Results 11 to 20 of about 319 (90)

An Efficient and Eco-Friendly Procedure for Electrophilic Thiocyanation of Anilines and 1-(Substituted benzylidene)-2-phenyl Hydrazines

open access: yesChemistry
Thiocyanates form an important class of organic compounds commonly found in natural products that exhibit excellent antimicrobial activity. The electrophilic thiocyanation is one of the most effective methods of introducing a -SCN functional group to the
A. M. M. Mallikarjunaswamy   +4 more
doaj   +2 more sources

Imidazole Functionalized Magnetic Fe3O4 Nanoparticles a Highly Efficient and Reusable Brønsted Acid Catalyst for the Regioselective Thiocyanation of Aromatic and Heteroaromatic Compounds at Room Temperature in Water:Ethanol [PDF]

open access: yesJournal of Sciences, Islamic Republic of Iran, 2015
The Magnetically recoverable Fe3O4 nanoparticle and the supported brønsted acidic ionic liquid 1-methyl-3-(3-trimethoxysilylpropyl) imidazolium hydrogen sulfate (Fe3O4-IL-HSO4) were synthesized and used as efficient magnetic catalysts for the ...
E. Rezaee Nezhad   +2 more
doaj   +2 more sources

Regioselective C–H thiocyanation of arenes by iron(III) chloride catalysis [PDF]

open access: yes, 2023
Aryl thiocyanates are flexible synthetic intermediates that can be used in the preparation of a diverse range of arene building blocks for medicinal chemistry.
Waddell, Lachlan J.N.   +2 more
core   +2 more sources

Electrophilic Thiocyanato Reagent Assisted Oxa-Michael/Thiocyanation of ,-Unsaturated Ketones

open access: yes, 2021
A route for thiocyanation-functionalization of the electron-deficient CC double bond was developed. Regioselective thiocyanation-etherification of α,β-unsaturated ketones was achieved.
Zhenda Fu (11714059)   +7 more
core   +1 more source

Lewis Base/Brønsted Acid Cocatalysis for Thiocyanation of Amides and Thioamides

open access: yes, 2020
Lewis base/Brønsted acid cocatalysis for electrophilic thiocyanation of olefins is reported. Using a combination of triphenylphosphine selenide and diphenyl phosphate as a catalyst, a wide range of unsaturated amides and thioamides underwent ...
Arun Yadav (5044940)   +3 more
core   +2 more sources

Organocatalyzed Asymmetric α‑Thiocyanation of Oxindoles: Synthesis of Chiral Tertiary 3‑Thiocyanatoxindoles

open access: yes, 2019
An enantioselective thiocyanation of oxindoles has been developed for the first time using a bifunctional cinchona-derived organo-catalyst and N-thiocyanatophthalimide as the electrophilic thiocyanation source in the presence of 2-naphthol as the ...
Fu-Xue Chen (2397511)   +5 more
core   +3 more sources

Immobilized Rose Bengal as Photocatalyst for Metal-Free Thiocyanation of Azaheterocycles under Continuous Flow Conditions [PDF]

open access: yes, 2023
Organosulfur compounds play a crucial role as synthetic intermediates for biologically active target molecules, therefore the exploration of synthetic methodologies to incorporate sulfur-containing functional groups into organic scaffolds is a topic of ...
Monica F. Boselli   +4 more
core   +3 more sources

Water Microdroplet Chemistry for Accelerating Green Thiocyanation and Discovering Water-Controlled Divergence

open access: yes, 2023
As an important class of five-membered N-heterocyclic compounds, pyrazolin-5-one derivatives play an extremely important role in the construction of fine chemicals and bioactive molecules.
Luyun Xue   +9 more
core   +1 more source

Reaction of allene esters with Selectfluor/TMSX (X = I, Br, Cl) and Selectfluor/NH4SCN: Competing oxidative/electrophilic dihalogenation and nucleophilic/conjugate addition

open access: yesBeilstein Journal of Organic Chemistry, 2015
Reaction of benzyl and ethyl allenoates with TMSX (X = I, Br, Cl) and with NH4SCN were investigated in MeCN, DMF, and in imidazolium ionic liquids [BMIM][NTf2] and [BMIM][PF6] as solvent, in the presence and absence of Selectfluor.
A. Srinivas Reddy, Kenneth K. Laali
doaj   +1 more source

Selective Electrochemical Thiocyanation of lndoles1

open access: yes, 1992
Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi-221 005 Department of Applied Chemistry, Banaras Hindu University, Varanasi-221 005 Manuscript received 28 May 1992, accepted 21 September 1992 Selective Electrochemical ...
DINESH C. RUPAINWAR   +2 more
core   +1 more source

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