Results 61 to 70 of about 4,875 (234)
MolbankIn order to investigate the coordination chemistry of O-alkyl N-aryl thiocarbamate ligands, HgI2 was reacted with one equivalent of PrOC(=S)N(H)Ph L in toluene solution to afford the 1D polymeric title compound [{IHg(μ-I)}{κ1-PrOC(=S)N(H)Ph}]n CP1.
Wafa Arar +5 more
doaj +1 more source
Deuteration of Six‐Membered N‐Heteroarenes: Chemistry and Applications
Chemistry – A European Journal, Volume 31, Issue 67, December 1, 2025.Deuterated six‐membered N‐Heteroarenes (6NHetAr) are finding utility in an increasing repertoire of applications. Our paper comprehensively reviews synthetic approaches that have been reported for the deuteration of 6NHetAr and their fused counterparts while providing an overview of established and emerging applications for these materials.
Liju Raju +4 more
wiley +1 more source
S-2-(Adamant-1-yl)-4-methylphenyl N,N-dimethylthiocarbamate
Acta Crystallographica Section E, 2008 The title compound, C20H27NOS, was obtained from the corresponding O-thiocarbamate. The structure features a C=O bond distance of 1.209 (2) Å and an sp3-hybridized S atom [C—S—C = 101.66 (1)°].
Raúl Huerta +2 more
doaj +1 more source
Synthesis of Copper(I) Cyclic (Alkyl)(Amino)Carbene Complexes with Potentially Bidentate N^N, N^S and S^S Ligands for Efficient White Photoluminescence [PDF]
, 2019 The reaction of (Me2L)CuCl with either NaS2CX [X = OEt, NEt2 or carbazolate (Cz)] or with 1,3-diarylguanidine, 1,3-diarylformamidine or thioacetaniline in the presence of KOtBu affords the corresponding S- or N-bound copper complexes (Me2L)Cu(S^S) 1–3 ...
Bochmann, Manfred +3 more
core +1 more source
[O-Ethyl N-(4-nitrophenyl)thiocarbamato-κS](tri-p-tolylphosphine-κP)gold(I)
Acta Crystallographica Section E, 2008 A nearly linear coordination geometry for Au is found in the title compound, [Au(C9H9N2O3S)(C21H21P)]. The thiocarbamate ligand is orientated so that the aryl group is in close proximity to the Au atom, consistent with an Au...π contact [Au...Cg = 3.
Edward R. T. Tiekink, Grant A. Broker
doaj +1 more source
Evolutionary expansion of the amidohydrolase superfamily in bacteria in response to the synthetic compounds molinate and diuron [PDF]
, 2015 The amidohydrolase superfamily has remarkable functional diversity, with considerable structural and functional annotation of known sequences. In microbes, the recent evolution of several members of this family to catalyze the breakdown of environmental ...
Carr, Paul D. +8 more
core +1 more source
Journal of Enzyme Inhibition and Medicinal Chemistry, 2018 The inhibition of the δ-class carbonic anhydrase (CAs, EC 4.2.1.1) from the diatom Thalassiosira weissflogii, TweCAδ, was investigated using a panel of 36 mono- and di-thiocarbamates chemotypes that have recently been shown to inhibit mammalian and ...
Silvia Bua +6 more
doaj +1 more source
(E)-O-Isopropyl N-(4-nitrophenyl)thiocarbamate
Acta Crystallographica Section E, 2008 The configuration of the thione–aryl C—N single bond in the title molecule, C10H12N2O3S, is E. Centrosymmetrically related molecules are connected into a dimer via an eight-membered thioamide {...H—N—C=S}2 synthon and molecules ...
Carol A. Ellis +2 more
doaj +1 more source
Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis [PDF]
, 2016 The presence of both κ2-chelating and μ2,κ2-tridentate bridging dithiocarbamate ligands in centrosymmetric {Hg[S2CN(iPr)CH2CH2OH]2}2 (1) leads to globular aggregates that are linked into a three-dimensional architecture via hydroxyl-O–H···O(hydroxy ...
Jotani, Mukesh M. +2 more
core +1 more source
Impact of paraquat regulation on suicide in South Korea [PDF]
, 2015 Background: Ingestion of pesticides (mainly paraquat) accounted for one-fifth of suicides in South Korea in 2006-10. We investigated the effect on suicide mortality of regulatory action, culminating in a ban on paraquat in South Korea in 2011-12. Methods:
Cha, Eun Shil +5 more
core +2 more sources