Results 11 to 20 of about 30,747 (247)
Phosphorus pentasulfide mediated conversion of organic thiocyanates to thiols
Beilstein Journal of Organic Chemistry, 2017 In this paper we report an efficient and mild procedure for the conversion of organic thiocyanates to thiols in the presence of phosphorus pentasulfide (P2S5) in refluxing toluene.
Chandra Kant Maurya +2 more
doaj +2 more sources
Frontiers in Oncology, 2020 Sirtuin 1 (Sirt1) is a NAD+ dependent lysine deacetylase associated with the pathogenesis of various diseases including cancer. In many cancer types Sirt1 expression is increased and higher levels have been associated with metastasis and poor prognosis ...
Nathalie Wössner +11 more
doaj +2 more sources
Inorganic ChemistryMetal thiocyanates were some of the first pseudohalide compounds to be discovered and adopt a diverse range of structures. This review describes the structures, properties, and syntheses of the known binary and ternary metal thiocyanates. It provides a categorization of their diverse structures and connects them to the structures of atomic inorganic ...
M. Cliffe
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Strengthening the Magnetic Interactions in Pseudobinary First-Row Transition Metal Thiocyanates, M(NCS)2. [PDF]
Inorganic Chemistry, 2020 Understanding the effect of chemical composition on the strength of magnetic interactions is key to the design of magnets with high operating temperatures.
Euan N. Bassey +8 more
semanticscholar +1 more source
Straightforward Access to Thiocyanates via Dealkylative Cyanation of Sulfoxides
Organic Letters, 2021 Thiocyanates, versatile building blocks in organic synthesis, are shown to be easily accessible via an interrupted Pummerer reaction of sulfoxides. This facile dealkylative functionalization proceeds under mild conditions through electrophilic activation
U. Todorović, Immo Klose, N. Maulide
semanticscholar +1 more source
Organic Letters, 2019 Thiocyanate compounds are key intermediates in the synthesis of pharmaceuticals and other sulfur-containing organic compounds. Herein, we first report an electrochemical protocol to synthesize vinyl thiocyanates from decarboxylative coupling of cinnamic ...
Shun Yang +3 more
semanticscholar +1 more source
Remote functionalization by tandem radical chain reactions [PDF]
, 1997 Normal radical relay chlorination of cholestan-3α-ol directed by an attached m-iodobenzoate ester group affords a 9α-chloro steroid, but when the same reaction is conducted in the presence of an excess of CBr4 the product is a 9α-bromo steroid ...
Wiedenfeld, David
core +1 more source
The Effect of Thiocyanate Concentration on Thiocyanate Distribution and Excretion
Experimental Biology and Medicine, 1971 SummaryIt has been observed in rats that the measured volume of distribution of thiocyanate is decreased by high plasma concentrations of thiocyanate, and that large doses of thiocyanate have a faster rate of disappearance from the plasma than does endogenous thiocyanate at normal concentrations. These observations are interpreted as results of (i) the
C F, Funderburk, L, Van Middlesworth
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Constructing chiral MOFs by functionalizing 4,2′:6′,4″-terpyridine with long-chain alkoxy domains: rare examples of neb nets [PDF]
, 2016 Reactions of 4′-(4- n alkyloxyphenyl)-4,2′:6′,4″-terpyridines (alkyl = hexyl or nonyl) with CoIJNCS) 2 lead to three structurally characterized chiral 3D assemblies which adopt rare neb topologies.
Coles, Simon +5 more
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