, triggered by specific stimuli. Their versatility drives advances in drug delivery, diagnostics, nanotechnology, materials chemistry, and biosensing, offering chemists control over molecular activation and ...
Windbedema Prisca Ouédraogo +2 more
wiley +1 more source
[O-Ethyl N-(4-nitrophenyl)thiocarbamato-κS](tri-p-tolylphosphine-κP)gold(I)
A nearly linear coordination geometry for Au is found in the title compound, [Au(C9H9N2O3S)(C21H21P)]. The thiocarbamate ligand is orientated so that the aryl group is in close proximity to the Au atom, consistent with an Au...π contact [Au...Cg = 3.
Edward R. T. Tiekink, Grant A. Broker
doaj +1 more source
Sulfur‐Rich μ‐O Diiron Catalyst for Electrochemical Hydrogen Production
A diferric μ‐oxido complex supported by a sulfur‐rich scaffold acts as a proton‐reduction electrocatalyst for H2 production via a μ‐hydroxido species. An aminodithiophenolate scaffold with an NS2 donor set supports diiron complex formation. The diferrous precursor activates O2, giving rise to a diferric μ‐oxido species, which acts as a proton‐reduction
Hugo C. Hernández‐Toledo +7 more
wiley +1 more source
The inhibition of the δ-class carbonic anhydrase (CAs, EC 4.2.1.1) from the diatom Thalassiosira weissflogii, TweCAδ, was investigated using a panel of 36 mono- and di-thiocarbamates chemotypes that have recently been shown to inhibit mammalian and ...
Silvia Bua +6 more
doaj +1 more source
(E)-O-Isopropyl N-(4-nitrophenyl)thiocarbamate
The configuration of the thione–aryl C—N single bond in the title molecule, C10H12N2O3S, is E. Centrosymmetrically related molecules are connected into a dimer via an eight-membered thioamide {...H—N—C=S}2 synthon and molecules ...
Carol A. Ellis +2 more
doaj +1 more source
Impact of paraquat regulation on suicide in South Korea [PDF]
Background: Ingestion of pesticides (mainly paraquat) accounted for one-fifth of suicides in South Korea in 2006-10. We investigated the effect on suicide mortality of regulatory action, culminating in a ban on paraquat in South Korea in 2011-12. Methods:
Cha, Eun Shil +5 more
core +2 more sources

