Thiocyanation of Pyrazoles Using KSCN/K2S2O8 Combination
SynOpen, 2018 A convenient and practical thiocyanation of pyrazoles is reported employing a combination of KSCN and K2S2O8 in dimethyl sulfoxide (DMSO). The salient features of the present reaction include environmentally benign reagents and solvents, and simple ...
T. Songsichan +6 more
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Electrooxidation Is a Promising Approach to Functionalization of Pyrazole-Type Compounds [PDF]
Molecules, 2021 The review summarizes for the first time the poorly studied electrooxidative functionalization of pyrazole derivatives leading to the C–Cl, C–Br, C–I, C–S and N–N coupling products with applied properties.
Boris V. Lyalin +5 more
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Metal-Free Regioselective Thiocyanation of (Hetero) Aromatic C-H Bonds using Ammonium Thiocyanate: An Overview [PDF]
Journal of Chemistry Letters, 2020 (Hetero)aryl thiocyanates have been extensively used as dyes, insecticides, vulcanization accelerators, and building blocks in the synthesis of diverse organosulfur compounds.
Soma Majedi +3 more
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A New Method for the Synthesis of 3-Thiocyanatopyrazolo[1,5-a]pyrimidines [PDF]
Molecules, 2020 In this article, we demonstrate how an original effective “metal-free” and “chromatography-free” route for the synthesis of 3-thiocyanatopyrazolo[1,5-a]pyrimidines has been developed.
Vladimir A. Kokorekin +3 more
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Imidazole Functionalized Magnetic Fe3O4 Nanoparticles a Highly Efficient and Reusable Brønsted Acid Catalyst for the Regioselective Thiocyanation of Aromatic and Heteroaromatic Compounds at Room Temperature in Water:Ethanol [PDF]
Journal of Sciences, Islamic Republic of Iran, 2015 The Magnetically recoverable Fe3O4 nanoparticle and the supported brønsted acidic ionic liquid 1-methyl-3-(3-trimethoxysilylpropyl) imidazolium hydrogen sulfate (Fe3O4-IL-HSO4) were synthesized and used as efficient magnetic catalysts for the ...
E. Rezaee Nezhad +2 more
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Green Synthesis and Catalysis, 2022 3-Thiocyanated chromones was conveniently synthesized from alkynyl aryl ketones using commercially available, inexpensive trichloroisocyanuric acid (TCCA) as oxidant and NH4SCN as thiocyanato (SCN) source.
Jiaxi Xiao +7 more
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Novel one-pot process for the synthesis of ethyl 2-imino-4-methyl-2,3-dihydrothiazole-5-carboxylates [PDF]
Journal of the Serbian Chemical Society, 2015 A facile one-pot two-step process for the synthesis of ethyl 2-imino-4-methyl-2,3-dihydrothiazole-5-carboxylates via the cyclocondensation of ethyl 2-thiocyanatoacetoacetate with a variety of hydrazine and hydrazide derivatives has been ...
Beyzaei Hamid, Aryan Reza, Moghadas Hadi
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Molecules, 2001 N-Bromosulphonamides, synthesized via direct bromination of sulphonamides, react with several types of arene substrates in the presence of KSCN to afford aryl thiocyanates. The method appears to be generally applicable to benzenoid substrates with a wide
Ardeshir Khazaei +2 more
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Molecules, 2011 SelectfluorTM F-TEDA-BF4 (1-chloromethyl-4-fluoro-1,4-diazoniabicyclo [2.2.2]octane bis(tetrafluoroborate) is not only one of the most efficient and popular reagents for electrophilic fluorination, but as a strong oxidant is also a convenient mediator or
Stojan Stavber
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Electrochemical C-H thiocyanation of BODIPYs: Two birds with one stone of KSCN
Green Synthesis and CatalysisAn efficient electrochemical C–H thiocyanation of BODIPYs was developed by using potassium thiocyanide as the source of thiocyanation. The straightforward C–H thiocyanation protocol possesses many advantages: metal-free, oxidant-free conditions ...
Kui Liu +6 more
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