Inorganic Metal Thiocyanates. [PDF]
Inorg ChemMetal thiocyanates are some of the earliest reported molecular framework materials and adopta diverse range of structures. This review describes the structures, properties and syntheses ofthe known binary and ternary thiocyanates. It provides a categorization of their diverse structures,and connects them to the structures of atomic inorganic materials.
Cliffe MJ.
europepmc +7 more sources
Photochemical Degradation of Cyanides and Thiocyanates from an Industrial Wastewater [PDF]
Molecules, 2019 We have explored the simultaneous degradation of cyanides and thiocyanate present in wastewaters from a cokemaking factory using photoassisted methods under varied illumination conditions (from simulated solar light to UV light).
Juan Jose Viña Mediavilla +4 more
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Tandem hydrothiocyanation/cyclization of CF3-iminopropargyl alcohols with NaSCN in the presence of AcOH [PDF]
Beilstein Journal of Organic ChemistryThe synthesis of trifluoromethylated isothiazolium thiocyanates and 4-thiocyanato-2,5-dihydrofurans is presented through hydrothiocyanation/cyclization of CF3-iminopropargyl alcohols using NaSCN in AcOH/MeCN.
Ruslan S. Shulgin +5 more
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The Enigma of Sponge-Derived Terpenoid Isothiocyanate–Thiocyanate Pairs: A Biosynthetic Proposal [PDF]
Marine DrugsThe co-occurrence of rare terpenoid thiocyanates (R-SCN), structurally similar to their more common isothiocyanate isomers (R-NCS), poses an enigma: how does the accepted path, terpenyl cation R+ → R-NC → R-NCS, accommodate R-SCN?
Tadeusz F. Molinski
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Phosphorus pentasulfide mediated conversion of organic thiocyanates to thiols [PDF]
Beilstein Journal of Organic Chemistry, 2017 In this paper we report an efficient and mild procedure for the conversion of organic thiocyanates to thiols in the presence of phosphorus pentasulfide (P2S5) in refluxing toluene.
Chandra Kant Maurya +2 more
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Photocascade chemoselective controlling of ambident thio(seleno)cyanates with alkenes via catalyst modulation [PDF]
Nature CommunicationsControlling the ambident reactivity of thiocyanates in reaction manifolds has been a long-standing and formidable challenge. We report herein a photoredox strategy for installing thiocyanates and isothiocyanates in a controlled chemoselective fashion by ...
Injamam Ul Hoque +5 more
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Harnessing coumarin-thio(seleno)cyanate conjugates: potent In vivo antiproliferative agents targeting carbonic anhydrases [PDF]
Journal of Enzyme Inhibition and Medicinal ChemistryWe synthesised coumarin-based derivatives bearing thio- and selenocyanates to selectively inhibit tumour-associated carbonic anhydrases (CAs) IX and XII and to exert antiproliferative effects on tumour cells. Structural variations included chalcogen atom
Silvia Alejandra Meza-Ireta +16 more
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An Overview of Coking Wastewater Characteristics and Treatment Technologies [PDF]
Kemija u Industriji, 2023 Coke is a high-calorie carbon mass obtained by dry distillation of coal, and used in various processes, the most significant of which is production of iron and steel.
Ana Tutić +8 more
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Inorganics, 2022 An efficient and easy approach to the synthesis of novel racemic planar-chiral 3,4-dihydroferroceno[c]pyridines and 1H-ferroceno[c]pyrroles via the intramolecular Ritter reaction of 2-ferrocenyl-3,3-dimethylbutan-2-ol with nitriles and thiocyanates in ...
Yuliya S. Rozhkova +3 more
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Photochemical Thiocyanation of Halobenzenes with Thiocyanate Anion [PDF]
Bulletin of the Chemical Society of Japan, 1979 Abstract Halobenzenes having such an electrondonating group as amino, hydroxyl or methoxyl group at their para position were thiocyanated with sodium thiocyanate under irradiation. Also, the ring isomer of o-thiocyanatoaniline, 2-aminobenzothiazole, was obtained by the photoreaction of o-chloroaniline with sodium thiocyanate.
Kiyoko Fujiki +2 more
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