Thiocyanation of Pyrazoles Using KSCN/K2S2O8 Combination [PDF]
SynOpen, 2018 A convenient and practical thiocyanation of pyrazoles is reported employing a combination of KSCN and K2S2O8 in dimethyl sulfoxide (DMSO). The salient features of the present reaction include environmentally benign reagents and solvents, and simple ...
T. Songsichan +6 more
doaj +2 more sources
An Efficient and Eco-Friendly Procedure for Electrophilic Thiocyanation of Anilines and 1-(Substituted benzylidene)-2-phenyl Hydrazines [PDF]
ChemistryThiocyanates form an important class of organic compounds commonly found in natural products that exhibit excellent antimicrobial activity. The electrophilic thiocyanation is one of the most effective methods of introducing a -SCN functional group to the
A. M. M. Mallikarjunaswamy +4 more
doaj +2 more sources
Regioselective C-H Thiocyanation of Arenes by Iron(III) Chloride Catalysis. [PDF]
J Org Chem, 2023 Aryl thiocyanates are flexible synthetic intermediates that can be used in the preparation of a diverse range of arene building blocks for medicinal chemistry.
Waddell LJN, Senkans MR, Sutherland A.
europepmc +5 more sources
Imidazole Functionalized Magnetic Fe3O4 Nanoparticles a Highly Efficient and Reusable Brønsted Acid Catalyst for the Regioselective Thiocyanation of Aromatic and Heteroaromatic Compounds at Room Temperature in Water:Ethanol [PDF]
Journal of Sciences, Islamic Republic of Iran, 2015 The Magnetically recoverable Fe3O4 nanoparticle and the supported brønsted acidic ionic liquid 1-methyl-3-(3-trimethoxysilylpropyl) imidazolium hydrogen sulfate (Fe3O4-IL-HSO4) were synthesized and used as efficient magnetic catalysts for the ...
E. Rezaee Nezhad +2 more
doaj +2 more sources
Cooperative Photometallobiocatalysis: Nonheme Fe Enzyme-Catalyzed Enantioconvergent Radical Decarboxylative Azidation, Thiocyanation, and Isocyanation of Redox-Active Esters. [PDF]
Angew Chem Int Ed EnglThrough the directed evolution of an underexploited nonheme Fe extradiol dioxygenase, we developed a unified cooperative photobiocatalytic strategy to allow for three types of enantioconvergent radical transformations, including azidation, thiocyanation, and isocyanation.
Zhao LP +8 more
europepmc +3 more sources
Photoredox-Catalyzed Decarboxylative Bromination, Chlorination and Thiocyanation Using Inorganic Salts. [PDF]
Angew Chem Int Ed Engl, 2023 Decarboxylative halogenations of alkyl carboxylic acids are highly valuable reactions for the synthesis of stucturally diverse alkyl halides. However, many reported protocols rely on stoichiometric strong oxidants or highly electrophilic halogenating ...
Wu J, Shu C, Li Z, Noble A, Aggarwal VK.
europepmc +2 more sources
Cationic Selenuranes - Bench-Stable Sources of Se(III) Radicals. [PDF]
Angew Chem Int Ed EnglWe present the synthesis of cationic selenurane salts via oligomerization of dibenzoselenophene‐based radical cations, allowing the formation of radicals without external activation. The salts can be prepared on a multigram scale and stored as solids for more than a month at ambient conditions.
Zhiliaev K +4 more
europepmc +3 more sources
Electrophilic Thiocyanato Reagent Assisted Oxa-Michael/Thiocyanation of ,-Unsaturated Ketones [PDF]
, 2021 A route for thiocyanation-functionalization of the electron-deficient CC double bond was developed. Regioselective thiocyanation-etherification of α,β-unsaturated ketones was achieved.
Zhenda Fu (11714059) +7 more
core +1 more source
Lewis Base/Brønsted Acid Cocatalysis for Thiocyanation of Amides and Thioamides [PDF]
, 2020 Lewis base/Brønsted acid cocatalysis for electrophilic thiocyanation of olefins is reported. Using a combination of triphenylphosphine selenide and diphenyl phosphate as a catalyst, a wide range of unsaturated amides and thioamides underwent ...
Arun Yadav (5044940) +3 more
core +3 more sources
Organocatalyzed Asymmetric α‑Thiocyanation of Oxindoles: Synthesis of Chiral Tertiary 3‑Thiocyanatoxindoles [PDF]
, 2019 An enantioselective thiocyanation of oxindoles has been developed for the first time using a bifunctional cinchona-derived organo-catalyst and N-thiocyanatophthalimide as the electrophilic thiocyanation source in the presence of 2-naphthol as the ...
Fu-Xue Chen (2397511) +5 more
core +5 more sources