Enantioselective Organocatalyzed Direct α‑Thiocyanation of Cyclic β‑Ketoesters by N‑Thiocyanatophthalimide [PDF]
, 2018 A new electrophilic thiocyanation reagent, N-thiocyanatophthalimide, was synthesized and applied to the first example of catalytic asymmetric electrophilic α-thiocyanation of various cyclic β-ketoesters by the bifunctional cinchona alkaloid catalysis ...
Fu-Xue Chen (2397511) +4 more
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K2S2O8-mediated regio- and stereo-selective thiocyanation of enamides with NH4SCN [PDF]
, 2021 A direct and straightforward thiocyanation of enamides with NH4SCN under metal-free conditions has been accomplished. A variety of (E)-β-thiocyanoenamides are readily produced in a regio- and stereoselective manner.
Wang, Qiyang +9 more
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Two-step synthesized sulfonic acid functionalized imidazolium thiocyanate solid acid catalyst for thiocyanation of various electron rich arenes by metal-free method in water [PDF]
, 2022 An eco-friendly, highly efficient, and novel sulfonic acid functionalized imidazolium thiocyanate (Imidazole-SO3H)/SCN and sulfonic acid functionalized imidazolium chloride (Imidazole-SO3H)/Cl solid acid catalyst were successfully synthesized.
Sobhan Rezayati (10870219) +2 more
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RESEARCHES ON THIOCYANATES AND ISOTHIOCYANATES. [PDF]
Journal of the American Chemical Society, 1902 n ...
Wheeler, Henry L., Johnson, Treat B.
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Molecules, 2011 SelectfluorTM F-TEDA-BF4 (1-chloromethyl-4-fluoro-1,4-diazoniabicyclo [2.2.2]octane bis(tetrafluoroborate) is not only one of the most efficient and popular reagents for electrophilic fluorination, but as a strong oxidant is also a convenient mediator or
Stojan Stavber
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Thiocyanate and Endemic Goitre [PDF]
Nature, 1951 THE amount of thiocyanate has been determined in the blood of volunteers from Sumperk in Moravia and Roudnice in Bohemia, two districts in Czechoslovakia where the incidence of endemic goitre is high. In Sumperk, the investigations were carried out in both spring and autumn, but in Roudnice in the autumn only.
K, SILINK, L, MARSIKOVA
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Visible Light-Induced Thiocyanation of Enaminone C–H Bond to Access Polyfunctionalized Alkenes and Thiocyano Chromones [PDF]
, 2019 The visible light induced C–H bond thiocyanation on the α-site of tertiary enaminones has been realized under metal-free, photocatalytic conditions in the presence of Rose Bengal, which enables the synthesis of thiocyanated alkene derivatives and ...
Yong Gao (29929) +2 more
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Electrochemical C-H thiocyanation of BODIPYs: Two birds with one stone of KSCN
Green Synthesis and CatalysisAn efficient electrochemical C–H thiocyanation of BODIPYs was developed by using potassium thiocyanide as the source of thiocyanation. The straightforward C–H thiocyanation protocol possesses many advantages: metal-free, oxidant-free conditions ...
Kui Liu +6 more
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Catalyst-Free Regioselective C‑3 Thiocyanation of Imidazopyridines [PDF]
, 2015 A direct and straightforward approach for highly regioselective thiocyanation of imidazoheterocycles through sp2 C–H functionalization has been realized at room temperature.
Daoshan Yang (734863) +7 more
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Beilstein Journal of Organic Chemistry, 2015 Reaction of benzyl and ethyl allenoates with TMSX (X = I, Br, Cl) and with NH4SCN were investigated in MeCN, DMF, and in imidazolium ionic liquids [BMIM][NTf2] and [BMIM][PF6] as solvent, in the presence and absence of Selectfluor.
A. Srinivas Reddy, Kenneth K. Laali
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