THE OPTIMIZATION OF ZINC DIALKYLDI-THIOCARBAMATES SYNTHESIS AND DETERMINATION OF THEIR ANTIOXIDANT ACTIVITY [PDF]
A two-step optimized laboratory synthetic method of zinc dialkyldithiocarbamates is presented. In the course of the first phase, a sodium salt of dialkyldithiocarbamic acid has been synthesized from the dialkylamines, carbon disulfide and sodium ...
Aleksandar D. Marinković +3 more
doaj
Life-threatening intoxication with methylene bis(thiocyanate): clinical picture and pitfalls. A case report [PDF]
Background Methylene bis(thiocyanate) (MBT) is a microbiocidal agent mainly used in industrial water cooling systems and paper mills as an inhibitor of algae, fungi, and bacteria.
Claude Braun +14 more
core +1 more source
Substituent Effects on Cyanine Dyes Vary with Position and Chain Length
In cyanines, substituent effects vary as a function of substituent position and cyanine length. Electron‐donating‐ and ‐withdrawing groups at meso‐ and α‐positions of 4n+1/4n−1 long cyanines (n = 1, 2, 3…) cause opposing, hypsochromic and bathochromic shifts of the 1st UV–vis absorption bands.
David Dunlop +2 more
wiley +1 more source
A simple approach for the synthesis of new classes of dithiocarbamate-linked peptidomimetics [PDF]
An efficient protocol for the synthesis of a new series of dithiocarbamate-linked peptidomimetics is described. The in situ generated dithiocarbamic acid intermediate formed by the reaction of an amino acid ester and carbon disulfide in the presence of ...
Hemantha, H.P., Sureshbabu, V.V.
core +1 more source
Reactions of N-acetylcysteine adducts of aromatic (di)isocyanates with functional groups of organic molecules [PDF]
Glutathione thiocarbamate conjugates of isocyanates play a key role in transport and final reactions of isocyanates in the human body by transcarbamoylation. N-acetylcysteine is the simplest model for thiocarbamate reactions.
Frank, Petra +3 more
core
Crystal structure of tert-butyl 2-phenylethylcarbamate, C13H19NO2 [PDF]
C13H19NO2, monoclinic, P21/n (no. 14), a = 5.2692(3) Å, b = 13.8663(9) Å, c = 17.8020(13) Å, β = 93.323(6)°, V = 1298.50(15), Z = 4, R gt(F) = 0.0590, wR ref(F 2) = 0.1932, T = 293 K.
Ajarim, Mansour D. +4 more
core +1 more source
Simple Preparation of N-Protected Chiral β-Amino Alkyl Thiols from Corresponding Iodides Employing Sodium Trithiocarbonate [PDF]
A simple protocol for the preparation of N-protected amino alkyl thiols is reported that employs a reaction of sodium trithiocarbonate (Na2CS3) with N-protected amino alkyl iodides. Na2CS3 is easy to prepare and the protocol circumvents the use of strong
Chilakapati Madhu, . +2 more
core +1 more source
Catalytic Hydrogenation of Thioesters, Thiocarbamates, and Thioamides [PDF]
Direct hydrogenation of thioesters with H2 provides a facile and waste-free method to access alcohols and thiols. However, no report of this reaction is documented, possibly because of the incompatibility of the generated thiol with typical hydrogenation catalysts. Here, we report an efficient and selective hydrogenation of thioesters.
Jie Luo +4 more
openaire +4 more sources
Synthetic Strategies for Activity‐Based Probes to Decode Ubiquitin‐Like Modifiers
ABSTRACT Ubiquitin‐like proteins (Ubls) such as SUMO, NEDD8, ISG15, URM1, UFM1, FAT10, ATG8/ATG12, and FUBI are essential regulators of cellular homeostasis, controlling processes from protein stability and trafficking to immune signaling and autophagy.
Saibal Chanda +5 more
wiley +1 more source
This study illustrates distinct quantum interference effect in saturated systems as compared to their unsaturated counterparts and the origin of multiple conductance features observed in single molecule conductance experiments of different isomers of bipiperdine and their in‐situ generated dithiocarbamates.
Umar Rashid +5 more
wiley +2 more sources

