Study on the Passivation of Defect States in Wide-Bandgap Perovskite Solar Cells by the Dual Addition of KSCN and KCl [PDF]
Wide-bandgap (WBG) perovskite solar cells (PSCs) are critical for high-efficiency tandem photovoltaic devices, but their practical application is severely limited by phase separation and poor film quality. To address these challenges, this study proposes
Min Li +4 more
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Aqueous Biphasic Systems Based on Tetrabutylammonium Bromide for Extraction and Determination of Azorubine, Allura Red, Sunset Yellow, Tartrazine and Fast Green in Food Samples [PDF]
Aqueous biphasic systems (ABSs) based on tetrabutylammonium bromide (TBABr) and potassium thiocyanate or citrate (K3Cit) were proposed as “green” tools for liquid–liquid microextraction of Azorubine, Allura Red, Sunset Yellow, Tartrazine and Fast Green ...
Svetlana V. Smirnova +4 more
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Thiocyanation of Pyrazoles Using KSCN/K2S2O8 Combination [PDF]
A convenient and practical thiocyanation of pyrazoles is reported employing a combination of KSCN and K2S2O8 in dimethyl sulfoxide (DMSO). The salient features of the present reaction include environmentally benign reagents and solvents, and simple ...
T. Songsichan +6 more
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The Role of Polarizability in Isoelectronic Ions: The Case of Pseudohalides [PDF]
Specific ion effects are widespread and have been studied for over a century, yet they remain poorly understood. Terms like “kosmotropes” and “chaotropes” are convenient rules of thumb but the frequent reversal of the Hofmeister series implies their ...
Mert Acar +3 more
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Paired Electrolysis Enabled Cyanation of Diaryl Diselenides with KSCN Leading to Aryl Selenocyanates
The first example of paired electrolysis-enabled cyanation of diaryl diselenides, with KSCN as the green cyanating agent, has been developed. A broad range of aryl selenocyanates can be efficiently synthesized under chemical-oxidant- and additive-free ...
Wei-Bao He +6 more
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Digital holography has been employed for in situ observation of dynamic processes occurring at the electrode|electrolyte interface during the anodic dissolution of Alloy 690 in solutions containing SO42− + SCN− with or without magnetic field (MF). It was
Dongling Xu +3 more
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Reaction of FeCl2·4H2O with KSCN and 3-cyanopyridine (pyridine-3-carbonitrile) in ethanol accidentally leads to the formation of single crystals of Fe(NCS)(Cl)(3-cyanopyridine)4 or [FeCl(NCS)(C6H4N2)4].
Asmus Müller-Meinhard +2 more
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Raman spectroscopic study of the valinomycin-KSCN complex [PDF]
Abstract This paper reports the first Raman spectroscopic study of the potassium complex of the cation-specific antibiotic valinomycin. Complete Raman spectra (140 to 3600 cm−1) of crystalline valinomycin-KSCN and its CCl4, CHCl3 and C2H5OH solutions are presented and used to probe the structure of the complex in these environments.
I M, Asher +2 more
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Synthesis, Characterization and Antibacterial Properties of Complex [Ag(SCN)(2-NH2py)] [PDF]
The reaction of AgSCN with 2-aminopyridine in ammonia solution produces the colorless crystal of catena-poly [Ag(SCN))(C6H5N2)]n. The crystals were characterized by FTIR analysis and single crystal X-Ray diffraction.
Mariyam Dewi +3 more
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Novel one-pot process for the synthesis of ethyl 2-imino-4-methyl-2,3-dihydrothiazole-5-carboxylates [PDF]
A facile one-pot two-step process for the synthesis of ethyl 2-imino-4-methyl-2,3-dihydrothiazole-5-carboxylates via the cyclocondensation of ethyl 2-thiocyanatoacetoacetate with a variety of hydrazine and hydrazide derivatives has been ...
Beyzaei Hamid, Aryan Reza, Moghadas Hadi
doaj +1 more source

