Tandem hydrothiocyanation/cyclization of CF3-iminopropargyl alcohols with NaSCN in the presence of AcOH [PDF]
Beilstein Journal of Organic ChemistryThe synthesis of trifluoromethylated isothiazolium thiocyanates and 4-thiocyanato-2,5-dihydrofurans is presented through hydrothiocyanation/cyclization of CF3-iminopropargyl alcohols using NaSCN in AcOH/MeCN.
Ruslan S. Shulgin +5 more
doaj +2 more sources
Inorganic Metal Thiocyanates. [PDF]
Inorg ChemMetal thiocyanates are some of the earliest reported molecular framework materials and adopta diverse range of structures. This review describes the structures, properties and syntheses ofthe known binary and ternary thiocyanates. It provides a categorization of their diverse structures,and connects them to the structures of atomic inorganic materials.
Cliffe MJ.
europepmc +3 more sources
The Enigma of Sponge-Derived Terpenoid Isothiocyanate–Thiocyanate Pairs: A Biosynthetic Proposal [PDF]
Marine DrugsThe co-occurrence of rare terpenoid thiocyanates (R-SCN), structurally similar to their more common isothiocyanate isomers (R-NCS), poses an enigma: how does the accepted path, terpenyl cation R+ → R-NC → R-NCS, accommodate R-SCN?
Tadeusz F. Molinski
doaj +2 more sources
Photocascade chemoselective controlling of ambident thio(seleno)cyanates with alkenes via catalyst modulation [PDF]
Nature CommunicationsControlling the ambident reactivity of thiocyanates in reaction manifolds has been a long-standing and formidable challenge. We report herein a photoredox strategy for installing thiocyanates and isothiocyanates in a controlled chemoselective fashion by ...
Injamam Ul Hoque +5 more
doaj +2 more sources
Photochemical Degradation of Cyanides and Thiocyanates from an Industrial Wastewater
Molecules, 2019 We have explored the simultaneous degradation of cyanides and thiocyanate present in wastewaters from a cokemaking factory using photoassisted methods under varied illumination conditions (from simulated solar light to UV light).
Begoña Fernández Pérez
exaly +3 more sources
Harnessing coumarin-thio(seleno)cyanate conjugates: potent In vivo antiproliferative agents targeting carbonic anhydrases [PDF]
Journal of Enzyme Inhibition and Medicinal ChemistryWe synthesised coumarin-based derivatives bearing thio- and selenocyanates to selectively inhibit tumour-associated carbonic anhydrases (CAs) IX and XII and to exert antiproliferative effects on tumour cells. Structural variations included chalcogen atom
Silvia Alejandra Meza-Ireta +16 more
doaj +2 more sources
An Overview of Coking Wastewater Characteristics and Treatment Technologies [PDF]
Kemija u Industriji, 2023 Coke is a high-calorie carbon mass obtained by dry distillation of coal, and used in various processes, the most significant of which is production of iron and steel.
Ana Tutić +8 more
doaj +1 more source
Inorganics, 2022 An efficient and easy approach to the synthesis of novel racemic planar-chiral 3,4-dihydroferroceno[c]pyridines and 1H-ferroceno[c]pyrroles via the intramolecular Ritter reaction of 2-ferrocenyl-3,3-dimethylbutan-2-ol with nitriles and thiocyanates in ...
Yuliya S. Rozhkova +3 more
doaj +1 more source
Complexation of lithium and sodium cations with B-phosphorylate ethers, modelling terminal groups of organophosphorus podands. An experimental and theoretical study [PDF]
, 1992 The organophosphorus compounds o-Ph2P(O)C6H4OCH3 and Ph2P(O)C2H4OCH3, which are analogs of podands' terminal groups, have been synthesized. The thermodynamic characteristics of their complexation with LiNCS and NaNCS in acetonitrile were obtained by ...
Baulin, V.E. +5 more
core +16 more sources
Synthesis of N-Fmoc-ProtectedAmino Alkyl Thiocyanates/Selenocyanates and their Applicationin the Preparation of 5-Substituted S/Se-Linked Tetrazoles [PDF]
, 2011 A novel class of N-Fmoc-protected amino alkyl thiocy- anates/selenocyanates has been prepared by thiocyanation/seleno-cyanation of the corresponding alkyl iodides. These thiocyanates/selenocyanates undergo a facile [2+3]-cycloaddition reaction
Basavalingappa, P. Vasantha +2 more
core +1 more source