Results 81 to 90 of about 3,852 (256)

Revisiting Nucleophilic Substitution Reactions:  Microwave-Assisted Synthesis of Azides, Thiocyanates, and Sulfones in an Aqueous Medium

, 2016
A practical, rapid, and efficient microwave (MW) promoted synthesis of various azides, thiocyanates, and sulfones is described in an aqueous medium.
Dalip Kumar (467427), Rajender S. Varma (1407823), Yuhong Ju (2531302)   +2 more
core   +1 more source

C‐Terminal Functionalization Methods of Amino Acids, Peptides, and Proteins

Chemistry – A European Journal, EarlyView.
C‐terminal functionalization offers powerful routes to peptide and protein diversification, yet epimerization, hydrolysis, and selectivity remain key challenges. This Review surveys enzymatic, decarboxylative, and condensation strategies, highlighting advances toward chemo‐ and regioselective, protecting‐group‐free, atom‐efficient methods applicable to
Jay Hanssens, Mark Lambers, Romano V. A. Orru, Jordy M. Saya   +3 more
wiley   +1 more source

Alkyne‐Assisted Stereospecific Skeletal Rearrangement via Nonclassical Carbocations

Chemistry – A European Journal, EarlyView.
We report stereospecific nucleophilic substitution of homopropargylic alcohols enabled by alkyne anchimeric assistance. Alcohol activation triggers formation of a nonclassical cyclopropylidenemethyl cation, allowing efficient chirality transfer to densely substituted tertiary homopropargyl fluorides.
Rajan Kumar Kharwar, Kaushalendra Patel, Noam Orbach, Ilan Marek   +3 more
wiley   +1 more source

Novel synthesis of allyl and cyclopropylcarbinyl thiocyanates by the reaction of organocobaloximes with thiocyanogen

, 2002
970-972Thioeyanogen reacts in aprotic solvents with allyl and but-3- enyl cobaloximes to give moderate yields of allyl and cyclopropylcarbinyl thiocyanates.
Dixit, Vandana, Mandal, Debprasad, Gupta, B D   +2 more
core  

Photoinduced Synthesis of Iododifluoromethyl Sulfides from Organic Thiocyanates via Difluorinated Phosphonium Salts

A protocol for the synthesis of iododifluoromethyl sulfides from thiocyanates has been described. The method involves the formation of gem-difluorinated phosphonium salts from organic thiocyanates, difluorocarbene, and triphenylphosphine, followed by ...
Gregory A. Lozhkin, Alexander D. Dilman, Alexey L. Trifonov   +2 more
core   +1 more source

Selectfluor™: a novel and efficient reagent for the synthesis of β-hydroxy thiocyanates

, 2004
A variety of epoxides undergo rapid ring opening with ammonium thiocyanate in the presence of 10 mol % Selectfluor™ in acetonitrile at room temperature to afford the corresponding β-hydroxy thiocyanates in excellent yields with high ...
Reddy, B. V. S., Yadav, J. S., Srinivas Reddy, Ch.   +2 more
core   +1 more source

Synthesis of aryl thiocyanates and aryl selenocyanates via visible light activation of arylazo sulfones

, 2023
Two visible-light mediated protocols (based on a copper photoredox catalyzed and on a photochemical reaction, respectively) for the preparation of aryl thiocyanates and aryl selenocyanates from arylazo sulfones are presented herein, by exploiting ...
Serra M., Yue G., Gao Y., Di Terlizzi L., Lu Y., Fagnoni M., Zhao X., Protti S., Sparascio S.   +8 more
core   +1 more source

Interface‐Engineered MXene/g‐C3N4 Heterostructures for Energy and Environmental Applications

EcoEnergy, EarlyView.
This review highlights how interface engineering in MXene/g‐C3N4 heterostructures regulates charge transfer, band alignment, and surface chemistry, enabling broad applications in photocatalytic conversion, environmental remediation, energy storage, and multifunctional sensing/therapy. ABSTRACT Two‐dimensional MXene/g‐C3N4 heterostructures have recently
Feng Wang, Geng Liu, Xiaoqiang An
wiley   +1 more source

Benzoylphenyl thiocyanates are new, effective inhibitors of the mycobacterial resuscitation promoting factor B protein

Annals of Clinical Microbiology and Antimicrobials, 2017
Background Resuscitation promoting factors (Rpfs) are the proteins involved in the process of reactivation of the dormant cells of mycobacteria. Recently a new class of nitrophenylthiocyanates (NPTs), capable of inhibiting the biological and enzymatic ...
Galina R. Demina, Vadim D. Nikitushkin, Margarita O. Shleeva, Olga B. Riabova, Alexander Yu. Lepioshkin, Vadim A. Makarov, Arseny S. Kaprelyants   +6 more
doaj   +1 more source

Thiocyanates as attractive redox-active electrolytes for high-energy and environmentally-friendly electrochemical capacitors

, 2017
This manuscript reports on the novel insight into the development of high voltage carbon/carbon electrochemical capacitors operating in aqueous solutions of alkali metals and ammonium thiocyanates (KSCN, NaSCN, LiSCN, and NH4SCN).
Barbara Gorska, Paulina Bujewska, Krzysztof Fic   +2 more
core   +1 more source