Note on the Spectra of the Disubstituted Acetylenes and of the Mustard Oils [PDF]
, 1937 It has been observed that in the Raman spectra of many disubstituted acetylenes the line corresponding to the so-called C≡C frequency is split into two components of not greatly different intensity (1), though this is not the case in the monosubstituted ...
Badger, Richard M.
core +1 more source
Investigations on the Formation of 4-Aminobicyclo[2.2.2]-octanones
Molecules, 2005 Benzylidene acetone reacts with thiocyanates derived from secondary amines in a one-pot reaction to give 4-aminobicyclo[2.2.2]octan-2-ones. The reaction mixture was investigated for the presence of possible intermediates using GC-MS.
Robert Weis +5 more
doaj +1 more source
Observation of a reversible isomorphous phase transition and an interplay of "sigma-holes'' and "pi-holes'' in Fmoc-Leu-psi[CH2-NCS] [PDF]
, 2014 Fmoc-Leu-psi[CH2NCS] undergoes a reversible isomorphous phase transition upon cooling. The crystal structure at 100 K displays a short N=C=S center dot center dot center dot N=C=S intermolecular interaction, which has been characterized based on ...
Nagendra, G. +4 more
core +1 more source
Application of Probabilistic Risk Assessment in Establishing Perchlorate and Goitrogen Risk Mitigation Strategies. [PDF]
, 2015 This paper applies probabilistic risk assessment in quantifying risks from cumulative and aggregate risk pathways for selected goitrogens in water and food.
Crawford-Brown, Douglas
core +3 more sources
Molecules, 2001 N-Bromosulphonamides, synthesized via direct bromination of sulphonamides, react with several types of arene substrates in the presence of KSCN to afford aryl thiocyanates. The method appears to be generally applicable to benzenoid substrates with a wide
Ardeshir Khazaei +2 more
doaj +1 more source
Deoxycyanamidation of alcohols with N-Cyano-N-phenyl-p-methylbenzenesulfonamide (NCTS) [PDF]
, 2017 The first one-pot deoxycyanamidation of alcohols has been developed using N-cyano-N-phenyl-p-methylbenzenesulfonamide (NCTS) as both a sulfonyl transfer reagent and a cyanamide source, accessing a diverse range of tertiary cyanamides in excellent ...
Ashford, Matthew +6 more
core +2 more sources
The Far Side of Carboranes: Anticancer Active Monocations and Ambiently Stable Dications
Angewandte Chemie, EarlyView.This work describes the synthesis of bench‐stable dicationic carboranes. Their enhanced electrophilicity is documented by opening the clusters with weak nucleophiles or dihydrogen. The surprising stability of positively charged carboranes in water enabled a study of their in vitro antiproliferative activity, which surpassed the effects of doxorubicin ...
Vlastimil Němec +10 more
wiley +2 more sources
Effect of stevia supplementation of kale juice spheres on their quality changes during refrigerated shelf life [PDF]
, 2018 Kale is a vegetable with high contents of health–promoting compounds although its consumption as a beverage is highly limited due to its bitter flavour. Nonetheless, the bitter flavour of Brassicas may be masked by sweetening.
Artés Calero, Francisco +4 more
core +2 more sources
Aryl hydrocarbon receptor activation during in vitro and in vivo digestion of raw and cooked broccoli (brassica oleracea var. Italica) [PDF]
, 2020 Broccoli is rich in glucosinolates, which can be converted upon chewing and processing into Aryl hydrocarbon Receptor (AhR) ligands. Activation of AhR plays an important role in overall gut homeostasis but the role of broccoli processing on the ...
Capuano, Edoardo +11 more
core +4 more sources
Photocatalytic Transfer Hydrogenation Using Plastic Hydrolysates as Hydrogen Donor
Angewandte Chemie, EarlyView.Plastic waste is transformed into functional amines via solar‐driven transfer hydrogenation. Soluble monomers from acid hydrolysis of waste polymers serve as a hydrogen (electron/proton)donors in the selective reduction of nitroarenes using a visible light active photocatalyst consisting of cobalt promoted molybdenum disulfide integrated in cyanamide ...
Papa K. Kwarteng +2 more
wiley +2 more sources