ChemistryThiocyanates form an important class of organic compounds commonly found in natural products that exhibit excellent antimicrobial activity. The electrophilic thiocyanation is one of the most effective methods of introducing a -SCN functional group to the
A. M. M. Mallikarjunaswamy +4 more
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Regioselective C-H Thiocyanation of Arenes by Iron(III) Chloride Catalysis. [PDF]
J Org Chem, 2023 Aryl thiocyanates are flexible synthetic intermediates that can be used in the preparation of a diverse range of arene building blocks for medicinal chemistry.
Waddell LJN, Senkans MR, Sutherland A.
europepmc +3 more sources
Imidazole Functionalized Magnetic Fe3O4 Nanoparticles a Highly Efficient and Reusable Brønsted Acid Catalyst for the Regioselective Thiocyanation of Aromatic and Heteroaromatic Compounds at Room Temperature in Water:Ethanol [PDF]
Journal of Sciences, Islamic Republic of Iran, 2015 The Magnetically recoverable Fe3O4 nanoparticle and the supported brønsted acidic ionic liquid 1-methyl-3-(3-trimethoxysilylpropyl) imidazolium hydrogen sulfate (Fe3O4-IL-HSO4) were synthesized and used as efficient magnetic catalysts for the ...
E. Rezaee Nezhad +2 more
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Cooperative Photometallobiocatalysis: Nonheme Fe Enzyme-Catalyzed Enantioconvergent Radical Decarboxylative Azidation, Thiocyanation, and Isocyanation of Redox-Active Esters. [PDF]
Angew Chem Int Ed EnglThrough the directed evolution of an underexploited nonheme Fe extradiol dioxygenase, we developed a unified cooperative photobiocatalytic strategy to allow for three types of enantioconvergent radical transformations, including azidation, thiocyanation, and isocyanation.
Zhao LP +8 more
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Photoredox-Catalyzed Decarboxylative Bromination, Chlorination and Thiocyanation Using Inorganic Salts. [PDF]
Angew Chem Int Ed Engl, 2023 Decarboxylative halogenations of alkyl carboxylic acids are highly valuable reactions for the synthesis of stucturally diverse alkyl halides. However, many reported protocols rely on stoichiometric strong oxidants or highly electrophilic halogenating ...
Wu J, Shu C, Li Z, Noble A, Aggarwal VK.
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Cationic Selenuranes - Bench-Stable Sources of Se(III) Radicals. [PDF]
Angew Chem Int Ed EnglWe present the synthesis of cationic selenurane salts via oligomerization of dibenzoselenophene‐based radical cations, allowing the formation of radicals without external activation. The salts can be prepared on a multigram scale and stored as solids for more than a month at ambient conditions.
Zhiliaev K +4 more
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Recent Synthetic Advances in C-H/N-H Functionalization of 1H-Pyrazoles: Diverse Strategies Across Variously Substituted Scaffolds. [PDF]
Chem RecSystematic overview of pyrazole functionalization reactions from C‐5 to N−H. It covers different strategies, from traditional cross‐coupling of prefunctionalized pyrazoles to more efficient direct functionalizations. This review briefly and systematically overviews C–H and N–H functionalization reactions of pyrazoles, aimed at creating new CC and C ...
Dzedulionytė Müldür K +3 more
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Photochemical Thiocyanation of Halobenzenes with Thiocyanate Anion [PDF]
Bulletin of the Chemical Society of Japan, 1979 Abstract Halobenzenes having such an electrondonating group as amino, hydroxyl or methoxyl group at their para position were thiocyanated with sodium thiocyanate under irradiation. Also, the ring isomer of o-thiocyanatoaniline, 2-aminobenzothiazole, was obtained by the photoreaction of o-chloroaniline with sodium thiocyanate.
Kiyoko Fujiki +2 more
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Electrophilic Thiocyanato Reagent Assisted Oxa-Michael/Thiocyanation of ,-Unsaturated Ketones
, 2021 A route for thiocyanation-functionalization of the electron-deficient CC double bond was developed. Regioselective thiocyanation-etherification of α,β-unsaturated ketones was achieved.
Zhenda Fu (11714059) +7 more
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Lewis Base/Brønsted Acid Cocatalysis for Thiocyanation of Amides and Thioamides
, 2020 Lewis base/Brønsted acid cocatalysis for electrophilic thiocyanation of olefins is reported. Using a combination of triphenylphosphine selenide and diphenyl phosphate as a catalyst, a wide range of unsaturated amides and thioamides underwent ...
Arun Yadav (5044940) +3 more
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